公开(公告)号：US20090082488A1

公开(公告)日：2009-03-26

申请号：US11911501

申请日：2006-04-14

Applicant: Masanao Takeda ,  Nao Fujita ,  Hitoshi Tamai ,  Yoshiki Nakagawa

Inventor： Masanao Takeda ,  Nao Fujita ,  Hitoshi Tamai ,  Yoshiki Nakagawa

IPC: C08F2/46 ,  C08F120/18 ,  C08F230/04

CPC classification number: C09J133/08 ,  C08F8/26 ,  C08F220/18 ,  C08F220/30 ,  C08F220/36 ,  C08F290/04 ,  C08F290/06 ,  C08F290/061 ,  C08F2438/01 ,  C08F2800/20 ,  C08F2810/30 ,  C09J4/06 ,  C09J133/06 ,  C09J133/10 ,  C08F2220/1858 ,  C08F2220/1825 ,  C08F20/18

Abstract: The present invention has its object to provide an acrylic curable composition which is improved in tackiness, retention and other adhesive properties without reducing the thermal stability and weather resistance. The above-mentioned object can be solved by a curable composition which comprises, as an essential component, polymer (I), which is a (meth)acrylic acid ester copolymer having, in each molecule, at least one group represented by the general formula 1: —OC(O)C(Ra)═CH2  (1)  (wherein Ra represents a hydrogen atom or a hydrocarbon group containing 1 to 20 carbon atoms) at a terminus of the molecular chain and is obtained by (co)polymerizing an (meth)acrylic acid alkyl ester the alkyl moiety of which contains 7 to 20 carbon atoms.

Abstract translation: 本发明的目的是提供一种在不降低热稳定性和耐候性的情况下提高粘合性，保留性等粘合性能的丙烯酸类固化性组合物。 上述目的可以通过包含作为必要成分的聚合物（I）的可固化组合物来解决，聚合物（I）是在每个分子中具有至少一个由通式表示的基团的（甲基）丙烯酸酯共聚物 -OC（O）C（Ra）-CH2（1）<？in-line-formula description =“In-line-formula description =”In-line-formula description = （其中R a表示氢原子或含有1〜20个碳原子的烃基），并且通过（共）聚合（甲基）丙烯酸烷基酯 酯，其烷基部分含有7至20个碳原子。

公开(公告)号：US07439308B2

公开(公告)日：2008-10-21

申请号：US10506103

申请日：2003-04-18

Applicant: Shigeki Ohno ,  Yoshiki Nakagawa ,  Kenichi Kitano ,  Masanao Takeda ,  Nao Fujita

Inventor： Shigeki Ohno ,  Yoshiki Nakagawa ,  Kenichi Kitano ,  Masanao Takeda ,  Nao Fujita

IPC: C08F20/02 ,  C08C19/25 ,  C08C2/04

CPC classification number: C08F6/02 ,  C08F2/38 ,  C08F6/001 ,  C08F8/26 ,  C08F8/42 ,  C08F220/18 ,  C08F2438/01 ,  C08L33/00 ,  C08F20/00

Abstract: A method for producing a (meth)acrylic polymer having crosslinkable silyl groups at the termini, comprising a step of adding a hydrosilane compound having a crosslinkable silyl group to an alkenyl-terminated (meth)acrylic polymer (A), which is prepared by atom transfer radical polymerization, in the presence of a platinum hydrosilylation catalyst. The amount of the platinum hydrosilylation catalyst is 0.1 to 10 mg on a platinum metal basis per kilogram of the alkenyl-terminated (meth)acrylic polymer (A). An object of the invention is to provide a method for producing a (meth)acrylic polymer having terminal crosslinkable silyl.

