摘要:
The present invention provides a magnetic recording medium having high durability and excellent electromagnetic transfer characteristics and having a lower coating layer, which contains a binder and has high dispersion property and durability. The magnetic recording medium comprises a lower coating layer where non-magnetic powder or ferromagnetic power is dispersed in a binder and an upper magnetic layer where ferromagnetic powder is dispersed in a binder, said two layers being placed on a non-magnetic support member, whereby the binder of the lower coating layer comprises polyurethane resin, which is a reaction product using diol and organic diisocyanate as major materials, the polyurethane resin contains short-chain diol having cyclic structure by 17 to 40 weight %, and the polyurethane resin contains long-chain diol, containing ether groups by 1.0 to 5.0 mmol/g to the entire polyurethane resin, by 10 to 50 weight %.
摘要:
The present invention provides a magnetic recording medium having high dispersion property, good running durability and good preservation property, and it comprises at least one magnetic layer having ferromagnetic powder dispersed by a binder placed on a non-magnetic support member, whereby a polyurethane resin or a polyurethane urea resin consisting of 5 mol % or less of a long chain diol having weight average molecular weight of 800 to 5,000, a short chain diol having weight average molecular weight of 50 to 500 and/or a short chain diamine and an organic diisocyanate is contained as the binder, said long chain diol has one polar group selected from —COOM, —SO3M, —OSO3M, —OPO(OM)2, or —PO(OM)2 (where M represents a hydrogen atom, an alkali metal ion, or an ammonium ion) in the molecule, and the polar group is contained in the polyurethane by 1 to 5 mol %.
摘要:
A binder for a magnetic recording medium which contains a polyvinyl alkylal resin modified by a sultone to introduce thereinto an atom group containing a polar group. Also disclosed is a magnetic recording medium that uses the above-described binder in a magnetic layer, a non-magnetic layer, a protective layer, an undercoat layer, etc. The binder and the magnetic recording medium are superior in dispersibility and exhibit high magnetic coating strength.
摘要:
The invention relates to a binder which improves the dispersibility of ferromagnetic powders and makes it possible to achieve a magnetic recording medium excellent in operation durability and storability, and a magnetic recording medium using such a binder. The invention provides a magnetic recording medium including a non-magnetic support substrate and a magnetic layer formed on said support substrate, said magnetic layer comprising a dispersion of ferromagnetic fine powders in a binder, wherein said binder comprises a polyurethane resin that is a reaction product obtained by using a polyol and an organic diisocyanate as main starting materials, said polyurethane resin containing as components of said polyol 15 to 40% by weight of a short-chain diol component having a cyclic structure, and 10 to 50% by weight of a long-chain polyether polyol component, and further including a polar group-containing long-chain polyol component having a molecular weight of 500 to 5,000.
摘要:
A binder for a magnetic recording medium comprising a polyurethane which is a reaction product obtained from a polyol and a polyisocyanate as principal raw materials. The polyol is an aliphatic polyol with a molecular weight of not lower than 500. The binder has high dispersibility and provides excellent running durability and shelf stability. Also disclosed is a magnetic recording medium having at least one magnetic or non-magnetic layer containing the above-described binder on at least one surface of a non-magnetic support.
摘要:
In a binder for a magnetic recording medium for forming a magnetic layer with ferromagnetic powder dispersed therein being arranged on a non-magnetic support member, whereby said binder consists of a polyurethane resin, which is a reaction product of diol and organic diisocyanate as principal materials, said polyurethane resin contains a short-chain diol having cyclic structure by 17 to 40 weight %, and said polyurethane resin contains a long-chain diol comprising 1.0 to 5.0 mmol/g of ether group to total urethane resin by 10 to 50 weight %. According to a binder for a magnetic recording medium and a magnetic recording medium using said binder of the present invention, good dispersion property, high running durability and preservation property can be obtained.
