Method for purification of vinyl polymers
    1.
    发明授权
    Method for purification of vinyl polymers 失效
    乙烯基聚合物的纯化方法

    公开(公告)号:US06794461B2

    公开(公告)日:2004-09-21

    申请号:US09938310

    申请日:2001-08-24

    CPC classification number: C08F8/42 C08F6/02 C08F8/04 C08F8/06

    Abstract: This invention provides a method for purification of a vinyl polymer which comprises the atom transfer radical polymerization of a vinyl monomer using a transition metal complex as the polymerization catalyst, said vinyl polymer being brought into contact with an oxidizing agent or a reducing agent.

    Abstract translation: 本发明提供了一种乙烯基聚合物的纯化方法,其包括使用过渡金属络合物作为聚合催化剂的乙烯基单体的原子转移自由基聚合,所述乙烯基聚合物与氧化剂或还原剂接触。

    Dispersing agents for pigments or extenders based on acrylic acid alkyl ester polymers
    2.
    发明授权
    Dispersing agents for pigments or extenders based on acrylic acid alkyl ester polymers 失效
    基于丙烯酸烷基酯聚合物的颜料或增量剂分散剂

    公开(公告)号:US06596816B1

    公开(公告)日:2003-07-22

    申请号:US09075613

    申请日:1998-05-11

    CPC classification number: C09D17/00 B01F17/005 C08F8/32 C09D7/45 C08F20/12

    Abstract: The present invention relates to dispersing agents for pigments or extenders based on acrylic acid alkyl ester polymers, wherein at least part of the ester groups of the polymers is reacted to form acid amides, wherein the dispersing agent is obtainable by the aminolysis of ester groups of the polymers by means of amines, wherein, for the aminolysis, at least one amine is used from the group comprising a) amines of general formula NH2—R1—NR2R3, wherein R1 is a divalent alkylene radical comprising 2-4 carbon atoms and R2 and R3 are aliphatic and/or alicyclic alkyl radicals which comprise 1-12, preferably 1-6 carbon atoms and which can be the same or different. The invention also relates to the use of the dispersing agents according to the invention for the production of pigment concentrates and coating media, and to a process for producing the dispersing agents.

    Abstract translation: 本发明涉及基于丙烯酸烷基酯聚合物的颜料或增量剂分散剂,其中聚合物的至少部分酯基反应形成酰胺,其中分散剂可通过 通过胺的聚合物,其中,对于氨解,使用至少一种胺,其包含a)通式NH 2 -R 1 -NR 2 R 3的胺,其中R 1是包含2-4个碳原子的二价亚烷基和R 2 并且R 3是包含1-12个,优选1-6个碳原子并且可以相同或不同的脂族和/或脂环族烷基。 本发明还涉及根据本发明的分散剂用于制备颜料浓缩物和涂料介质的用途,以及生产该分散剂的方法。

    High-molecular, cross-linked polyvinyl butyrals, method for the production thereof and their use
    3.
    发明授权
    High-molecular, cross-linked polyvinyl butyrals, method for the production thereof and their use 失效
    高分子交联聚乙烯醇缩丁醛,其制备方法及其应用

    公开(公告)号:US06835784B2

    公开(公告)日:2004-12-28

    申请号:US10257574

    申请日:2002-10-15

    Inventor: Bernd Papenfuhs

    CPC classification number: B32B17/10761 C08F8/00 C08K5/11 C08F16/06 C08L29/00

    Abstract: The present invention relates to high-molecular-weight, crosslinked polyvinyl butyrals obtainable by crosslinking a polyvinyl butyral with at least one di- and/or polycarboxylic acid or derivatives of these as crosslinking reagent, to a process for their production, and to their use.

    Abstract translation: 本发明涉及通过将聚乙烯醇缩丁醛与至少一种二 - 和/或多羧酸或它们的衍生物交联为交联剂的高分子量交联聚乙烯醇缩丁醛,其生产方法及其用途 。

    Amorphous (per) fluorinated polymers
    4.
    发明授权
    Amorphous (per) fluorinated polymers 有权
    无定形(全)氟化聚合物

    公开(公告)号:US06828388B2

    公开(公告)日:2004-12-07

    申请号:US10136424

    申请日:2002-05-02

    CPC classification number: G02B1/046 B29D11/00721 C08F8/22 C08L45/00 C08F214/18

    Abstract: Amorphous perfluorinated or fluorinated polymers containing an amount lower than 0.05 mmoles/kg polymer of each of the following ionic end groups: COF, COOH, their esters or salts, when the used determination method for said end groups is the Fourier Transform IR spectroscopy by Nicolet® Nexus FT-IR equipment (256 scannings, resolution 2 cm−1)

    Abstract translation: 当用于所述端基的所用测定方法是Nicolet的傅立叶变换红外光谱时,含有低于0.05mmoles / kg以下各个离子端基的聚合物的无定形全氟化或氟化聚合物:COF,COOH,它们的酯或盐 (R)Nexus FT-IR设备(256扫描,分辨率2厘米-1)

    Air content stabilizing agents for hydraulic cement compositions and hydraulic cement compositions containing same

    公开(公告)号:US06627703B2

    公开(公告)日:2003-09-30

    申请号:US09972846

    申请日:2001-10-04

    Abstract: An agent for stabilizing air content of hydraulic cement compositions includes graft copolymers obtained by a first step in which copolymers with average numerical molecular weight 5000-50000 are obtained by radical polymerization of a mixture of radical polymerizable monomers containing anhydrous maleic acid and monomers of a specified form, together in an amount of 80 molar % or more and at molar ratio of 40/60-60/40 and a second step in which graft copolymers are obtained by a graft reaction of 100 weight parts of the copolymers obtained in the first step and 7-60 weight parts of polyoxyalkylene monoalkylether and/or polyoxyalkylene monoalkenylether with a block addition of a total of 23-70 moles of ethylene oxide and propylene oxide per 1 mole of aliphatic alcohol with 8-20 carbon atoms. A hydraulic cement composition is produced with cement, aggregates, water, a cement dispersant, an agent for controlling air content and contains an agent for stabilizing air content as described above in the amount of 0.001-0.5 weight parts per 100 weight parts of the cement.