Abstract translation: 一种在末端具有交联性甲硅烷基的（甲基）丙烯酸系聚合物的制造方法，其特征在于，包括将由具有交联性甲硅烷基的氢硅烷化合物加成到由链烯基封端的（甲基）丙烯酸系聚合物（A） 在铂氢硅烷化催化剂存在下转移自由基聚合。 铂氢化硅烷化催化剂的量为每千克烯基封端的（甲基）丙烯酸类聚合物（A）为铂金属为0.1〜10mg。 本发明的目的是提供一种具有末端可交联甲硅烷基的（甲基）丙烯酸聚合物的制备方法。

公开(公告)号：US20050014912A1

公开(公告)日：2005-01-20

申请号：US10491187

申请日：2002-10-17

Applicant: Akihisa Hirota ,  Kosuke Tanaka ,  Shigeru Hagimori ,  Yosuke Asai ,  Naoki Furukawa ,  Masanao Takeda ,  Nao Fujita ,  Yoshiki Nakagawa

Inventor： Akihisa Hirota ,  Kosuke Tanaka ,  Shigeru Hagimori ,  Yosuke Asai ,  Naoki Furukawa ,  Masanao Takeda ,  Nao Fujita ,  Yoshiki Nakagawa

IPC: C08F4/40 ,  C08F4/42 ,  C08F6/00 ,  C08F6/02 ,  C08F8/06 ,  C08F8/42 ,  C08L83/05

CPC classification number: C08F6/02 ,  C08F8/06 ,  C08F2438/01 ,  C08F2810/30 ,  C08F2810/40 ,  C08F8/26 ,  C08F120/18 ,  C08F2220/1808 ,  C08F2220/1825 ,  C08F2220/281

Abstract: The present invention provides a method for producing a vinyl polymer including the steps of polymerizing a vinyl monomer by atom transfer radical polymerization with a transition metal complex as a polymerization catalyst, and bringing the resultant vinyl polymer into contact with an adsorbent in the presence of an oxidizing agent; the vinyl polymer produced by the method; and a reactive composition susceptible to hydrosilylation containing the vinyl polymer produced by the method and having at least one alkenyl group per molecule.

Abstract translation: 本发明提供一种乙烯基聚合物的制造方法，包括以下步骤：用过渡金属络合物作为聚合催化剂通过原子转移自由基聚合使乙烯基单体聚合，并使所得到的乙烯基聚合物与吸附剂接触， 氧化剂; 通过该方法制备的乙烯基聚合物; 以及易受含有通过该方法制备的乙烯基聚合物的氢化硅烷化的反应性组合物，并且每分子具有至少一个烯基。

公开(公告)号：US20050014904A1

公开(公告)日：2005-01-20

申请号：US10913550

申请日：2004-08-09

Applicant: Nao Fujita ,  Kenichi Kitano ,  Yoshiki Nakagawa

Inventor： Nao Fujita ,  Kenichi Kitano ,  Yoshiki Nakagawa

IPC: C08F6/02 ,  C08F8/04 ,  C08F8/06 ,  C08F8/42 ,  C08F8/14

CPC classification number: C08F8/42 ,  C08F6/02 ,  C08F8/04 ,  C08F8/06

Abstract: This invention provides a method for purification of a vinyl polymer which comprises the atom transfer radical polymerization of a vinyl monomer using a transition metal complex as the polymerization catalyst, said vinyl polymer being brought into contact with an oxidizing agent or a reducing agent.

Abstract translation: 本发明提供一种乙烯基聚合物的纯化方法，其包括使用过渡金属配合物作为聚合催化剂的乙烯基单体的原子转移自由基聚合，所述乙烯基聚合物与氧化剂或还原剂接触。

公开(公告)号：US06649701B1

公开(公告)日：2003-11-18

申请号：US09647171

申请日：2000-11-20

Applicant: Yoshiki Nakagawa ,  Nao Fujita

Inventor： Yoshiki Nakagawa ,  Nao Fujita

IPC: C08F800

CPC classification number: C08F293/005 ,  C08F8/00 ,  C08F220/12 ,  C08F2438/01 ,  C08F10/00

Abstract: The present invention has for its object to provide a polymer available upon coupling of polymers of radical-polymerizable olefin monomer or monomers and a process for producing said polymer. The present invention is concerned with a method for effecting polymer-polymer coupling in the living radical polymerization of a radical-polymerizable olefin monomer which comprises adding a compound having at least two sparingly radical-polymerizable alkenyl groups during or after polymerization.

