Pigment compositions containing substituted amido phthalocyanine derivatives
    1.
    发明授权
    Pigment compositions containing substituted amido phthalocyanine derivatives 有权
    含有取代的酰氨基酞菁衍生物的颜料组合物

    公开(公告)号:US06284031B1

    公开(公告)日:2001-09-04

    申请号:US09619397

    申请日:2000-07-19

    申请人: Thomas Healy

    发明人: Thomas Healy

    IPC分类号: C09B4704

    摘要: A pigment composition comprising pigment and an amido phthalocyanine compound having the general formula I: MPc—(CONR1R2)n  I wherein which Pc is a phthalocyanine ring which is optionally further substituted by up to an average of one chlorine or bromine atom or of a sulphonic acid; M is hydrogen or a metal such as Mg, Al, Ni, Fe, Zn, Pb, Sn or Cu: n is a number ranging from 0.1 to 4.0; R1 and R2 are independently selected from hydrogen, C1-C20 alkyl, C5-C12 cycloalkyl, C7-C12 aralkyl, C6-C10 aryl, C4-C6 alkyl amino alkyl, C2-C20 aliphatic amine, C2-C20 aliphatic amine acid salt, C2-C20 alcohol, polyoxyalkylene, polyoxyalkylene amine.

    摘要翻译: 一种颜料组合物,其包含颜料和具有通式I的酰氨基酞菁化合物:其中Pc是任选进一步被至多平均一个氯或溴原子或磺酸取代的酞菁环; M是氢或金属如Mg,Al,Ni,Fe,Zn,Pb,Sn或Cu:n为0.1至4.0的数; R1和R2独立地选自氢,C1-C20烷基,C5-C12环烷基,C7-C12芳烷基,C6-C10芳基,C4-C6烷基氨基烷基,C2-C20脂族胺,C2-C20脂族胺酸盐, C2-C20醇,聚氧化烯,聚氧化烯胺。

    Composite pigments, coloring compositions, and image recording substances
    2.
    发明授权
    Composite pigments, coloring compositions, and image recording substances 有权
    复合颜料,着色组合物和图像记录物质

    公开(公告)号:US06368399B1

    公开(公告)日:2002-04-09

    申请号:US09614713

    申请日:2000-07-12

    IPC分类号: C09B4704

    摘要: A composite pigment of a bluish green color comprises copper phthalocyanine and aluminum phthalocyanine which are preferably in the form of a mixture or solid solution. The composite pigment can be produced by mixing copper phthalocyanine and aluminum phthalocyanine into a mixture and then converting said mixture into a pigment form. A coloring composition comprises at least a resin and a pigment which comprises copper phthalocyanine and aluminum phthalocyanine. The coloring composition can be produced by mixing copper phthalocyanine and aluminum phthalocyanine which have been independently comminuted, into a composite pigment, and then kneading the pigment and a resin such that the pigment is dispersed in the resin. An image recording substance is produced using the coloring composition. The image recording substance can be a dry developer of a fine powder form or a wet developer of a liquid form, an ink-jet ink, or a thermal transfer ink ribbon with the coloring composition coated on a film-shaped or sheet-shaped base material.

    摘要翻译: 蓝绿色的复合颜料包括铜酞菁和铝酞菁,其优选为混合物或固溶体形式。 复合颜料可以通过将铜酞菁和铝酞菁混合到混合物中,然后将所述混合物转化为颜料形式来制备。 着色组合物至少包含树脂和包含铜酞菁和铝酞菁的颜料。 着色组合物可以通过将已经独立粉碎的铜酞菁和铝酞菁混合到复合颜料中,然后捏合颜料和树脂使得颜料分散在树脂中来制备。 使用着色组合物制造图像记录物质。 图像记录物质可以是细粉末形式的干燥显影剂或液体形式的湿式显影剂,喷墨油墨或具有着色组合物的热转印墨带涂覆在薄膜状或片状基材上 材料。

    Phthalocyanine compound, method for production thereof, and near infrared absorption dye using the compound
    3.
    发明授权
    Phthalocyanine compound, method for production thereof, and near infrared absorption dye using the compound 有权
    酞菁化合物,其制备方法和使用该化合物的近红外吸收染料

    公开(公告)号:US06323340B1

    公开(公告)日:2001-11-27

    申请号:US09624637

    申请日:2000-07-24

    IPC分类号: C09B4704

    摘要: A phthalocyanine compound is provided which exhibits particularly high transmittance to a visible ray, offers a highly efficient cut of a near infrared ray, excels in the ability to effect selective absorption in a near infrared region, excels in the solubility in a solvent, excels in the compatibility with a resin, and excels in heat resistance, light resistance, and weatherability, a method for the production thereof, a near infrared absorbable dye using the same, and a heat ray shielding material, a plasma display grade filter and a near infrared absorbable material formed thereof. The phthalocyanine compound of this invention is represented by the following formula (1): wherein Z2, Z3, Z6, Z7, Z10, Z11, Z14, and Z15 independently stand for SR1, OR2, or a halogen atom, provided that at least one of them stands for SR1 or OR2; Z1, Z4, Z5, Z5, Z9, Z12, Z13, and Z16 independently stand for NHR3, SR1, OR2, or a halogen atom, provided that at least one of them stands for NHR3 and at least four of them stand for OR2; a plurality of R1, R2, and R3, independently to each other, stand for a substituted or non-substituted phenyl group, a substituted or non-substituted aralkyl group, or a substituted or non-substituted alkyl group of 1 to 20 carbon atoms; and M stands for a nonmetal, a metal, a metal oxide, or a metal halide.

