公开(公告)号：US09324950B2

公开(公告)日：2016-04-26

申请号：US13302063

申请日：2011-11-22

申请人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

发明人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

IPC分类号： H01L51/54 ,  H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0072 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1022 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0051 ,  H01L51/0054 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5004 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5056 ,  H01L51/5092 ,  H01L51/5096

摘要： An organic electroluminescence device that includes an anode, an emitting layer that includes a host and a fluorescent dopant, an electron transporting zone, a cathode, a blocking layer adjacent to the emitting layer in the electron transporting zone where the blocking layer includes an aromatic heterocyclic derivative with an azine ring and where the triplet energy ETb (eV) of the aromatic heterocyclic derivative is larger than a triplet energy ETh (eV) of the host.

摘要翻译： 一种有机电致发光器件，其包括阳极，包括主体和荧光掺杂剂的发光层，电子传输区，阴极，与电子传输区中发光层相邻的阻挡层，其中阻挡层包含芳族杂环 衍生物，其中芳族杂环衍生物的三重态能量ETb（eV）大于主体的三重态能量ETh（eV）。

公开(公告)号：US08803420B2

公开(公告)日：2014-08-12

申请号：US13388389

申请日：2011-01-14

申请人： Yuichiro Kawamura ,  Masahiro Kawamura ,  Hitoshi Kuma ,  Hirokatsu Ito

发明人： Yuichiro Kawamura ,  Masahiro Kawamura ,  Hitoshi Kuma ,  Hirokatsu Ito

IPC分类号： H01L51/54

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/5004 ,  H01L51/5012 ,  H01L51/5072 ,  H05B33/14

摘要： An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “ETb>ETh” (where, ETh is the triplet energy of the host material, and ETb is the triplet energy of the barrier material).

摘要翻译： 有机电致发光器件包括阳极，发光层，电子传输区域和阴极，阳极，发光层，电子传输区域和阴极依次层叠，发光层包括主体 材料和发射具有550nm以下的主峰波长的荧光的掺杂剂材料，所述电子传输区域包括与发光层相邻的阻挡层，并且所述阻挡层包括阻挡材料，所述阻挡材料包括电子发射层， 输送结构部分和包含稠合多环芳烃化合物的三重态势垒结构部分，并且满足关系“ETb> ETh”（其中ETh是主体材料的三线态能量，ETb是势垒的三线态能量 材料）。

公开(公告)号：US08883323B2

公开(公告)日：2014-11-11

申请号：US13302205

申请日：2011-11-22

申请人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

发明人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

IPC分类号： H01L51/54 ,  H01L51/50 ,  H01L51/00

CPC分类号： H01L51/5096 ,  H01L51/0072 ,  H01L51/0073 ,  H01L2251/55 ,  Y10S428/917

摘要： An organic electroluminescence device that includes an anode, an emitting layer that includes a host and a dopant, a blocking layer, an electron injecting layer, and a cathode where the blocking layer includes an aromatic heterocyclic derivative, the triplet energy ETb (eV) of the blocking layer is larger than a triplet energy ETh (eV) of the host, and the affinity Ab (eV) of the blocking layer and an affinity Ae (eV) of the electron injecting layer satisfy a relationship of Ae−Ab

摘要翻译： 一种有机电致发光器件，其包括阳极，包括主体和掺杂剂的发光层，阻挡层，电子注入层和阴极，其中阻挡层包含芳族杂环衍生物，三重态能量ETb（eV） 阻挡层大于主体的三线态能量ETh（eV），并且阻挡层的亲和力Ab（eV）和电子注入层的亲和力Ae（eV）满足Ae-Ab <0.2的关系。

