公开(公告)号：US20070197758A1

公开(公告)日：2007-08-23

申请号：US11657108

申请日：2007-01-24

申请人： Yuii Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

发明人： Yuii Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

IPC分类号： C08G77/24 ,  B32B9/04

CPC分类号： C09D183/12 ,  C08G65/007 ,  C08G77/48 ,  Y10T428/31663

摘要： A fluorine-containing organopolysiloxane represented by the following average compositional formula (1) (Z2Q)βRf(QZ1Aα)2-β  (1) wherein Rf is a divalent group containing a perfluoroether residue, Q is a divalent organic group, Z1 is a di- to nona-valent organopolysiloxane residue and may contain a silalkylene bond, α is an integer of from 1 to 8, β is a number larger than 0 and smaller than 2, Z2 is a monovalent group represented by the following formula (2) wherein b is an integer of from 1 to 10, R1 may be the same with and different from each other and is an alkyl group having 1 to 4 carbon atoms or a phenyl group, and A is a monovalent group represented by the following formula (3) wherein R2 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, a is 2 or 3, and c is an integer of from 1 to 6.

摘要翻译： 由以下平均组成式（1）表示的含氟有机聚硅氧烷<？in-line-formula description =“In-line formula”end =“lead”→>（Z < β（β-β）β（β-β）2-β（1）<β在线公式描述= “直列式”末端=“尾”→其中，Rf是含有全氟醚残基的二价基团，Q是二价有机基团，Z 1是二至少价的有机聚硅氧烷残基 并且可以含有亚硅烷基键，α为1〜8的整数，β为大于0且小于2的数，Z 2是由下式（2）表示的一价基团， 其中b为1〜10的整数，R 1可以相同也可以不同，为碳原子数为1〜4的烷基或苯基，A为 由下式（3）表示的一价基团，其中R 2是具有1至4个碳原子的烷基或ph 烯基，X为水解性基团，a为2或3，c为1〜6的整数。

公开(公告)号：US07601428B2

公开(公告)日：2009-10-13

申请号：US11657108

申请日：2007-01-24

申请人： Yuii Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

发明人： Yuii Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

IPC分类号： B32B9/04 ,  C08G77/46

CPC分类号： C09D183/12 ,  C08G65/007 ,  C08G77/48 ,  Y10T428/31663

摘要： A fluorine-containing organopolysiloxane represented by the following average compositional formula (1) (Z2Q)βRf(QZ1Aα)2−β  (1) wherein Rf is a divalent group containing a perfluoroether residue, Q is a divalent organic group, Z1 is a di- to nona-valent organopolysiloxane residue and may contain a silalkylene bond, α is an integer of from 1 to 8, β is a number larger than 0 and smaller than 2, Z2 is a monovalent group represented by the following formula (2) wherein b is an integer of from 1 to 10, R1 may be the same with and different from each other and is an alkyl group having 1 to 4 carbon atoms or a phenyl group, and A is a monovalent group represented by the following formula (3) wherein R2 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, a is 2 or 3, and c is an integer of from 1 to 6.

摘要翻译： 由以下平均组成式（1）（Z2Q）βRf（QZ1Aalpha）2-β（1）表示的含氟有机聚硅氧烷，其中Rf是含有全氟醚残基的二价基团，Q是二价有机基团，Z1是二 - 至少有机聚硅氧烷残基并且可以含有亚烷基键，α是1至8的整数，β是大于0且小于2的数，Z2是由下式（2）表示的一价基团，其中 b为1〜10的整数，R 1可以相同也可以不同，为碳原子数为1〜4的烷基或苯基，A为下述式（3）表示的一价基团 ）其中R2是具有1至4个碳原子的烷基或苯基，X是可水解基团，a是2或3，c是1至6的整数。

