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公开(公告)号：WO2007068965A2
公开(公告)日：2007-06-21
申请号：PCT/GB2006/004748
申请日：2006-12-18
Inventor： GIDDIS, Clive, Robert , STEWART, Paul, Hendry
CPC classification number: C07C19/12 , C07C17/206 , C07C17/21 , C07C19/08
Abstract: A process for the production of dichlorotrifluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride (HF) at elevated temperature in the vapour phase in at least one reactor in the presence of a fluorination catalyst. The process is operated so that 30 weight % or more of the perchloroethylene reactant that is fed to the at least one reactor remains unreacted having passed through the or each reactor. The dichlorotrifluoroethane may be purified and then used as it is or used to prepare pentafiuoroethane.
Abstract translation: 描述了制备二氯三氟乙烷的方法。 该方法包括在升温的温度下，在氟化催化剂存在下，在至少一个反应器中，使气相中的全氯乙烯与氟化氢（HF）反应。 操作该方法使得进料到至少一个反应器的30重量％或更多的全氯乙烯反应物保持未反应，通过该反应器或每个反应器。 二氯三氟乙烷可以纯化，然后原样使用或用于制备五氟乙烷。
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公开(公告)号：WO2007068964A2
公开(公告)日：2007-06-21
申请号：PCT/GB2006/004747
申请日：2006-12-18
Inventor： GIDDIS, Clive, Robert , STEWART, Paul, Hendry
CPC classification number: C07C17/206 , C07C17/21 , C07C19/08 , C07C19/12
Abstract: A process for the production of dichlorotrifluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride in the vapour phase at elevated temperature in at least one reactor in the presence of a fluorination catalyst to produce a composition comprising dichlorotrifluoroethane, hydrogen chloride, unreacted perchloroethylene and unreacted hydrogen fluoride. The composition that is produced is subjected to a separation step to recover a first fraction comprising dichlorotrifluoroethane and a second fraction comprising perchloroethylene and hydrogen fluoride. The second fraction is further separated into a hydrogen fluoride-rich fraction and a perchloroemylene-containing, organic-rich fraction which are then recycled. The dichlorotrifluoroethane that is recovered may be used to prepare pentafluoroethane.
Abstract translation: 描述了生产二氯三氟乙烷的方法。 该方法包括在氟化催化剂存在下在至少一个反应器中在高温下使全氯乙烯与氟化氢在气相中反应，以产生包含二氯三氟乙烷，氯化氢，未反应的全氯乙烯和未反应的氟化氢的组合物。 生产的组合物经历分离步骤以回收包含二氯三氟乙烷的第一馏分和包含全氯乙烯和氟化氢的第二馏分。 第二馏分进一步分离成富含氟化氢的馏分和含全氯乙烯的富含有机物馏分，然后将其再循环。 回收的二氯三氟乙烷可用于制备五氟乙烷。
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公开(公告)号：WO2007068962A2
公开(公告)日：2007-06-21
申请号：PCT/GB2006/004738
申请日：2006-12-18
Inventor： GIDDIS, Clive, Robert , STEWART, Paul, Hendry
CPC classification number: C07C17/206 , C07C17/21 , C07C19/08 , C07C19/12
Abstract: A process for the production of pentafluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride in the vapour phase in a first reactor or a first plurality of reactors in the presence of a fluorination catalyst to produce a composition comprising dichlorotrifluoroethane, hydrogen chloride, unreacted hydrogen fluoride and perchloroethylene. This composition is subjected to a separation step to yield a purified composition comprising at least 95 weight % of dichlorotrifluoroethane and less than 0.5 weight % of compounds having the formula C 2 C 16-X F X , where x is an integer of from 0 to 6, based on the total weight of organic compounds in the composition. The composition from the separation step is then reacted with hydrogen fluoride in the vapour phase in a second reactor or a second plurality of reactors in the presence of a fluorination catalyst to produce a composition comprising pentafluoroethane and less than 0.5 weight % of chloropentafluoroethane, based on the total weight of organic compounds in the composition.
