Silver halide color photographic material containing pyrazolo
(1,5-b)(1,2,4)triazole magenta coupler
    3.
    发明授权
    Silver halide color photographic material containing pyrazolo (1,5-b)(1,2,4)triazole magenta coupler 失效
    含有吡咯并(1,5-B)(1,2,4)三唑杂环的银盐彩色摄影材料

    公开(公告)号:US5066575A

    公开(公告)日:1991-11-19

    申请号:US473166

    申请日:1990-01-31

    IPC分类号: C07D487/04 G03C7/333 G03C7/38

    CPC分类号: C07D487/04 G03C7/3835

    摘要: The present invention relates to a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, which contains at least one nondiffusible pyrazolo(1,5-b)(1,2,4)triazole magenta coupler represented by the following general formula (I) in at least one of the silver halide emulsion layers in order to acquire high color formability and to produce a dye image excellent in hue: ##STR1## wherein R.sub.1 represents an alkyl group; R.sub.2 and R.sub.3 each represents a hydrogen atom or an alkyl group, provided that both are not a hydrogen atom; R.sub.4 represents an alkyl group, an alkoxy group or a halogen atom; L represents an alkylene group; m represents an integer of 0 to 5; n represents an integer of 0 to 5, and when n is 2 or more, the R.sub.4 's may be different from one another; and X represents a halogen atom.

    Tribenzazepine compound and production method thereof
    5.
    发明授权
    Tribenzazepine compound and production method thereof 失效
    三苯并吖庚因化合物及其制备方法

    公开(公告)号:US06476221B1

    公开(公告)日:2002-11-05

    申请号:US09672991

    申请日:2000-09-29

    IPC分类号: C07D22314

    CPC分类号: C07D223/14

    摘要: This invention provides a compound which is useful as an electric charge transportation agent for electrophotographic photosensitive materials and organic EL devices, and its production method. Illustratively, a compound of formula (I) is produced by way of a dehydration reaction of a compound of formula (II).

    摘要翻译: 本发明提供了可用作电子照相感光材料和有机EL器件的电荷输送剂的化合物及其制备方法。 示例性地,式(I)化合物通过式(II)化合物的脱水反应制备。

    Method for preparing N,N-disubstituted hydroxylamines
    6.
    发明授权
    Method for preparing N,N-disubstituted hydroxylamines 失效
    制备N,N-二取代羟胺的方法

    公开(公告)号:US6031130A

    公开(公告)日:2000-02-29

    申请号:US81943

    申请日:1998-05-21

    摘要: A method for preparing N,N-disubstituted hydroxylamine compounds represented by the formula (II): HO--N(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 may be the same or different, and independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aromatic heterocyclic group, which comprises the step of adding a rhenium catalyst and aqueous hydrogen peroxide to a mixture containing a secondary amine compound represented by the formula (I): HN(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 have the same meanings as those defined above and a dehydrating agent.

    摘要翻译: 制备由式(II)表示的N,N-二取代羟胺化合物的方法:HO-N(R1)(R2)其中R1和R2可以相同或不同,并且独立地表示取代或未取代的烷基, 取代或未取代的芳基或取代或未取代的芳族杂环基,其包括将铼催化剂和过氧化氢水溶液加入到由式(I)表示的仲胺化合物的混合物中:HN(R1)(R2 )其中R1和R2具有与上述相同的含义和脱水剂。

    Silver halide color photographic material containing
pyrazole-substituted couplers
    7.
    发明授权
    Silver halide color photographic material containing pyrazole-substituted couplers 失效
    含有吡唑取代的成色剂的卤化银彩色照相材料

    公开(公告)号:US5500334A

    公开(公告)日:1996-03-19

    申请号:US941179

    申请日:1992-09-04

    IPC分类号: G03C7/38 G03C7/305

    CPC分类号: G03C7/30529

    摘要: Disclosed is a silver halide color photographic material having at least one silver halide emulsion layer on a support, in which at least one layer constituting the material contains a coupler of formula (I): ##STR1## where R.sub.1 represents an electron-attracting substituent having a Taft's substituent constant .sigma.* value of +0.52 or more; R.sub.2 represents a branched alkyl group; and X represents a pyrazolyl group. The material has excellent heat stability, sensitivity, gradation and color image fastness, and it also has excellent color forming capacity and absorption characteristics.