公开(公告)号：US20070149746A1

公开(公告)日：2007-06-28

申请号：US11643988

申请日：2006-12-22

申请人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

发明人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

IPC分类号： C08G77/24

CPC分类号： C08G77/385 ,  C07F7/21 ,  C08G77/50 ,  Y10T428/31663

摘要： An organopolysiloxane represented by the following general formula (A), (B) or (C) SinR12n+2On−1  (A) SinR12nOn  (B) SinR12n+2R2kOn−k  (C) wherein R1 may be the same with or different from each other and is a hydrogen atom or a monovalent organic group, R2 is an alkylene group having 2 to 6 carbon atoms, n is an integer of from 2 to 40 and k is an integer of 1 to 3, characterized in that at least two R1's are represented by the following formula (i): wherein X is a hydrolyzable group, R3 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5 and a is 2 or 3; and one SiR1 bond is represented by the following formula (ii) or one SiOSi bond is replaced with a bond represented by the following formula (iii): SiQRf1  (ii) SiQRf2QSi  (iii) wherein Rf1 is a monovalent group containing a perfluoroether residue, Rf is a divalent group containing a perfluoroether residue, and Q is a divalent organic group.

公开(公告)号：US08022161B2

公开(公告)日：2011-09-20

申请号：US11898013

申请日：2007-09-07

申请人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

发明人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

IPC分类号： C08G77/46

CPC分类号： C08G77/46 ,  C08G65/007 ,  C08L71/02 ,  C08L2205/05 ,  C08L83/00

摘要： A perfluoropolyether-polyorganosiloxane copolymer comprising at least one perfluoropolyether block, at least one polyorganosiloxane block which may has a silalkylene group, and two monovalent groups represented by the following formula (1), each one at both ends of the copolymer, wherein X is a hydrolyzable group, R1 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5, and a is an integer of 2 or 3, said copolymer having a number average molecular weight, reduced to polystyrene, of from 7,000 to 25,000.

摘要翻译： 包含至少一个全氟聚醚嵌段，至少一个可具有亚硅烷基的聚有机硅氧烷嵌段和由下式（1）表示的两个一价基团的全氟聚醚 - 聚有机硅氧烷共聚物，其中X是一个 可水解基团，R 1为具有1〜4个碳原子的烷基或苯基，y为1〜5的整数，a为2或3的整数，所述共聚物的数均分子量为 聚苯乙烯，从7000到25,000。

公开(公告)号：US08420763B2

公开(公告)日：2013-04-16

申请号：US12911890

申请日：2010-10-26

申请人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

发明人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

IPC分类号： C08G77/24

CPC分类号： G02B1/14 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C08L71/02 ,  C09D5/165 ,  C09D171/02 ,  G02B1/105 ,  G02B27/0006 ,  C08L2666/22

摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.

摘要翻译： 本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性， 良好的耐污染性，并提供包含该表面处理剂的表面处理剂。 本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

公开(公告)号：US08362186B2

公开(公告)日：2013-01-29

申请号：US12167873

申请日：2008-07-03

申请人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

发明人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

IPC分类号： C08G77/24

CPC分类号： C08L83/12 ,  C09D183/12 ,  Y10T428/31663

摘要： A coating composition comprising a fluorine-containing silicon compound represented by the following formula (1) wherein Z is a linear or branched divalent polyorganosiloxane residue having 1 to 40 siloxane units, R is an alkyl group having 1 to 4 carbon atoms or a phenyl group, X is a hydrolyzable group, Q is a C2-12 divalent connecting group, a is an integer of 2 or 3, b is an integer of from 1 to 10, y is an integer of 1 to 5, and Rf is a group represented by the following formula (2) -Rf1-(Q-W-Q-Rf1)q-  (2) wherein Rf1 is a perfluoropolyether residue, W is an organopolysiloxane residue having 1 to 40 siloxane units and Q is as defined above and may be the same with or different from each other, and q is an integer of from 0 to 3, and at least one solvent selected from the group consisting of alcohols, esters, ethers, ketones, and perfluoroethers. The coating prepared from the composition is oil-repellent, water-repellent and has water sliding property.