    摘要翻译: 提供了对可见光线具有特别高的透射率的酞菁化合物,提供近红外线的高效切割,在近红外区域中实现选择性吸收的能力优异,在溶剂中的溶解性优异 与树脂的相容性,耐热性,耐光性和耐候性优异,其制造方法,使用该树脂的近红外可吸收染料,以及热射线屏蔽材料,等离子体显示级过滤器和近红外 由其形成的可吸收材料。 本发明的酞菁化合物由下式(1)表示:其中Z2,Z3,Z6,Z7,Z10,Z11,Z14和Z15独立地代表SR1,OR2或卤原子,条件是至少一个 代表SR1或OR2; Z 1,Z 4,Z 5,Z 5,Z 9,Z 12,Z 13和Z 16独立地代表NHR 3,SR 1,OR 2或卤原子,条件是它们中至少有一个代表NHR 3,并且至少有四个代表OR2; 多个R1,R2和R3彼此独立地表示取代或未取代的苯基,取代或未取代的芳烷基或取代或未取代的碳原子数1〜20的烷基 ; M代表非金属,金属,金属氧化物或金属卤化物。

    Fluorescent labeling complexes with large stokes shift formed by coupling together cyanine and other fluorochromes capable of resonance energy transfer
    4.
    发明授权
    Fluorescent labeling complexes with large stokes shift formed by coupling together cyanine and other fluorochromes capable of resonance energy transfer 有权
    通过将能够共振能量转移的花青和其它荧光染料耦合在一起而形成具有大的斯克利克斯位移的荧光标记复合物

    公开(公告)号:US06673943B2

    公开(公告)日:2004-01-06

    申请号:US10300459

    申请日:2002-11-20

    IPC分类号: C09B4704

    摘要: The present invention provides low molecular weight fluorescent labeling complexes with large wavelength shifts between absorption of one dye in the complex and emission from another dye in the complex. These complexes can be used, for example, for multiparameter fluorescence cell analysis using a single excitation wavelength. The low molecular weight of the complex permits materials labeled with the complex to penetrate cell structures for use as probes. The labeling complexes are synthesized by covalently attaching through linkers at least one cyanine fluorochrome to another low molecular weight fluorochrome to form energy donor-acceptor complexes. Resonance energy transfer from an excited donor to fluorescent acceptor provides wavelength shifts up to 300 nm. The fluorescent labeling complexes preferably contain reactive groups for the labeling of functional groups on target compounds, such as derivatized oxy and deoxy polynucleic acids, antibodies, enzymes, proteins and other materials. The complexes may also contain functional groups permitting covalent reaction with materials containing reactive groups.

    摘要翻译: 本发明提供了在复合物中的一种染料的吸收和复合物中另一种染料的发射之间具有大的波长偏移的低分子量荧光标记复合物。 这些复合物可用于例如使用单个激发波长的多参数荧光细胞分析。 复合物的低分子量允许用复合物标记的材料穿透细胞结构用作探针。 通过将至少一个花青荧光染料共价连接到另一个低分子量荧光染料上以形成能量供体 - 受体复合物来合成标记复合物。 从受激供体到荧光受体的共振能量转移提供高达300nm的波长漂移。 荧光标记复合物优选含有用于标记靶化合物上的官能团的反应性基团,例如衍生的氧基和脱氧多核酸,抗体,酶,蛋白质和其它材料。 络合物还可以含有允许与含有反应性基团的材料共价反应的官能团。

    Fluorochromes labelling complexes with large stokes shift formed by coupling together cyanine and other fluorochromes capable of resonance energy transfer
    5.
    发明授权
    Fluorochromes labelling complexes with large stokes shift formed by coupling together cyanine and other fluorochromes capable of resonance energy transfer 有权
    通过将能够进行共振能量转移的花青和其它荧光染料耦合在一起而形成的具有大的斯托克斯位移的荧光色素标记复合物

    公开(公告)号:US06545164B1

    公开(公告)日:2003-04-08

    申请号:US09413998

    申请日:1999-10-07

    IPC分类号: C09B4704

    摘要: The present invention provides low molecular weight fluorescent labeling complexes with large wavelength shifts between absorption of one dye in the complex and emission from another dye in the complex. These complexes can be used, for example, for multiparameter fluorescence cell analysis using a single excitation wavelength. The low molecular weight of the complex permits materials labeled with the complex to penetrate cell structures for use as probes. The labeling complexes are synthesized by covalently attaching through linkers at least one cyanine fluorochrome to another low molecular weight fluorochrome to form energy donor-acceptor complexes. Resonance energy transfer from an excited donor to fluorescent acceptor provides wavelength shifts up to 300 nm. The fluorescent labeling complexes preferably contain reactive groups for the labeling of functional groups on target compounds, such as derivatized oxy and deoxy polynucleic acids, antibodies, enzymes, proteins and other materials. The complexes may also contain functional groups permitting covalent reaction with materials containing reactive groups.