    摘要翻译: 公开了一种卤化银彩色照相材料,其在载体上具有至少一个卤化银乳剂层,其中构成该材料的至少一层包含式(I)的成色剂:其中R1表示电子 - 吸引具有Taft's取代基常数σ*值+0.52以上的取代基; R2表示支链烷基; X表示吡唑基。 该材料具有优异的热稳定性,灵敏度,等级和色牢度,并且还具有优异的成色能力和吸收特性。

    Process for producing 5-amino-4-halogeno-1H-pyrazole compounds
    8.
    发明授权
    Process for producing 5-amino-4-halogeno-1H-pyrazole compounds 失效
    生产5-氨基-4-甲基-1H-吡唑化合物的方法

    公开(公告)号:US5122612A

    公开(公告)日:1992-06-16

    申请号:US723050

    申请日:1991-06-28

    IPC分类号: C07D231/06 C07D231/38

    CPC分类号: C07D231/38

    摘要: There is disclosed a process for producing 5-amino-4-halogeno-1H-pyrazole compounds comprising reacting a compound represented by the following formula (I) with a halogenating agent to obtain a compound represented by the following formula (II): ##STR1## wherein R represents a hydrogen atom, an alkyl group, or an aryl group, m is 0 or an integer, and Y represents an organic or inorganic acid radical, ##STR2## wherein R has the same meaning as defined above in formula (I), X represents a halogen atom, n is 0 or an integer, and Z represents an organic or inorganic acid radical.

    Silver halide color photographic material containing novel pyrazoloazole
coupler and method to produce color image
    10.
    发明授权
    Silver halide color photographic material containing novel pyrazoloazole coupler and method to produce color image 失效
    含有新型吡唑并唑成色剂的卤化银色彩照相材料和产生彩色图像的方法

    公开(公告)号:US5155016A

    公开(公告)日:1992-10-13

    申请号:US580874

    申请日:1990-09-11

    IPC分类号: G03C7/38 G03C7/305 G03C7/407

    CPC分类号: G03C7/30529

    摘要: A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer and at least one coupler represented by the following general formula (I): ##STR1## wherein (Q) represents a pyrazoloazole type color image forming coupler residue; L.sub.1 and L.sub.2 each represents a methylene group or an ethylene group; l and m each represents 0 or 1; R.sub.1 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sub.2 represents a group connecting with A through a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom; A represents a carbon atom or a sulfur atom; n represents 1, when A is a carbon atom, or 1 or 2, when A is a sulfur atom; B represents a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom; X represents an atomic group necessary to form a ring; R.sub.1 and R.sub.2 may connect with each other to form a ring; and B and R.sub.2 may connect with each other to form a ring, when B is a carbon atom or a nitrogen atom.A method of forming a color image comprising developing a silver halide photographic material with a developing solution containing an aromatic primary amine in the presence of a at least one coupler represented by the general formula (I) described above is also disclosed.The coupler represented by the general formula (I) has good color reproducibility due to being free from the undesirable subsidiary absorption of the dye formed therefrom and a high color forming rate, and provides a sufficiently high color density even when an amount of silver employed in the light-sensitive material is reduced or the light-sensitive material is subjected to a rapid processing method and a low level of fog. Further, the dye formed from the coupler exhibits excellent fastness.

    摘要翻译: 一种卤化银照相材料,其包含其上具有至少一个卤化银乳剂层和至少一种由以下通式(I)表示的偶联剂的载体:其中(Q)表示吡唑并唑型彩色图像形成成色剂 残留物 L1和L2各自表示亚甲基或亚乙基; l和m各自表示0或1; R1表示氢原子,烷基,芳基或杂环基; R2表示通过碳原子,氧原子,氮原子或硫原子与A连接的基团; A表示碳原子或硫原子; 当A为碳原子,当A为硫原子时,n表示1,或1或2。 B表示碳原子,氧原子,氮原子或硫原子; X表示形成环所需的原子团; R1和R2可以彼此连接以形成环; 当B为碳原子或氮原子时,B和R2可以相互连接形成环。 还公开了一种形成彩色图像的方法,其包括在由上述通式(I)表示的至少一种成色剂的存在下,用含有芳族伯胺的显影溶液显影卤化银照相材料。 由通式(I)表示的成色剂具有良好的色彩再现性,这是由于没有由其形成的染料的不期望的辅助吸收和高的成色速率,并且即使当使用的银量 感光材料减少或感光材料经受快速处理方法和低雾度。 此外,由成色剂形成的染料表现出优异的牢度。