摘要翻译： 一种涂料组合物，其包含由下式（1）表示的含氟硅化合物，其中Z为具有1至40个硅氧烷单元的直链或支链二价聚有机硅氧烷残基，R为具有1至4个碳原子的烷基或苯基 X为水解性基团，Q为C2-12二价连接基团，a为2或3的整数，b为1〜10的整数，y为1〜5的整数，Rf为基团 由下式（2）-Rf1-（QWQ-Rf1）q-（2）表示，其中Rf1是全氟聚醚残基，W是具有1至40个硅氧烷单元的有机聚硅氧烷残基，Q如上定义并且可以相同 q为0〜3的整数，以及选自醇，酯，醚，酮，全氟醚中的至少一种溶剂。 由该组合物制备的涂料具有防油，防水，具有水滑动性。

公开(公告)号：US20110098402A1

公开(公告)日：2011-04-28

申请号：US12911890

申请日：2010-10-26

申请人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

发明人： Yuji Yamane ,  Noriyuki Koike ,  Hirofumi Kishita ,  Koichi Yamaguchi

IPC分类号： C09D127/12

CPC分类号： G02B1/14 ,  C08G65/007 ,  C08G65/336 ,  C08G2650/48 ,  C08L71/02 ,  C09D5/165 ,  C09D171/02 ,  G02B1/105 ,  G02B27/0006 ,  C08L2666/22

摘要： An object of the present invention is to provide a fluorooxyalkylene group-containing polymer composition, which yields a coating having excellent adhesior to a substrate, good water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance and good stain resistance, and to provide a surface treatment agent comprising the same. The present inventors have found that a composition comprising a fluorooxyalkylene group-containing polymer having a fluorinated group and a hydrolyzable group at each terminal and a fluorooxyalkylene group-containing polymer having hydrolyzable groups at both terminals can form a coating which has excellent water- and oil-repellency, a low dynamic friction coefficient, good releasing property, good abrasion resistance, and good stain resistance.

摘要翻译： 本发明的目的是提供一种含有氧代烯烃基的聚合物组合物，该组合物产生对基材的粘附性优异的防水拒油性，低动摩擦系数，良好的剥离性，良好的耐磨性， 良好的耐污染性，并提供包含该表面处理剂的表面处理剂。 本发明人已经发现，包含含有含氟氧化烯基的聚合物，每个末端具有氟化基团和可水解基团的组合物和在两端具有可水解基团的含氟氧化烯基的聚合物可以形成具有优异的水和油的涂层 - 动态摩擦系数低，脱模性好，耐磨性好，耐污染性好。

公开(公告)号：US07794843B2

公开(公告)日：2010-09-14

申请号：US11643988

申请日：2006-12-22

申请人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

发明人： Yuji Yamane ,  Noriyuki Koike ,  Koichi Yamaguchi ,  Hirofumi Kishita

IPC分类号： C08G77/46

CPC分类号： C08G77/385 ,  C07F7/21 ,  C08G77/50 ,  Y10T428/31663

摘要： An organopolysiloxane represented by the following general formula (A), (B) or(C) SinR12n+2On−1  (A) SinR12nOn  (B) SinR12n+2R2kOn−k  (C) wherein R1 may be the same with or different from each other and is a hydrogen atom or a monovalent organic group, R2 is an alkylene group having 2 to 6 carbon atoms, n is an integer of from 2 to 40 and k is an integer of 1 to 3, characterized in that at least two R1's are represented by the following formula (i): wherein X is a hydrolyzable group, R3 is an alkyl group having 1 to 4 carbon atoms or a phenyl group, y is an integer of from 1 to 5 and a is 2 or 3; and one SiOSi bond is replaced with a bond represented by the following formula (iii): SiQRf2QSi  (iii) wherein Rf1 is a monovalent group containing a perfluoroether residue, Rf2 is a divalent group containing a perfluoroether residue, and Q is a divalent organic group.