公开(公告)号：US20120126209A1

公开(公告)日：2012-05-24

申请号：US13302205

申请日：2011-11-22

申请人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

发明人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

IPC分类号： H01L51/54

CPC分类号： H01L51/5096 ,  H01L51/0072 ,  H01L51/0073 ,  H01L2251/55 ,  Y10S428/917

摘要： An organic electroluminescence device that includes an anode, an emitting layer that includes a host and a dopant, a blocking layer, an electron injecting layer, and a cathode where the blocking layer includes an aromatic heterocyclic derivative, the triplet energy ETb (eV) of the blocking layer is larger than a triplet energy ETh (eV) of the host, and the affinity Ab (eV) of the blocking layer and an affinity Ae (eV) of the electron injecting layer satisfy a relationship of Ae−−Ab

摘要翻译： 一种有机电致发光器件，其包括阳极，包括主体和掺杂剂的发光层，阻挡层，电子注入层和阴极，其中阻挡层包含芳族杂环衍生物，三重态能量ETb（eV） 阻挡层大于主体的三线态能量ETh（eV），并且阻挡层的亲和力Ab（eV）和电子注入层的亲和力Ae（eV）满足Ae-Ab <0.2的关系 。

公开(公告)号：US20120126205A1

公开(公告)日：2012-05-24

申请号：US13017978

申请日：2011-01-31

申请人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito

发明人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito

IPC分类号： H01L51/52 ,  H01L51/54

CPC分类号： H01L51/5096 ,  H01L51/0055 ,  H01L51/0058 ,  H01L51/0072 ,  H01L51/5004 ,  H01L51/5012 ,  H01L51/504 ,  H01L51/5076

摘要： An organic electroluminescence device includes an anode, an emitting layer, a blocking layer, an electron injecting layer, and a cathode in sequential order. The emitting layer includes a host and dopant. The blocking layer includes an aromatic heterocyclic derivative. A triplet energy ETb (eV) of the blocking layer is larger than a triplet energy ETh (eV) of the host. An affinity Ab (eV) of the blocking layer and an affinity Ab (eV) of the electron injecting layer satisfy a relationship of Ae−Ab

摘要翻译： 有机电致发光器件依次包括阳极，发光层，阻挡层，电子注入层和阴极。 发光层包括主体和掺杂剂。 阻挡层包括芳族杂环衍生物。 阻挡层的三重态能量ETb（eV）大于主体的三线态能量ETh（eV）。 阻挡层的亲和力Ab（eV）和电子注入层的亲和力Ab（eV）满足Ae-Ab <0.2的关系。

公开(公告)号：US20120153268A1

公开(公告)日：2012-06-21

申请号：US13388389

申请日：2011-01-14

申请人： Yuichiro Kawamura ,  Masahiro Kawamura ,  Hitoshi Kuma ,  Hirokatsu Ito

发明人： Yuichiro Kawamura ,  Masahiro Kawamura ,  Hitoshi Kuma ,  Hirokatsu Ito

IPC分类号： H01L51/54

CPC分类号： C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  H01L51/0054 ,  H01L51/0055 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/5004 ,  H01L51/5012 ,  H01L51/5072 ,  H05B33/14

摘要： An organic electroluminescence device includes an anode, an emitting layer, an electron-transporting region, and a cathode, the anode, the emitting layer, the electron-transporting region, and the cathode being stacked in this order, the emitting layer including a host material, and a dopant material that emits fluorescence having a main peak wavelength of 550 nm or less, the electron-transporting region including a barrier layer that is adjacent to the emitting layer, and the barrier layer including a barrier material that includes an electron-transporting structural part, and a triplet barrier structural part that includes a fused polycyclic aromatic hydrocarbon compound, and satisfies the relationship “ETb>ETh” (where, ETh is the triplet energy of the host material, and ETb is the triplet energy of the barrier material).

