公开(公告)号：US3927961A

公开(公告)日：1975-12-23

申请号：US26939872

申请日：1972-07-06

申请人： WOOL RES ORGANISATION

发明人： SIMPSON WILLIAM STANLEY

IPC分类号： D06M14/06 ,  D06P1/16 ,  D06P1/39 ,  D06P3/04 ,  D06P3/14 ,  D06P5/00

CPC分类号： D06P3/145 ,  D06M14/06 ,  D06P1/16 ,  D06P1/39 ,  D06P3/04 ,  D06P3/047 ,  Y10S8/917

摘要： This invention provides a combined dyeing and polymer deposition process for protein fibres. The fibres are treated in a liquid containing a dye, a polymerisable olefinic monomer and a catalyst in the form of a complex of copper, iron, chromium, manganese, vanadium, cobalt, nickel and aluminium together with a trihaloacetic acid or a salt or ester thereof. Other substances which can form trihalomethyl ions or free radicals in the presence of the complex can also be used. The combined catalyst of metal complex and trihaloacetic acid enables polymerisation of the monomer to be carried out in the presence of air and also permits formation of the polymer within the fibre substance rather than at the surface or in the liquid. The dye may be an acid, premetallised or reactive dye and is usually applied simultaneously with the polymer, for example by heating the fibres in an aqueous solution containing the reacting materials gradually from room temperature up to a temperature in the range 50* to 100*C and maintaining them at that temperature for between 30 minutes and 2 hours. The invention enables wool to be coloured and to have its physical and mechanical properties altered by polymer deposition in a single operation in a single bath, as well as ensuring that as much as possible of the polymer forms within the substance of the fibres.

摘要翻译： 本发明提供蛋白质纤维的组合染色和聚合物沉积方法。 纤维在含有染料，可聚合的烯属单体和铜，铁，铬，锰，钒，钴，镍和铝的复合物形式的催化剂以及三卤乙酸或盐或酯的液体中处理 其中。 也可以使用在复合物存在下可形成三卤甲基离子或自由基的其它物质。 金属络合物和三卤代乙酸的组合催化剂可以在空气存在下聚合单体，并且还允许在纤维物质内形成聚合物，而不是在表面或液体中形成。 染料可以是酸，预金属化或活性染料，并且通常与聚合物同时施加，例如通过将含有反应材料的水溶液中的纤维从室温逐渐加热至50℃至100℃的温度来进行。 并在该温度下保持30分钟至2小时。 本发明使得羊毛可以被着色并且在单个浴中在单次操作中通过聚合物沉积改变其物理和机械性能，并且确保尽可能多地在纤维物质内形成聚合物形式。

公开(公告)号：US08118880B1

公开(公告)日：2012-02-21

申请号：US12946461

申请日：2010-11-15

申请人： John C. Warner ,  Emily J. Stoler

发明人： John C. Warner ,  Emily J. Stoler

IPC分类号： C09B67/00

CPC分类号： C09B61/00 ,  A61K8/19 ,  A61K8/35 ,  A61K8/355 ,  A61K8/36 ,  A61K8/44 ,  A61K8/66 ,  A61K2800/4324 ,  A61K2800/882 ,  A61Q5/10 ,  D06P1/0056 ,  D06P1/34 ,  D06P3/145

摘要： A natural coloring composition for coloring materials, and methods of its use. The coloring composition comprises a natural precursor aromatic ring molecule such as L-DOPA that is oxidatively oligomerized or polymerized in the presence of arginine and an activator, such as a salt or an enzyme, wherein the L-DOPA and the amino acid form a specific non-covalent interaction. The natural coloring composition can also include a buffer, colorant, stabilizer, and/or thickening agent, and can comprise one or two inactive solutions that are combined to form an active coloring composition.

摘要翻译： 用于着色材料的天然着色组合物及其使用方法。 着色组合物包含天然前体芳环分子如L-DOPA，其在精氨酸和活化剂如盐或酶的存在下被氧化低聚或聚合，其中L-DOPA和氨基酸形成特异性 非共价相互作用。 天然着色组合物还可以包括缓冲剂，着色剂，稳定剂和/或增稠剂，并且可以包含一种或两种组合形成活性着色组合物的无活性溶液。

公开(公告)号：US07976585B2

公开(公告)日：2011-07-12

申请号：US12598494

申请日：2008-04-25

申请人： Christian Cremer ,  Richard Lewis Riggs ,  Beate Fröhling ,  Martin Müller

发明人： Christian Cremer ,  Richard Lewis Riggs ,  Beate Fröhling ,  Martin Müller

IPC分类号： A61Q5/10 ,  C07F7/18

CPC分类号： C08G77/26 ,  A61K8/11 ,  A61K8/26 ,  A61K8/898 ,  A61K2800/413 ,  A61K2800/43 ,  A61K2800/434 ,  A61Q5/065 ,  B82Y5/00 ,  C07F7/1804 ,  C08G77/22 ,  C08L83/08 ,  C09B69/008 ,  C09B69/101 ,  C09B69/103 ,  C09B69/106 ,  C09B69/107 ,  C09B69/109 ,  D06P1/0052 ,  D06P3/145 ,  Y10T428/29

摘要： A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.