摘要翻译： 由以下通式（A），（B）或（C）表示的有机聚硅氧烷SinR12n + 2On-1（A）SinR12nOn（B）SinR12n + 2R2kOn-k（C）其中R1可以相同或不同 另一个是氢原子或一价有机基团，R 2是具有2至6个碳原子的亚烷基，n是2至40的整数，k是1至3的整数，其特征在于，至少两个R 1的 由下式（i）表示：其中X是可水解基团，R 3是具有1至4个碳原子的烷基或苯基，y是1至5的整数，a是2或3; 并且一个SiOSi键用下式（ⅲ）表示的键代替：SiQRf2QSi（ⅲ）其中Rf1是含有全氟醚残基的一价基团，Rf2是含有全氟醚残基的二价基团，Q是二价有机基团 。

公开(公告)号：US20080114120A1

公开(公告)日：2008-05-15

申请号：US11984175

申请日：2007-11-14

申请人： Noriyuki Koike ,  Yuji Yamane ,  Hirofumi Kishita ,  Koichi Yamaguchi

发明人： Noriyuki Koike ,  Yuji Yamane ,  Hirofumi Kishita ,  Koichi Yamaguchi

IPC分类号： C08L83/00 ,  C08G77/00

CPC分类号： C09D5/165 ,  C08G65/007 ,  C08G2650/48 ,  C08K5/095 ,  C08L2205/05 ,  C09D5/1675 ,  C09D171/02 ,  C09D183/08 ,  C09D183/12 ,  C09D183/14 ,  C08L83/00 ,  C08L2666/32

摘要： A coating composition comprising (A) at least one fluorine-containing organosilicon compound represented by the following formula (1) or (2) and Rf1-QZ1Aα   (1) AαZ1Q-Rf2-(Q-Z2-Q-Rf2)x-QZ1Aα   (2) (B) a fluorine-containing carboxylic acid having a number average molecular weight of from 100 to 10,000 and a fluorine content of at least 25 wt %, wherein an amount of (B) ranges from 0.001 to 10 parts by weight per 100 parts by weight of the component (A). The composition can be cured rapidly even at room temperature to produce water-repellent and antifouling coating.

摘要翻译： 一种涂料组合物，其包含（A）至少一种由下式（1）或（2）表示的含氟有机硅化合物和<？在线式描述=“在线配方”中的“=”lead“ （1）<？in-line-formula description =“In-line Formulas”end =“tail “？> <？in-line-formula description =”In-line Formulas“end =”lead“？> A Z <1> Q-Rf 2 - （QZ 2 -Q-Rf 2）＆lt; x＆gt; -QZ＆lt; 1＆lt; （2）<？in-line-formula description =“In-line Formulas”end =“tail”？>（B）数均分子量为100至10,000的含氟羧酸 和氟含量为至少25重量％，其中（B）的量相对于（A）成分为100重量份为0.001〜10重量份。 组合物即使在室温也可以快速固化，以产生防水和防污涂层。

公开(公告)号：US08900711B2

公开(公告)日：2014-12-02

申请号：US13226987

申请日：2011-09-07

申请人： Yuji Yamane ,  Yasunori Sakano ,  Koichi Yamaguchi ,  Noriyuki Koike ,  Hirofumi Kishita

发明人： Yuji Yamane ,  Yasunori Sakano ,  Koichi Yamaguchi ,  Noriyuki Koike ,  Hirofumi Kishita

IPC分类号： C08L71/00 ,  C08G65/336 ,  C08G65/00 ,  C08G77/24 ,  C08G77/46 ,  C09D171/02

CPC分类号： C08G77/46 ,  C08G65/007 ,  C08G65/336 ,  C08G77/24 ,  C08G2650/48 ,  C09D171/02 ,  Y10T428/3154

摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.

摘要翻译： 含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物 由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％ ，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。