Abstract translation: 本发明的目的是提供一种在可自由基聚合的烯烃单体或单体的聚合物偶联时可获得的聚合物和用于制备所述聚合物的方法。本发明涉及在活性基团中进行聚合物 - 聚合物偶联的方法 可自由基聚合的烯烃单体的聚合，其包括在聚合期间或之后加入具有至少两个少量可自由基聚合的烯基的化合物。

公开(公告)号：US07781534B2

公开(公告)日：2010-08-24

申请号：US11987469

申请日：2007-11-30

Applicant: Kenichi Kitano ,  Akihisa Hirota ,  Masanao Takeda ,  Kosuke Tanaka ,  Yoshiki Nakagawa ,  Shigeru Hagimori ,  Naoki Furukawa ,  Shigeki Ono ,  Nao Fujita

Inventor： Kenichi Kitano ,  Akihisa Hirota ,  Masanao Takeda ,  Kosuke Tanaka ,  Yoshiki Nakagawa ,  Shigeru Hagimori ,  Naoki Furukawa ,  Shigeki Ono ,  Nao Fujita

IPC: C08J3/28 ,  C08C2/04 ,  C08C19/25

CPC classification number: C08F8/26 ,  C08F8/16 ,  C08F8/48 ,  C08F2810/30 ,  C08F2810/40 ,  Y10T436/196666

Abstract: The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.

Abstract translation: 本发明提供了一种制备乙烯基聚合物的方法，该乙烯基聚合物含有每千克1,000mg以下的卤素，其中含有通过乙烯基单体的原子转移自由基聚合产生的卤素的乙烯基聚合物在温度为 范围为140至250℃，以使乙烯基聚合物脱卤; 通过该方法获得的乙烯基聚合物; 和含有乙烯基聚合物的氢化硅烷化反应性固化组合物。

公开(公告)号：US20090275705A1

公开(公告)日：2009-11-05

申请号：US11887390

申请日：2006-03-27

Applicant: Nao Fujita ,  Yoshiki Nakagawa

Inventor： Nao Fujita ,  Yoshiki Nakagawa

IPC: C08F8/00

CPC classification number: C08F293/00 ,  C08F8/42 ,  C08F293/005 ,  C08F2800/20 ,  C08F2810/20 ,  C08F2810/40 ,  C08L53/00 ,  C08L2666/02 ,  C08L2666/24 ,  C09J153/00

Abstract: The present invention has its object to provide an acrylic hot-melt pressure-sensitive adhesive composition showing only small changes in melt viscosity, showing good hot-melt applicability and excellent in initial cohesive force prior to moisture curing, and showing excellent tackiness and thermostable cohesive force after moisture curing.The present invention relates to a acrylic block copolymer which comprises an acrylic polymer block (A) and an acrylic polymer block (B) differing in glass transition temperature range and having at least one crosslinkable functional group (X) at its molecular termini; and a reactive hot-melt adhesive composition which comprises the acrylic block copolymer described above.

Abstract translation: 本发明的目的是提供一种丙烯酸类热熔压敏粘合剂组合物，其在熔融粘度方面只有微小的变化，显示出良好的热熔适用性和在湿润固化之前具有优异的初始内聚力，并且显示出优异的粘性和耐热粘结性 湿度固化后的力。 本发明涉及一种丙烯酸类嵌段共聚物，其包含在玻璃化转变温度范围不同且在其分子末端具有至少一个可交联官能团（X）的丙烯酸类聚合物嵌段（A）和丙烯酸类聚合物嵌段（B） 以及包含上述丙烯酸类嵌段共聚物的反应性热熔粘合剂组合物。

