公开(公告)号：US20120302726A1

公开(公告)日：2012-11-29

申请号：US13576229

申请日：2011-01-31

申请人： Yong-Jun Shin ,  II-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  II-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

IPC分类号： C08G75/16

CPC分类号： C08G75/14 ,  C08G75/0263

摘要： This disclosure relates to a method for preparing polyarylene sulfide having reduced iodine content while having excellent thermal stability, specifically to a method comprising polymerization reacting a composition comprising diiodide aromatic compounds, sulfur compounds, and a polymerization terminator. The preparation method may effectively reduce iodine content of polyarylene sulfide to prevent corrosion of post processing equipment, improve properties of polyarylene sulfide such as thermal stability, and the like, and thus, it may be usefully applied in the industrial field relating to preparation of polyarylene sulfide.

摘要翻译： 本公开内容涉及一种具有降低碘含量同时具有优异的热稳定性的聚芳硫醚的制备方法，具体涉及使包含二碘化物芳族化合物，硫化合物和聚合终止剂的组合物聚合反应的方法。 制备方法可以有效降低聚芳硫醚的碘含量，防止后处理设备的腐蚀，改善聚芳硫醚的热稳定性等，从而可用于与聚亚芳基的制备有关的工业领域 硫化物。

公开(公告)号：US08492502B2

公开(公告)日：2013-07-23

申请号：US12518243

申请日：2008-01-04

申请人： Young-Rok Lee ,  II-Hoon Cha ,  Jun-Sang Cho

发明人： Young-Rok Lee ,  II-Hoon Cha ,  Jun-Sang Cho

IPC分类号： C08G75/00

CPC分类号： C08G75/0263 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0281 ,  C08L81/02 ,  C08L81/00

摘要： The present invention relates to a process of producing polyarylene sulfide (PAS) and PAS resin produced therefrom, and more specifically, to a process of preparing polyarylene sulfide with better thermal properties and luminosity than conventional PAS and the PAS resin produced therefrom, including the steps of: a) melting and mixing a composition including solid sulfur, iodinated aryl compounds, and a polymerization terminator; b) polymerizing the molten mixture of step a) for 1 to 30 hours while increasing the temperature and decreasing the pressure from initial reaction conditions of a temperature of 180 to 250° C. and a pressure of 50 to 450 Torr to final reaction conditions of a temperature of 270 to 350° C. and a pressure of 0.001 to 20 Torr; and c) heating the reaction product of step b) at a temperature of 270 to 350° C. for 1 to 25 hours. The process of polyarylene sulfide resin further includes a step of heating the polymerized product at a high temperature following the polymerization step, and uses the polymerization terminator in a suitable amount to control the molecular weight of polyarylene sulfide, thereby producing polyarylene sulfide with excellent thermal properties and luminosity.

摘要翻译： 本发明涉及一种生产聚芳硫醚（PAS）和由其制备的PAS树脂的方法，更具体地说，涉及制备具有比常规PAS和由其制备的PAS树脂更好的热性能和发光度的聚芳硫醚的方法，包括步骤 a）熔融和混合包括固体硫，碘化芳基化合物和聚合终止剂的组合物; b）使步骤a）的熔融混合物聚合1至30小时，同时增加温度并将温度从180-250℃的初始反应条件和50至450托的压力降低至最终反应条件 温度为270〜350℃，压力为0.001〜20托; 和c）将步骤b）的反应产物在270至350℃的温度下加热1至25小时。 聚芳硫醚树脂的方法还包括在聚合步骤之后在高温下加热聚合产物的步骤，并且使用适当量的聚合终止剂来控制聚芳硫醚的分子量，由此制备具有优异热性质的聚芳硫醚 和亮度。

