摘要:
A 1H-pyrazolo[1,5-b][1,2,4]triazole magenta coupler having a t-alkyl group at the position-6 and an amido group-substituted phenyl group at the position-2 is disclosed. There is also disclosed a silver halide color photographic material containing the same.
摘要:
A 1H-pyrazolo[1,5-b][1,2,4]triazole magenta coupler having a t-alkyl group at the position-6 and an amido group-substituted phenyl group at the position-2 is disclosed. There is also disclosed a silver halide color photographic material containing the same.
摘要:
The present invention relates to a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, which contains at least one nondiffusible pyrazolo(1,5-b)(1,2,4)triazole magenta coupler represented by the following general formula (I) in at least one of the silver halide emulsion layers in order to acquire high color formability and to produce a dye image excellent in hue: ##STR1## wherein R.sub.1 represents an alkyl group; R.sub.2 and R.sub.3 each represents a hydrogen atom or an alkyl group, provided that both are not a hydrogen atom; R.sub.4 represents an alkyl group, an alkoxy group or a halogen atom; L represents an alkylene group; m represents an integer of 0 to 5; n represents an integer of 0 to 5, and when n is 2 or more, the R.sub.4 's may be different from one another; and X represents a halogen atom.
摘要:
This invention provides a compound which is useful as an electric charge transportation agent for electrophotographic photosensitive materials and organic EL devices, and its production method. Illustratively, a compound of formula (I) is produced by way of a dehydration reaction of a compound of formula (II).
摘要:
A method for preparing N,N-disubstituted hydroxylamine compounds represented by the formula (II): HO--N(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 may be the same or different, and independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aromatic heterocyclic group, which comprises the step of adding a rhenium catalyst and aqueous hydrogen peroxide to a mixture containing a secondary amine compound represented by the formula (I): HN(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 have the same meanings as those defined above and a dehydrating agent.
摘要:
Disclosed is a silver halide color photographic material having at least one silver halide emulsion layer on a support, in which at least one layer constituting the material contains a coupler of formula (I): ##STR1## where R.sub.1 represents an electron-attracting substituent having a Taft's substituent constant .sigma.* value of +0.52 or more; R.sub.2 represents a branched alkyl group; and X represents a pyrazolyl group. The material has excellent heat stability, sensitivity, gradation and color image fastness, and it also has excellent color forming capacity and absorption characteristics.
摘要:
There is disclosed a process for producing 5-amino-4-halogeno-1H-pyrazole compounds comprising reacting a compound represented by the following formula (I) with a halogenating agent to obtain a compound represented by the following formula (II): ##STR1## wherein R represents a hydrogen atom, an alkyl group, or an aryl group, m is 0 or an integer, and Y represents an organic or inorganic acid radical, ##STR2## wherein R has the same meaning as defined above in formula (I), X represents a halogen atom, n is 0 or an integer, and Z represents an organic or inorganic acid radical.
摘要:
A process for producing a 3-iminonitrile represented by the following general formula (I): ##STR1## wherein M represents an alkali metal, which comprises reacting acetonitrile with an alkali metal hydride in an amount of from 0.01 to 0.5 molar equivalent to acetonitrile; and a process for producing a 3-iminonitrile of the formula (II): ##STR2## which comprises mixing the compound represented by the foregoing general formula (II), which was obtained by the reaction between acetonitrile and the alkali metal hydride, with a protic solvent, are disclosed. These processes are useful for producing the desired 3-iminonitrile safely, inexpensively and in high yields.
摘要:
A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer and at least one coupler represented by the following general formula (I): ##STR1## wherein (Q) represents a pyrazoloazole type color image forming coupler residue; L.sub.1 and L.sub.2 each represents a methylene group or an ethylene group; l and m each represents 0 or 1; R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sub.2 represents a group connecting with A through a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom; A represents a carbon atom or a sulfur atom; n represents 1, when A is a carbon atom, or 1 or 2, when A is a sulfur atom; B represents a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom; X represents an atomic group necessary to form a ring; R.sub.1 and R.sub.2 may connect with each other to form a ring; and B and R.sub.2 may connect with each other to form a ring, when B is a carbon atom or a nitrogen atom.A method of forming a color image comprising developing a silver halide photographic material with a developing solution containing an aromatic primary amine in the presence of a at least one coupler represented by the general formula (I) described above is also disclosed.The coupler represented by the general formula (I) has good color reproducibility due to being free from the undesirable subsidiary absorption of the dye formed therefrom and a high color forming rate, and provides a sufficiently high color density even when an amount of silver employed in the light-sensitive material is reduced or the light-sensitive material is subjected to a rapid processing method and a low level of fog. Further, the dye formed from the coupler exhibits excellent fastness.