公开(公告)号：US20110257363A1

公开(公告)日：2011-10-20

申请号：US13141822

申请日：2009-12-22

申请人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

IPC分类号： C08G75/04

CPC分类号： C08G75/0209 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide, in which the polyarylene sulfide is prepared by a polymerization reaction of reactants including a diiodo aromatic compound and a sulfur compound, the method including: further adding 0.01 to 10.0 wt. % of diphenyl disulfide with respect to the weight of the polyarylene sulfide to the reactants to form the polyarylene sulfide having a melting point of 265 to 320° C.The diphenyl disulfide included in the reactants according to the present invention costs far less than other conventional polymerization inhibitors to dramatically lower the production cost, and the polyarylene sulfide prepared using the diphenyl disulfide exhibits low iodine content and very excellence in thermal stability.

摘要翻译： 本发明涉及一种聚芳硫醚的制备方法，其中聚芳硫醚通过包括二碘芳族化合物和硫化合物的反应物的聚合反应制备，所述方法包括：进一步加入0.01至10.0wt。 相对于聚芳硫醚相对于反应物的重量的二苯基二硫化物的％为二苯醚，以形成熔点为265至320℃的聚芳硫醚。根据本发明的反应物中包含的二苯基二硫醚的成本远低于其它常规 聚合抑制剂大大降低生产成本，并且使用二苯基二硫化物制备的聚芳硫醚表现出低碘含量和非常优异的热稳定性。

公开(公告)号：US08859720B2

公开(公告)日：2014-10-14

申请号：US13141822

申请日：2009-12-22

申请人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

IPC分类号： C08G75/14 ,  C08G75/02 ,  C08G75/16

CPC分类号： C08G75/0209 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide, in which the polyarylene sulfide is prepared by a polymerization reaction of reactants including a diiodo aromatic compound and a sulfur compound, the method including: further adding 0.01 to 10.0 wt. % of diphenyl disulfide with respect to the weight of the polyarylene sulfide to the reactants to form the polyarylene sulfide having a melting point of 265 to 320° C.The diphenyl disulfide included in the reactants according to the present invention costs far less than other conventional polymerization inhibitors to dramatically lower the production cost, and the polyarylene sulfide prepared using the diphenyl disulfide exhibits low iodine content and very excellence in thermal stability.

摘要翻译： 本发明涉及一种聚芳硫醚的制备方法，其中聚芳硫醚通过包括二碘芳族化合物和硫化合物的反应物的聚合反应制备，所述方法包括：进一步加入0.01至10.0wt。 相对于聚芳硫醚相对于反应物的重量的二苯基二硫化物的％为二苯醚，以形成熔点为265至320℃的聚芳硫醚。根据本发明的反应物中包含的二苯基二硫醚的成本远低于其它常规 聚合抑制剂大大降低生产成本，并且使用二苯基二硫化物制备的聚芳硫醚表现出低碘含量和非常优异的热稳定性。

公开(公告)号：US09163119B2

公开(公告)日：2015-10-20

申请号：US13142932

申请日：2009-12-28

申请人： Yong-Jun Shin ,  Sung-Gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha

发明人： Yong-Jun Shin ,  Sung-Gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha

IPC分类号： C08G75/14 ,  C08G75/02 ,  C08G75/00

CPC分类号： C08G75/16 ,  C08G75/0213 ,  C08G75/0263 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide with a reduced free iodine content. More specifically, the method for preparing polyarylene sulfide includes: (a) polymerizing reactants including a diiodo aromatic compound and a sulfur compound to form a polyarylene sulfide; and (b) maintaining the polyarylene sulfide product at 100 to 260° C. for heat-setting. The preparation method of the present invention effectively reduces the free iodine content of the polyarylene sulfide to prevent potential corrosion of facilities for the subsequent process and improves the properties of the polyarylene sulfide product such as thermal stability, so the method can be usefully applied to industrial fields in regard to the preparation of polyarylene sulfide.

摘要翻译： 本发明涉及一种具有降低游离碘含量的聚芳硫醚的制备方法。 更具体地说，制备聚芳硫醚的方法包括：（a）使包含二碘芳族化合物和硫化合物的反应物聚合以形成聚芳硫醚; 和（b）将聚芳硫醚产物保持在100-260℃以进行热定型。 本发明的制备方法有效地降低了聚芳硫醚的游离碘含量，以防止随后工艺的设备的潜在腐蚀，提高聚芳硫醚产品的性能，如热稳定性，因此该方法可有效应用于工业 关于制备聚芳硫醚的领域。

公开(公告)号：US20110269935A1

公开(公告)日：2011-11-03

申请号：US13142932

申请日：2009-12-28

申请人： Yong-Jun Shin ,  Sung-gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  II-Hoon Cha

发明人： Yong-Jun Shin ,  Sung-gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  II-Hoon Cha

IPC分类号： C08G75/14

CPC分类号： C08G75/16 ,  C08G75/0213 ,  C08G75/0263 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide with a reduced free iodine content. More specifically, the method for preparing polyarylene sulfide includes: (a) polymerizing reactants including a diiodo aromatic compound and a sulfur compound to form a polyarylene sulfide; and (b) maintaining the polyarylene sulfide product at 100 to 260° C. for heat-setting. The preparation method of the present invention effectively reduces the free iodine content of the polyarylene sulfide to prevent potential corrosion of facilities for the subsequent process and improves the properties of the polyarylene sulfide product such as thermal stability, so the method can be usefully applied to industrial fields in regard to the preparation of polyarylene sulfide.

摘要翻译： 本发明涉及一种具有降低游离碘含量的聚芳硫醚的制备方法。 更具体地说，制备聚芳硫醚的方法包括：（a）使包含二碘芳族化合物和硫化合物的反应物聚合以形成聚芳硫醚; 和（b）将聚芳硫醚产物保持在100-260℃以进行热定型。 本发明的制备方法有效地降低了聚芳硫醚的游离碘含量，以防止随后工艺的设备的潜在腐蚀，提高聚芳硫醚产品的性能，如热稳定性，因此该方法可有效应用于工业 关于制备聚芳硫醚的领域。