公开(公告)号：US20090203853A1

公开(公告)日：2009-08-13

申请号：US12279282

申请日：2007-02-09

Applicant: Nao Fujita ,  Yoshiki Nakagawa

Inventor： Nao Fujita ,  Yoshiki Nakagawa

IPC: C08F2/00 ,  C08F118/02

CPC classification number: C08F8/00 ,  C08F2800/20 ,  C08F2810/30 ,  C08F2810/40 ,  C08F2220/1825

Abstract: A first object of the present invention is to provide a vinyl polymer that has a molecular chain into which a structure containing a polar functional group is introduced, and that is useful as a precursor of a graft polymer. A second object of the present invention is to provide a process for producing the vinyl polymer. These objects can be achieved by the present invention providing a vinyl polymer having a polar functional group (X), and further having, at the position of at least one molecular terminal thereof, a group (A) containing a carbon-carbon double bond.

Abstract translation: 本发明的第一个目的是提供具有分子链的乙烯基聚合物，其中引入了含有极性官能团的结构，并且其可用作接枝聚合物的前体。 本发明的第二个目的是提供一种生产乙烯基聚合物的方法。 这些目的可以通过提供具有极性官能团（X）的乙烯基聚合物的本发明来实现，并且在其至少一个分子末端的位置上还含有含有碳 - 碳双键的基团（A）。

公开(公告)号：US20080214742A1

公开(公告)日：2008-09-04

申请号：US11885584

申请日：2006-03-03

Applicant: Yousuke Asai ,  Nao Fujita

Inventor： Yousuke Asai ,  Nao Fujita

IPC: C08F8/06 ,  C08F20/06

CPC classification number: C08F6/02 ,  C08F6/001

Abstract: The present invention has its object to provide a process for producing a vinyl polymer which can provide a vinyl polymer in such form that a polymerization catalyst is effectively removed from that. The present invention relates to a process for producing a vinyl polymer wherein a vinyl polymer at the time of completion of the polymerization is treated with oxygen in the presence of a polar solvent. More preferably, the present invention relates to a process for bringing a polymer added with a polar solvent having a relative dielectric constant at 20° C. of not lower than 10 into contact with mixed gases of oxygen and an inert gas such as nitrogen with an oxygen concentration below the explosion limit oxygen concentration of this solvent as in the state of occurrence as a pure component.

Abstract translation: 本发明的目的是提供一种乙烯基聚合物的制造方法，该方法可以提供乙烯基聚合物，从而有效地除去聚合催化剂。 乙烯基聚合物的制造方法技术领域本发明涉及一种乙烯基聚合物的制造方法，其中在极性溶剂的存在下，用氧气处理聚合完成时的乙烯基聚合物。 更优选地，本发明涉及一种将相对介电常数在20℃以上的极性溶剂加入不低于10的聚合物的方法，该极性溶剂与氧气和惰性气体如氮气的混合气体接触， 氧浓度低于该溶剂的爆炸极限氧浓度，如作为纯组分的发生状态。

公开(公告)号：US06794461B2

公开(公告)日：2004-09-21

申请号：US09938310

申请日：2001-08-24

Applicant: Nao Fujita ,  Kenichi Kitano ,  Yoshiki Nakagawa

Inventor： Nao Fujita ,  Kenichi Kitano ,  Yoshiki Nakagawa

IPC: C08F814

CPC classification number: C08F8/42 ,  C08F6/02 ,  C08F8/04 ,  C08F8/06

Abstract: This invention provides a method for purification of a vinyl polymer which comprises the atom transfer radical polymerization of a vinyl monomer using a transition metal complex as the polymerization catalyst, said vinyl polymer being brought into contact with an oxidizing agent or a reducing agent.

Abstract translation: 本发明提供了一种乙烯基聚合物的纯化方法，其包括使用过渡金属络合物作为聚合催化剂的乙烯基单体的原子转移自由基聚合，所述乙烯基聚合物与氧化剂或还原剂接触。