摘要:
A magnetic recording medium having a ferromagnetic metal thin film on at least one surface of a non-magnetic support. The magnetic recording medium has a surface layer containing at least either one of fluorine compounds represented by the following formulae (1) and (2):Rf-R.sub.1 Formula (1)Rf-R.sub.2 -Rf Formula (2)whereRf: (CF.sub.3).sub.a CF.sub.3-a (CF.sub.2).sub.ba: 1 to 3a+b: 1 to 11R.sub.1 : an alkyl or alkenyl group having from 8 to 26 carbon atomsR.sub.2 : an alkylene or alkenylene group having from 2 to 14 carbon atoms.The surface layer may be formed on a carbon film provided on the ferromagnetic metal thin film. The surface layer may further contain a fluorine compound having at least one polar group and a perfluoroalkyl group, and a rust inhibitor. These components may be contained in or coated on a back coat layer. The magnetic recording medium is excellent in running properties, durability and shelf stability.
摘要:
A magnetic recording medium comprising a nonmagnetic support having on at least one side thereof a magnetic layer comprising a ferromagnetic particle and a binder, wherein the binder comprises a polyvinyl acetal resin having a polar group and a polyurethane resin having a polar group; and a magnetic recording medium comprising (a) a nonmagnetic support having on at least one side thereof at least one of a lower magnetic layer comprising a ferromagnetic particle and a binder and a nonmagnetic layer comprising a nonmagnetic particle and a binder and (b) an upper magnetic layer comprising a ferromagnetic particle and a binder provided thereon, wherein at least the binder contained in the upper magnetic layer comprises a polyvinyl acetal resin having a polar group and a polyurethane resin having a polar group.
摘要:
A magnetic recording medium, comprising a magnetic layer having ferromagnetic metallic thin film at least on one side of a non-magnetic support, whereby a layer is formed on the magnetic layer, said layer contains at least one type of fluorine compounds having at least two perfluoroalkyl groups given by the following general formula (1) or (2) and one or more polar groups selected from --OH, --COOM, --SO.sub.3 M, --OSO.sub.3 M, --PO.sub.3 M.sub.2 or --OPO.sub.3 M.sub.2 (M representing hydrogen atom, alkali metal or ammonium):General formula (1)CF.sub.3 CF.sub.2 (CF.sub.2).sub.n (CH.sub.2)--.sub.mGeneral formula (2)(CF.sub.3).sub.2 CF(CF.sub.2).sub.n (CH.sub.2)--.sub.mwhere n is a number of 2 to 10, m is a number of 1 to 18, and n+m are an integer of 6 to 26.
摘要:
A magnetic recording medium having a magnetic layer on a non-magnetic support, whereby an organic fluorine compound given by the following general formulae (1) or (2) is formed on said magnetic layer: ##STR1## where Rf.sup.1, Rf.sup.2 and Rf.sup.3 each represents a fluoroalkyl group, Y.sup.1, Y.sup.2 and Y.sup.3 each represents --O--, --OCO--, --COO, --NHCO--, or --CONH--and may be the same or different;R.sup.1 represents .dbd.CH.sub.2, .dbd.CH(CH.sub.2).sub.k CH.sub.3, or .dbd.CHCH.dbd.CH.sub.2, and k is a number from 0 to 2;R.sup.2 and R.sup.5 each represents H, and R.sup.2 is not present in case the carbon to which R.sup.2 is bonded has double bond.R.sup.3, R.sup.4 or R.sup.6 each represents H or a hydrocarbon group, which may have double bond.A, B and X each represents (CH.sub.2).sub.k, and k is a number from 0 to 2, and b is a number of 0 or one or higher.Rf.sup.1, Rf.sup.2, Rf.sup.3, Y.sup.1, Y.sup.2, Y.sup.3, A, B, X, R.sup.4, R.sup.5, R.sup.6, k, n, and m may be the same or different, and these may be cis type or trans type.