    摘要翻译: 本发明提供了在复合物中的一种染料的吸收和复合物中另一种染料的发射之间具有大的波长偏移的低分子量荧光标记复合物。 这些复合物可用于例如使用单个激发波长的多参数荧光细胞分析。 复合物的低分子量允许用复合物标记的材料穿透细胞结构用作探针。 通过将至少一个花青荧光染料共价连接到另一个低分子量荧光染料上以形成能量供体 - 受体复合物来合成标记复合物。 从受激供体到荧光受体的共振能量转移提供高达300nm的波长漂移。 荧光标记复合物优选含有用于标记靶化合物上的官能团的反应性基团,例如衍生的氧基和脱氧多核酸,抗体,酶,蛋白质和其它材料。 络合物还可以含有允许与含有反应性基团的材料共价反应的官能团。

    Soluble chromophores having improved solubilizing groups
    7.
    发明授权
    Soluble chromophores having improved solubilizing groups 有权
    可溶性发色团具有改善的增溶基团

    公开(公告)号:US06274728B1

    公开(公告)日:2001-08-14

    申请号:US09465868

    申请日:1999-12-16

    IPC分类号: C09B4704

    摘要: Compounds of formula A(B)x  (I), wherein x is an integer from 1 to 8, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, indanthrone, isoindolinone, isoindoline, dioxazine, azo, phthalocyanine or diketopyrrolopyrrole series that is bonded to x groups B via one or more hetero atoms, those hetero atoms being selected from the group consisting of N, O and S and forming part of the radical A, each group B independently of any other(s) is hydrogen or a group of the formula  at least one group B being a group of the formula The compounds according to the invention are used in high-molecular-weight organic materials, thermo-, photo- or chemo-sensitive recording materials, light-sensitive negative or positive resist compositions, ink compositions for ink-jet printing and color tapes for thermal transfer printing.

    摘要翻译: 甲醛的化合物是1至8的整数,A是与x基团键合的喹吖啶酮,蒽醌,苝,靛蓝,喹酞酮,阴丹酮,异吲哚啉酮,异吲哚啉,二恶嗪,偶氮,酞菁或二酮吡咯并吡咯系列的发色团的基团 B通过一个或多个杂原子,那些杂原子选自N,O和S并形成部分基团A,每个基团B独立地为任何其它基团,是氢或式 至少一组B是下式的基团根据本发明的化合物用于高分子量有机材料,热敏,光敏或化学敏感记录材料,感光负片或正光刻胶组合物,用于 喷墨打印和热转印打印用彩带。

    Process for preparing titanyl phthalocyanine crystal by solvent treatment of amorphous or quasi-amorphous titanyl phthalocyanine
    8.
    发明授权
    Process for preparing titanyl phthalocyanine crystal by solvent treatment of amorphous or quasi-amorphous titanyl phthalocyanine 失效
    通过溶剂处理无定形或准无定形氧钛酞菁制备钛氧酞菁晶体的方法

    公开(公告)号:US06232466B1

    公开(公告)日:2001-05-15

    申请号:US07674762

    申请日:1991-03-19

    IPC分类号: C09B4704

    CPC分类号: C09B67/0016 C09B67/0026

    摘要: A process for preparing a stable titanyl phthalocyanine crystal showing at least one diffraction peak at a Bragg angle (2&thgr;±0.2) of 27.3° is disclosed, which comprises treating amorphous or quasi-amorphous titanyl phthalocyanine with a solvent selected from an alcohol solvent, an aromatic solvent, a mixed solvent of an alcohol solvent and an aromatic solvent, or a mixed solvent of an alcohol solvent and water. The resulting titanyl phthalocyanine exhibits high photosensitivity and excellent durability as a photoconductive material of an electrophotographic photoreceptor.

    摘要翻译: 公开了一种制备稳定的氧钛酞菁晶体的方法,其显示出在布拉格角(2θ±0.2°)为27.3°的至少一个衍射峰,其包括用溶剂选择醇或溶剂,处理无定形或准无定形氧钛酞菁 芳族溶剂,醇溶剂和芳香族溶剂的混合溶剂,醇溶剂和水的混合溶剂。 所得的酞菁酞菁作为电子照相感光体的感光材料显示出高的光敏性和优异的耐久性。