摘要翻译： 包含至少10个Si原子的高度交联的聚硅氧烷染料，包括至少一个式（I）部分，其开放的Si键各自连接到氧原子和开放的O形键，其余部分与硅原子连接 聚硅氧烷，其中T为直接键或有机间隔基团，例如C 1 -C 18亚烷基，C 2 -C 12亚烯基，C 5 -C 10环亚烷基，C 5 -C 10亚芳基，-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - 各自可以是末端 通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，SO2，C5-C10亚环烷基，C5-C10亚芳基与染料键合。 CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，-SO2 - ，C5-的亚烷基被中断并且任选地被端基连接到染料上， C 5 -C 10亚芳基; 或是CO; （CH 2 CH 2 -O）1-5; 首席运营官 N（R1）; CON（R1）; O; S; 所以; SO2; R1是氢; 直链或支链的单环或多环，中断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 染料是有机染料的残留物，可用于染色有机材料，如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。

公开(公告)号：US20100192312A1

公开(公告)日：2010-08-05

申请号：US12598494

申请日：2008-04-25

申请人： Christian Cremer ,  Richard Lewis Riggs ,  Beate Frohling ,  Martin Muller

发明人： Christian Cremer ,  Richard Lewis Riggs ,  Beate Frohling ,  Martin Muller

IPC分类号： A61K8/89 ,  C08G77/04 ,  B32B1/00 ,  C09B27/00 ,  C07F7/10 ,  C09B67/22

CPC分类号： C08G77/26 ,  A61K8/11 ,  A61K8/26 ,  A61K8/898 ,  A61K2800/413 ,  A61K2800/43 ,  A61K2800/434 ,  A61Q5/065 ,  B82Y5/00 ,  C07F7/1804 ,  C08G77/22 ,  C08L83/08 ,  C09B69/008 ,  C09B69/101 ,  C09B69/103 ,  C09B69/106 ,  C09B69/107 ,  C09B69/109 ,  D06P1/0052 ,  D06P3/145 ,  Y10T428/29

摘要： A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.

摘要翻译： 包含至少10个Si原子的高度交联的聚硅氧烷染料，包括至少一个式（I）部分，其开放的Si键各自连接到氧原子和开放的O形键，其余部分与硅原子连接 聚硅氧烷，其中T为直接键或有机间隔基团，例如C 1 -C 18亚烷基，C 2 -C 12亚烯基，C 5 -C 10环亚烷基，C 5 -C 10亚芳基，-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - 各自可以是末端 通过CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，SO2，C5-C10亚环烷基，C5-C10亚芳基与染料键合。 CO，COO，NR1，CONR1，NR1CONR1，CS，CSS，CSNR1，NR1CSNR1，O，S，SO，-SO2 - ，C5-的亚烷基被中断并且任选地被端基连接到染料上， C 5 -C 10亚芳基; 或是CO; （CH 2 CH 2 -O）1-5; 首席运营官 N（R1）; CON（R1）; O; S; 所以; SO2; R1是氢; 直链或支链的单环或多环，中断或不间断的C 1 -C 14烷基; C2-C14烯基; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 染料是有机染料的残留物，可用于染色有机材料，如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。

公开(公告)号：US06689870B1

公开(公告)日：2004-02-10

申请号：US09116743

申请日：1998-07-16

申请人： Jinzong Yang ,  Shufen Zhang

发明人： Jinzong Yang ,  Shufen Zhang

IPC分类号： C08H100

CPC分类号： D06P3/32 ,  C07K14/4732 ,  C07K14/4741 ,  C07K14/78 ,  C09B69/10 ,  D06P1/0052 ,  D06P3/02 ,  D06P3/026 ,  D06P3/14 ,  D06P3/145 ,  D06P3/3266

摘要： Protein macromolecular dyes, A(B)b are disclosed, wherein A are protein macromolecules including natural protein macromolecules and modified natural protein macromolecules such as casein, gelatin and fur-protein; B are dyes including azo dyes, azo metal complex dyes and anthraquinone dyes which can react with the amino groups of the natural and modified protein macromolecules; b are integers between 1˜2500. The protein macromolecular dyes have excellent properties of crosslinking ability, better dyeing fastness, fixation ration than conventional dyes and the function of normal macromolecules such as compatibility, abilities of filling and forming membranes. They may be used in dyeing protein materials such as leather, wool and silk.

摘要翻译： 公开了蛋白质大分子染料A（B）b，其中A是蛋白质大分子，包括天然蛋白质大分子和改性天然蛋白质大分子如酪蛋白，明胶和毛皮蛋白; B是可以与天然和修饰的蛋白质大分子的氨基反应的染料，包括偶氮染料，偶氮金属络合物染料和蒽醌染料; b是1〜2500之间的整数。 蛋白质大分子染料具有优异的交联能力，较好的染色牢度，固色比常规染料的性能以及正常大分子的功能，如相容性，填充和形成膜的能力。 它们可用于染色蛋白质材料如皮革，羊毛和丝绸。