Dried porous crumbs of hydrogenated block copolymer
    1.
    发明授权
    Dried porous crumbs of hydrogenated block copolymer 有权
    氢化嵌段共聚物的干燥多孔碎屑

    公开(公告)号:US07579385B1

    公开(公告)日:2009-08-25

    申请号:US09446314

    申请日:1999-04-28

    IPC分类号: C08F8/04 C08J9/00

    摘要: Disclosed are dried porous crumbs of a hydrogenated block copolymer which is obtained by hydrogenating a block copolymer comprising (a) at least one polymer block composed mainly of aromatic vinyl monomer units and (b) at least one polymer block composed mainly of conjugated diene monomer units, and which has a molecular weight of 70,000 or more. The dried porous crumbs have a water content of 1% by weight or less and having the capability of absorbing an oil in an amount of 1.0 or more, in terms of the ratio of the weight of an oil, which is absorbed by the dried porous crumbs when the dried porous crumbs are immersed in the oil at 25° C. under atmospheric pressure for 1 minute, to the weight of the dried porous crumbs. Also disclosed is a method for producing the same. When the dried porous crumbs are used as a modifier in the production of a molding resin composition from a thermoplastic resin and a liquid additive, such as a softening agent or a silicone oil, a shaped article having an excellent appearance can be produced by molding the molding resin composition.

    摘要翻译: 公开了通过氢化嵌段共聚物获得的氢化嵌段共聚物的干燥多孔屑,所述嵌段共聚物包含(a)至少一种主要由芳族乙烯基单体单元组成的聚合物嵌段和(b)至少一种主要由共轭二烯单体单元组成的聚合物嵌段 ,其分子量为70,000以上。 干燥的多孔面包屑的含水量为1重量%以下,具有吸收1.0以上的油的能力,以油的重量比计,其被干燥的多孔 当干燥的多孔面包屑在大气压下在25℃下浸渍1分钟时,将干燥的多孔面粉的重量作为干燥的多孔面包屑的重量。 还公开了其制造方法。 当由热塑性树脂和液体添加剂如软化剂或硅油制造模制树脂组合物时,当干燥的多孔面包屑用作改性剂时,可以通过模塑 模塑树脂组合物。

    Method for removing hydrocarbon solvent from solution of hydrogenated block copolymer in hydrocarbon solvent
    2.
    发明授权
    Method for removing hydrocarbon solvent from solution of hydrogenated block copolymer in hydrocarbon solvent 有权
    从烃溶剂中氢化嵌段共聚物溶液中除去烃溶剂的方法

    公开(公告)号:US06451964B1

    公开(公告)日:2002-09-17

    申请号:US09857646

    申请日:2001-06-07

    IPC分类号: C08F600

    摘要: Disclosed is a method for removing a hydrocarbon solvent from a hydrocarbon solvent solution of a hydrogenated block copolymer which is obtained by hydrogenating a block copolymer comprising a polymer block composed mainly of vinyl aromatic monomer units and a polymer block composed mainly of conjugated diene monomer units, wherein the weight ratio of the vinyl aromatic monomer units to the conjugated diene monomer units is from 5/95 to 95/5, wherein the hydrogenated block copolymer has a degree of hydrogenation of 30% or more with respect to double bonds in the conjugated diene monomer units, and wherein the method comprises: (1) mixing a hydrocarbon solvent solution of the hydrogenated block copolymer with heated water to obtain a dispersion of the solution in the heated water, and (2) introducing the dispersion into a steam stripping vessel containing heated water, wherein the dispersion is spouted into the gaseous phase in the vessel toward the surface of the heated water in the vessel under conditions wherein the vapor pressure P1 of the dispersion and the pressure P2 of the gaseous phase in the vessel satisfy the formula: P1≧P2, thereby effecting a steam stripping of the dispersion to remove the solvent therefrom and obtain porous crumbs of the hydrogenated block copolymer.

    摘要翻译: 公开了一种从氢化嵌段共聚物的烃溶剂溶液中除去烃溶剂的方法,该氢化嵌段共聚物是通过氢化包括主要由乙烯基芳族单体单元组成的聚合物嵌段的嵌段共聚物和主要由共轭二烯单体单元组成的聚合物嵌段而获得的, 其中乙烯基芳族单体单元与共轭二烯单体单元的重量比为5/95至95/5,其中氢化嵌段共聚物相对于共轭二烯中的双键具有30%以上的氢化度 单体单元,并且其中所述方法包括:(1)将氢化嵌段共聚物的烃溶剂溶液与加热的水混合以获得溶液在加热水中的分散体,和(2)将分散体引入含有 加热的水,其中分散体喷射到容器中的气相中朝向ve中的加热水的表面 在容器中的蒸气压P1和气相的压力P2满足下列公式:P1> = P2,从而进行蒸汽汽提分散体以从其中除去溶剂的条件下,得到多孔面粉 氢化嵌段共聚物。