公开(公告)号：US20070260027A1

公开(公告)日：2007-11-08

申请号：US10581766

申请日：2004-05-11

申请人： Yong Kim ,  Eun An ,  Keehoon Won ,  Jae Song ,  Jeong Ryu ,  Bong Song

发明人： Yong Kim ,  Eun An ,  Keehoon Won ,  Jae Song ,  Jeong Ryu ,  Bong Song

IPC分类号： C12P15/00 ,  C08F2/00

CPC分类号： C09D5/1662 ,  C08G8/10 ,  C12P7/00 ,  C12P7/22

摘要： The present invention relates to a process for preparing a phenolic polymer using a phenothiazine-based mediator, in particular, to a process for preparing a phenolic polymer via polymerization of phenolic monomers by using a phenothiazine-based mediator in the presence of peroxidase biocatalyst and an oxidant, thereby drastically improving the enzyme reactivity of peroxidase. The phenolic polymers prepared according to the polymerization of this invention maintain unsaturated hydrocarbon groups linked to their side chains, so that they are very useful as a curing resin because they can easily form coatings through radical curing. In addition, the coating formed using the curing resin has an antioxidation effect and a low surface energy, so that they can prevent physical attachment of marine livings. Because the antifouling-causing functional groups are not consumed, the coatings continuously exhibit durability.

摘要翻译： 本发明涉及一种使用吩噻嗪类介质制备酚类聚合物的方法，特别涉及通过在过氧化物酶生物催化剂存在下使用吩噻嗪类介质通过酚单体聚合制备酚醛聚合物的方法， 氧化剂，从而大大提高过氧化物酶的酶反应性。 根据本发明的聚合制备的酚类聚合物保持与其侧链连接的不饱和烃基，使得它们作为固化树脂非常有用，因为它们可以通过自由基固化容易地形成涂层。 此外，使用固化树脂形成的涂层具有抗氧化作用和低表面能，因此它们可以防止海洋生物的物理附着。 由于防污性官能团不被消耗，所以涂料持续地呈现出耐久性。

公开(公告)号：US07737245B2

公开(公告)日：2010-06-15

申请号：US10581766

申请日：2004-05-11

申请人： Yong Hwan Kim ,  Eun Suk An ,  Keehoon Won ,  Jae Kwang Song ,  Jeong Yong Ryu ,  Bong Keun Song

发明人： Yong Hwan Kim ,  Eun Suk An ,  Keehoon Won ,  Jae Kwang Song ,  Jeong Yong Ryu ,  Bong Keun Song

IPC分类号： C08G65/38 ,  C08G61/02

CPC分类号： C09D5/1662 ,  C08G8/10 ,  C12P7/00 ,  C12P7/22

摘要： The present invention relates to a process for preparing a phenolic polymer using a phenothiazine-based mediator, in particular, to a process for preparing a phenolic polymer via polymerization of phenolic monomers by using a phenothiazine-based mediator in the presence of peroxidase biocatalyst and an oxidant, thereby drastically improving the enzyme reactivity of peroxidase. The phenolic polymers prepared according to the polymerization of this invention maintain unsaturated hydrocarbon groups linked to their side chains, so that they are very useful as a curing resin because they can easily form coatings through radical curing. In addition, the coating formed using the curing resin has an antioxidation effect and a low surface energy, so that they can prevent physical attachment of marine livings. Because the antifouling-causing functional groups are not consumed, the coatings continuously exhibit durability.

摘要翻译： 本发明涉及一种使用吩噻嗪类介质制备酚类聚合物的方法，特别涉及通过在过氧化物酶生物催化剂存在下使用吩噻嗪类介质通过酚单体聚合制备酚类聚合物的方法， 氧化剂，从而大大提高过氧化物酶的酶反应性。 根据本发明的聚合制备的酚类聚合物保持与其侧链连接的不饱和烃基，使得它们作为固化树脂非常有用，因为它们可以通过自由基固化容易地形成涂层。 此外，使用固化树脂形成的涂层具有抗氧化作用和低表面能，因此它们可以防止海洋生物的物理附着。 由于防污性官能团不被消耗，所以涂料持续地呈现出耐久性。