-
公开(公告)号:US07829044B2
公开(公告)日:2010-11-09
申请号:US10506424
申请日:2003-03-03
IPC分类号: C01F17/00 , C07D233/02
CPC分类号: C22B59/00 , C07F9/4407 , C07F9/4419 , C07F9/65848 , C22B3/0052 , C22B3/0072 , Y02P10/234
摘要: The invention provides a process by which rare earth metal ions can be efficiently extracted by easy operation, and effective extracting reagents for the process. Specifically, phosphonamides represented by the general formula [1]; a process for producing the same; reagents for extracting rare earth metal ions, containing the phosphonamides; and a process for extraction of rare earth metal ions with the phosphonamides: [1] wherein R1 is alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R2 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R3 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted, or the two R3s may be united to form alkylene, cycloalkylene, or arylene.
摘要翻译: 本发明提供了一种易于操作可有效提取稀土金属离子的方法,并为该方法提供了有效的提取试剂。 具体地,由通式[1]表示的膦酰胺; 其制造方法; 含有膦酰胺的稀土金属离子萃取试剂; 和用膦酰胺萃取稀土金属离子的方法:[1]其中R1是烷基,环烷基,烯基,环烯基,炔基,芳基,芳烷基或杂环基,条件是每个基团可以被取代; R2是氢,烷基,环烷基,烯基,环烯基,芳基,芳烷基或杂环基,条件是每个基团可以被取代; R 3是氢,烷基,环烷基,烯基,环烯基,芳基,芳烷基或杂环基,条件是每个基团可以被取代,或者两个R 3可以一起形成亚烷基,亚环烷基或亚芳基。
-
2.
公开(公告)号:US20050107599A1
公开(公告)日:2005-05-19
申请号:US10506424
申请日:2003-03-03
CPC分类号: C22B59/00 , C07F9/4407 , C07F9/4419 , C07F9/65848 , C22B3/0052 , C22B3/0072 , Y02P10/234
摘要: The invention provides a process by which rare earth metal ions can be efficiently extracted by easy operation, and effective extracting reagents for the process. Specifically, phosphonamides represented by the general formula [1]; a process for producing the same; reagents for extracting rare earth metal ions, containing the phosphonamides; and a process for extraction of rare earth metal ions with the phosphonamides: [1] wherein R1 is alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R2 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted; R3 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, aralkyl, or a heterocyclic group, with the proviso that each group may be substituted, or the two R3s may be united to form alkylene, cycloalkylene, or arylene.
摘要翻译: 本发明提供了一种易于操作可有效提取稀土金属离子的方法,并为该方法提供了有效的提取试剂。 具体地,由通式[1]表示的膦酰胺; 其制造方法; 含有膦酰胺的稀土金属离子萃取试剂; 以及用膦酰胺萃取稀土金属离子的方法:[1]其中R 1是烷基,环烷基,烯基,环烯基,炔基,芳基,芳烷基或杂环基,条件是 每个组可以被替代; R 2是氢,烷基,环烷基,烯基,环烯基,芳基,芳烷基或杂环基,条件是每个基团可以被取代; R 3是氢,烷基,环烷基,烯基,环烯基,芳基,芳烷基或杂环基,条件是每个基团可以被取代,或两个R 3 O 可以结合形成亚烷基,亚环烷基或亚芳基。
-
公开(公告)号:US4370237A
公开(公告)日:1983-01-25
申请号:US193280
申请日:1980-05-21
CPC分类号: C22B3/0041 , C22B3/0072 , C22B3/0077 , Y02P10/234
摘要: An extraction process for extracting ionic values from an aqueous solution containing same which comprises contacting the aqueous solution with an organic hydrophobic liquid extractant phase comprising an extractant for ions, the molecules of which extractant contain at least one hydrophobic group selected from cyclic phosphazene radicals, linear siloxane radicals, cyclic siloxane radicals, and three-dimensional siloxane radicals, and stripping resulting loaded extractant phase with an aqueous stripping liquid phase.
摘要翻译: PCT No.PCT / GB79 / 00171 Sec。 371日期1980年5月21日 102(e)日期1980年5月21日PCT提交1979年10月25日PCT公布。 出版物WO80 / 00796 日期:1980年5月1日。一种用于从含有该溶液的水溶液中提取离子值的提取方法,其包括使该水溶液与包含用于离子的萃取剂的有机疏水性液体萃取剂相接触,所述萃取剂的分子含有至少一个选自 从环状磷腈基团,直链硅氧烷基团,环状硅氧烷基团和三维硅氧烷基团,并用水性剥离液相汽提得到的负载萃取剂相。
-
-