摘要翻译： 有机电致发光器件包括阳极，发光层，电子传输区域和阴极，阳极，发光层，电子传输区域和阴极依次层叠，发光层包括主体 材料和发射具有550nm以下的主峰波长的荧光的掺杂剂材料，所述电子传输区域包括与发光层相邻的阻挡层，并且所述阻挡层包括阻挡材料，所述阻挡材料包括电子发射层， 输送结构部分和包含稠合多环芳烃化合物的三重态势垒结构部分，并且满足关系“ETb> ETh”（其中ETh是主体材料的三线态能量，ETb是势垒的三线态能量 材料）。

公开(公告)号：US20120126208A1

公开(公告)日：2012-05-24

申请号：US13302063

申请日：2011-11-22

申请人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

发明人： Yuichiro Kawamura ,  Hiroyuki Saito ,  Hitoshi Kuma ,  Masahiro Kawamura ,  Yukitoshi Jinde ,  Hirokatsu Ito ,  Takayasu Sado ,  Sayaka Mizutani

IPC分类号： H01L51/54

CPC分类号： H01L51/0072 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1022 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0051 ,  H01L51/0054 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/5004 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5056 ,  H01L51/5092 ,  H01L51/5096

摘要： An organic electroluminescence device that includes an anode, an emitting layer that includes a host and a fluorescent dopant, an electron transporting zone, a cathode, a blocking layer adjacent to the emitting layer in the electron transporting zone where the blocking layer includes an aromatic heterocyclic derivative with an azine ring and where the triplet energy ETb (eV) of the aromatic heterocyclic derivative is larger than a triplet energy ETh (eV) of the host.

摘要翻译： 一种有机电致发光器件，其包括阳极，包括主体和荧光掺杂剂的发光层，电子传输区，阴极，与电子传输区中的发光层相邻的阻挡层，其中阻挡层包含芳族杂环 衍生物，其中芳族杂环衍生物的三重态能量ETb（eV）大于主体的三重态能量ETh（eV）。

公开(公告)号：US09269907B2

公开(公告)日：2016-02-23

申请号：US13389514

申请日：2011-10-24

申请人： Yumiko Mizuki ,  Hiroyuki Saito ,  Yuichiro Kawamura ,  Hirokatsu Ito ,  Masahiro Kawamura

发明人： Yumiko Mizuki ,  Hiroyuki Saito ,  Yuichiro Kawamura ,  Hirokatsu Ito ,  Masahiro Kawamura

IPC分类号： H01L51/50 ,  H01L51/00 ,  C07C255/58 ,  C07D213/74 ,  C07F7/08 ,  C09K11/06 ,  H05B33/14

CPC分类号： H01L51/0067 ,  C07C255/58 ,  C07C2601/08 ,  C07C2603/18 ,  C07D213/74 ,  C07F7/081 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1088 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0094 ,  H01L51/5012 ,  H05B33/14

摘要： A compound is shown by the following formula (1). wherein l, m, and n are independently an integer from 1 to 3, Ar1 to Ar4 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms, Ar5, Ar6, and Ar7 are independently a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 30 ring atoms, and p is an integer from 0 to 2, and Ar6 and N are bonded via a single bond when p is 0, provided that at least one of Ar1 to Ar4 is substituted with a substituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and at least one of Ar1 to Ar4 is substituted with a cyano group.

摘要翻译： 化合物由下式（1）表示。 其中l，m和n独立地为1至3的整数，Ar 1至Ar 4独立地为取代或未取代的环碳原子数为6至30的芳基或取代或未取代的环原子数为5至30的杂芳基，Ar 5 Ar 6和Ar 7独立地为取代或未取代的碳原子数为6〜30的亚芳基或取代或未取代的环原子数为5〜30的亚杂芳基，p为0〜2的整数，Ar 6和N为 当p为0时，通过单键键合，条件是Ar 1〜Ar 4中的至少一个被取代的甲硅烷基，取代或未取代的碳原子数1〜20的烷基或取代或未取代的环烷基取代， 10个碳原子，并且Ar 1〜Ar 4中的至少一个被氰基取代。