    Polyolefins functionalized with maleic anhydride and with its high-boiling liquids esters, and their use as products with high compatibilizing power
    6.
    发明授权
    Polyolefins functionalized with maleic anhydride and with its high-boiling liquids esters, and their use as products with high compatibilizing power 失效
    用马来酸酐和其高沸点液体酯官能化的聚烯烃,并且它们用作具有高相容性能力的产品

    公开(公告)号:US06451919B1

    公开(公告)日:2002-09-17

    申请号:US09582829

    申请日:2000-10-18

    CPC classification number: C08F255/00 C08F222/06

    Abstract: Described herein are polyolefins functionalized with maleic anhydrid and at least one high-boiling ester of the latter, and a process for their preparation in high yields, with high degrees of functionalization, without the production of by-products of cross-linking or degradation. The process, which may be carried out either continuously or discontinuously, is characterized by the use of inorganic substances having a specific porosity, grain size, density and humidity, as vehicles of the functionalizing monomers; the presence of maleic ester contributes to enhancing the reaction efficiency. Likewise described herein is a double-screw extruder devised for carrying out the said process, and the use of products obtained as compatibilizing additives in the field of adhesive and reinforcing polymers.

    Abstract translation: 本文描述的是使用马来酸酐功能化的聚烯烃和后者的至少一种高沸点酯,以及其高官能度制备方法,具有高度官能度,而不产生交联或降解的副产物。 可以连续地或不连续地进行的方法的特征在于使用具有特定孔隙率,粒度,密度和湿度的无机物质作为官能化单体的载体; 马来酸酯的存在有助于提高反应效率。 本文同样描述了用于实施所述方法的双螺杆挤出机,以及在粘合剂和增强聚合物领域中作为相容添加剂获得的产品的用途。

    Fluoropolymers having pendant imidate structures
    7.
    发明授权
    Fluoropolymers having pendant imidate structures 失效
    含有亚氨酸酯侧链结构的含氟聚合物

    公开(公告)号:US06803425B2

    公开(公告)日:2004-10-12

    申请号:US10122487

    申请日:2002-04-11

    CPC classification number: C08F16/24 C08F214/18 C08F214/262 C08J5/18

    Abstract: A composition comprising (a) a fluoropolymer having pendant imidate groups, which imidate groups have the formula: —C═NH(OR) wherein R is a C1-C10 aliphatic group which aliphatic group may have F or Cl substituents; and optionally, (b) a perfluorovinyl ether of the general formula: CF2═CFO(R′fO)a(R″fO)bRf wherein R′f and R″f are the same or are different C1-C6 linear or branched perfluoroalkylene groups; a and b are, independently, 0 or an integer from 1 to 10; and Rf is a C1-C8 perfluoroalkyl group or a C1-C15 perfluoroalkoxy group. Also provided are a method of making a fluoropolymer composition and curable and cured articles comprising a fluoropolymer composition.

    Abstract translation: 一种组合物,其包含(a)具有亚酰氨基侧基的含氟聚合物,所述亚胺基具有下式:-C = NH(OR),其中R是C1-C10脂族基团,该脂族基团可以具有F或Cl取代基; 和(b)通式CF 2 = CFO(R'fO)a(R“f O)b R f的全氟乙烯基醚,其中R'f和R''f相同或不同,C1-C6直链或 支链全氟亚烷基; a和b独立地为0或1〜10的整数; Rf为C1-C8全氟烷基或C1-C15全氟烷氧基。 还提供了制备包含含氟聚合物组合物的含氟聚合物组合物和可固化和固化的制品的方法。

    Surface-crosslinking process for water-absorbent resin
    9.
    发明授权
    Surface-crosslinking process for water-absorbent resin 有权
    吸水树脂的表面交联方法

    公开(公告)号:US06254990B1

    公开(公告)日:2001-07-03

    申请号:US09250477

    申请日:1999-02-14

    CPC classification number: C08J3/245 C08J3/12 C08J2300/14 Y10T428/2982

    Abstract: The present invention provides a surface-crosslinking process of a water-absorbent resin to obtain a water-absorbing agent which has high absorption speed and excellent absorption capacity under a load (a water-absorbent resin which has specific or larger values of properties). In a process comprising the step of adding a crosslinking agent to a dry water-absorbent resin powder to thereby crosslink the neighborhood of its surface, the surface-crosslinking is carried out while the resin powder having a weight-average particle diameter of 200 to 1,000 &mgr;m is pulverized.

    Abstract translation: 本发明提供一种吸水性树脂的表面交联方法,以获得在负荷下具有高吸收速度和优异吸收能力的吸水剂(具有特定或更大特性值的吸水性树脂)。 在包括向干吸水性树脂粉末中添加交联剂从而交联其表面附近的步骤的过程中,进行表面交联,同时重均粒径为200〜1000的树脂粉末 妈妈被粉碎。

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