公开(公告)号：US20100022743A1

公开(公告)日：2010-01-28

申请号：US12518369

申请日：2008-01-04

申请人： Young-Rok Lee ,  Ii-Hoon Cha ,  Yong-Jun Shin ,  Jun-Sang Cho

发明人： Young-Rok Lee ,  Ii-Hoon Cha ,  Yong-Jun Shin ,  Jun-Sang Cho

IPC分类号： C08G75/14

CPC分类号： C08G75/14 ,  C08G75/0209 ,  C08G75/0231 ,  C08G75/0263 ,  C08L81/02 ,  C08L2666/22 ,  C08L81/00

摘要： The present invention relates to a polyarylene sulfide that is prepared from a composition including 100 parts by weight of solid sulfur, 500 to 10,000 parts by weight of iodinated aryl compounds, and 0.03 to 30 parts by weight of a sulfur-containing polymerization terminator with respect to 100 parts by weight of the solid sulfur, and has a melting temperature (Tm) of 255 to 285° C., and luminosity of 40 or higher as defined by the CIE Lab color model, and a process of preparing the same. The PAS resin is prepared from a composition including a sulfur-containing polymerization terminator and thus has excellent thermal properties and luminosity.

摘要翻译： 本发明涉及一种聚芳硫醚，其由包含100重量份固体硫，500至10,000重量份碘化芳基化合物和0.03至30重量份含硫聚合终止剂的组合物制备，相对于 至100重量份固体硫，并且具有255至285℃的熔融温度（Tm）和由CIE Lab颜色模型所定义的40或更高的亮度及其制备方法。 PAS树脂由包含含硫聚合终止剂的组合物制备，因此具有优异的热性能和亮度。

公开(公告)号：US20110269935A1

公开(公告)日：2011-11-03

申请号：US13142932

申请日：2009-12-28

申请人： Yong-Jun Shin ,  Sung-gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  II-Hoon Cha

发明人： Yong-Jun Shin ,  Sung-gi Kim ,  Jae-Bong Lim ,  Joon-Sang Cho ,  II-Hoon Cha

IPC分类号： C08G75/14

CPC分类号： C08G75/16 ,  C08G75/0213 ,  C08G75/0263 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide with a reduced free iodine content. More specifically, the method for preparing polyarylene sulfide includes: (a) polymerizing reactants including a diiodo aromatic compound and a sulfur compound to form a polyarylene sulfide; and (b) maintaining the polyarylene sulfide product at 100 to 260° C. for heat-setting. The preparation method of the present invention effectively reduces the free iodine content of the polyarylene sulfide to prevent potential corrosion of facilities for the subsequent process and improves the properties of the polyarylene sulfide product such as thermal stability, so the method can be usefully applied to industrial fields in regard to the preparation of polyarylene sulfide.

摘要翻译： 本发明涉及一种具有降低游离碘含量的聚芳硫醚的制备方法。 更具体地说，制备聚芳硫醚的方法包括：（a）使包含二碘芳族化合物和硫化合物的反应物聚合以形成聚芳硫醚; 和（b）将聚芳硫醚产物保持在100-260℃以进行热定型。 本发明的制备方法有效地降低了聚芳硫醚的游离碘含量，以防止随后工艺的设备的潜在腐蚀，提高聚芳硫醚产品的性能，如热稳定性，因此该方法可有效应用于工业 关于制备聚芳硫醚的领域。

公开(公告)号：US20120329983A1

公开(公告)日：2012-12-27

申请号：US13582868

申请日：2011-03-08

申请人： Sung-Gi Kim ,  Jae-Bong Lim ,  II-Hoon Cha

发明人： Sung-Gi Kim ,  Jae-Bong Lim ,  II-Hoon Cha

IPC分类号： C08G75/16 ,  B29C45/72

CPC分类号： C08G75/02 ,  C08G75/14 ,  C08J5/18 ,  C08J2381/04

摘要： This disclosure relates to polyarylene sulfide that may exhibit excellent processability at low temperature, decrease outgassing and flash or burr generation, and thus may satisfactorily mold a product requiring high molding accuracy, and a method for preparing the same. Specifically, the polyarylene sulfide includes an arylene sulfide repeat unit and an arylene disulfide repeat unit, wherein the weight ratio of the arylene sulfide repeat unit:arylene disulfide repeat unit is 1:0.0001 to 1:0.05.

摘要翻译： 本公开内容涉及在低温下表现出优异的加工性，减少脱气和闪光或毛刺产生的聚芳硫醚，因此可以令人满意地模制需要高成型精度的产品及其制备方法。 具体地，聚芳硫醚包括亚芳基硫醚重复单元和亚芳基二硫化物重复单元，其中亚芳基硫醚重复单元：亚芳基二硫化物重复单元的重量比为1:0.1:1至1:1,0.05。