公开(公告)号：US09353027B2

公开(公告)日：2016-05-31

申请号：US13499303

申请日：2010-12-20

申请人： Masahiro Kawamura ,  Yuichiro Kawamura ,  Yumiko Mizuki ,  Hiroyuki Saito ,  Hirokatsu Ito

发明人： Masahiro Kawamura ,  Yuichiro Kawamura ,  Yumiko Mizuki ,  Hiroyuki Saito ,  Hirokatsu Ito

IPC分类号： H01L51/54 ,  C07C15/38 ,  H01L51/00 ,  C09K11/06 ,  H05B33/10 ,  H01L51/50

CPC分类号： C07C15/38 ,  C07C2603/50 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/0054 ,  H01L51/5012 ,  H05B33/10

摘要： An organic electroluminescence device includes a pair of electrodes and an organic compound layer therebetween. The organic compound layer includes an emitting layer. The emitting layer includes a pyrene derivative represented by formula (1), such that a content of the pyrene derivative in the emitting layer is 50 to 100 wt %. Ar1 and Ar2 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms. X1 and X3 to X8 are a hydrogen atom. X2 is a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, provided that Ar1 or Ar2 is different from X2. In a case where any of Ar1, Ar2, and X2 is the aryl group having a substituent, the substituent is independently an alkyl group, a cycloalkyl group, an aryl group, a silyl group, or a cyano group.

摘要翻译： 有机电致发光器件包括一对电极和它们之间的有机化合物层。 有机化合物层包括发光层。 发光层包括由式（1）表示的芘衍生物，使得发光层中芘衍生物的含量为50〜100重量％。 Ar 1和Ar 2独立地为取代或未取代的环碳原子数为6〜30的芳基。 X1和X3至X8是氢原子。 X2是取代或未取代的环碳原子数为6〜30的芳基，条件是Ar1或Ar2不同于X2。 在Ar 1，Ar 2和X 2中的任一个为具有取代基的芳基的情况下，取代基独立地为烷基，环烷基，芳基，甲硅烷基或氰基。

公开(公告)号：US20130221331A1

公开(公告)日：2013-08-29

申请号：US13389514

申请日：2011-10-24

申请人： Yumiko Mizuki ,  Hiroyuki Saito ,  Yuichiro Kawamura ,  Hirokatsu Ito ,  Masahiro Kawamura

发明人： Yumiko Mizuki ,  Hiroyuki Saito ,  Yuichiro Kawamura ,  Hirokatsu Ito ,  Masahiro Kawamura

IPC分类号： H01L51/00

CPC分类号： H01L51/0067 ,  C07C255/58 ,  C07C2601/08 ,  C07C2603/18 ,  C07D213/74 ,  C07F7/081 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1088 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0094 ,  H01L51/5012 ,  H05B33/14

摘要： A compound is shown by the following formula (1). wherein l, m, and n are independently an integer from 1 to 3, Ar1 to Ar4 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms, Ar5, Ar6, and Ar7 are independently a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 30 ring atoms, and p is an integer from 0 to 2, and Ar6 and N are bonded via a single bond when p is 0, provided that at least one of Ar1 to Ar4 is substituted with a substituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and at least one of Ar1 to Ar4 is substituted with a cyano group.

摘要翻译： 化合物由下式（1）表示。 其中l，m和n独立地为1至3的整数，Ar 1至Ar 4独立地为取代或未取代的环碳原子数为6至30的芳基或取代或未取代的环原子数为5至30的杂芳基，Ar 5 Ar 6和Ar 7独立地为取代或未取代的碳原子数为6〜30的亚芳基或取代或未取代的环原子数为5〜30的亚杂芳基，p为0〜2的整数，Ar 6和N为 当p为0时，通过单键键合，条件是Ar 1〜Ar 4中的至少一个被取代的甲硅烷基，取代或未取代的碳原子数1〜20的烷基或取代或未取代的环烷基取代， 10个碳原子，并且Ar 1〜Ar 4中的至少一个被氰基取代。