Abstract translation: 描述了生产五氟乙烷的方法。 该方法包括使全氯乙烯与氟化氢在气相中在第一反应器或第一多个反应器中在氟化催化剂存在下反应以产生包含二氯三氟乙烷，氯化氢，未反应的氟化氢和全氯乙烯的组合物。 使该组合物经历分离步骤以产生包含至少95重量％的二氯三氟乙烷和小于0.5重量％的具有式C 2-16 C 16 -X的化合物的纯化组合物， 其中x是0至6的整数，基于组合物中有机化合物的总重量。 然后使来自分离步骤的组合物与氟化氢在气相中在第二反应器或第二多个反应器中在氟化催化剂存在下反应以产生包含五氟乙烷和小于0.5重量％的氯五氟乙烷的组合物，基于 组合物中有机化合物的总重量。
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公开(公告)号：WO02079129A3
公开(公告)日：2002-12-05
申请号：PCT/GB0201544
申请日：2002-03-28
Applicant: INEOS FLUOR HOLDINGS LTD , FLAHERTY STEPHEN ANDREW , STEWART PAUL HENDRY
Inventor： FLAHERTY STEPHEN ANDREW , STEWART PAUL HENDRY
IPC: C07C17/395
CPC classification number: C07C17/395
Abstract: A process for removing one or more unsaturated halocarbons from a halocarbon mixture comprising one or more unsaturated halocarbons and one or more saturated halocarbons, which process comprises contacting the halocarbon mixture with a mixture of a solid chemical oxidant and a solid support in the presence of water.
Abstract translation: 一种从包含一种或多种不饱和卤化碳和一种或多种饱和卤化碳的卤代烃混合物中除去一种或多种不饱和卤代烃的方法，该方法包括在水存在下使卤代烃混合物与固体化学氧化剂和固体载体的混合物接触 。
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公开(公告)号：WO2002079129A2
公开(公告)日：2002-10-10
申请号：PCT/GB2002/001544
申请日：2002-03-28
Inventor： FLAHERTY, Stephen, Andrew , STEWART, Paul, Hendry
IPC: C07C17/395
CPC classification number: C07C17/395
Abstract: A process for removing one or more unsaturated halocarbons from a halocarbon mixture comprising one or more unsaturated halocarbons and one or more saturated halocarbons, which process comprises contacting the halocarbon mixture with a mixture of a solid chemical oxidant and a solid support in the presence of water.
Abstract translation: 一种从包含一种或多种不饱和卤代烃和一种或多种饱和卤代烃的卤代烃混合物中除去一种或多种不饱和卤代烃的方法，该方法包括在水存在下将卤代烃混合物与固体化学氧化剂和固体载体的混合物接触 。
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Patent Agency Ranking
公开(公告)号：WO2007068964A3
公开(公告)日：2007-07-26
申请号：PCT/GB2006004747
申请日：2006-12-18
Applicant: INEOS FLUOR HOLDINGS LTD , GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
Inventor： GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
CPC classification number: C07C17/206 , C07C17/21 , C07C19/08 , C07C19/12
Abstract: A process for the production of dichlorotrifluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride in the vapour phase at elevated temperature in at least one reactor in the presence of a fluorination catalyst to produce a composition comprising dichlorotrifluoroethane, hydrogen chloride, unreacted perchloroethylene and unreacted hydrogen fluoride. The composition that is produced is subjected to a separation step to recover a first fraction comprising dichlorotrifluoroethane and a second fraction comprising perchloroethylene and hydrogen fluoride. The second fraction is further separated into a hydrogen fluoride-rich fraction and a perchloroemylene-containing, organic-rich fraction which are then recycled. The dichlorotrifluoroethane that is recovered may be used to prepare pentafluoroethane.
Abstract translation: 描述了制备二氯三氟乙烷的方法。 该方法包括使气相中的全氯乙烯与氟化氢在高温下在至少一个反应器中在氟化催化剂的存在下反应，以产生包含二氯三氟乙烷，氯化氢，未反应的全氯乙烯和未反应的氟化氢的组合物。 对所生产的组合物进行分离步骤以回收包含二氯三氟乙烷的第一级分和包含全氯乙烯和氟化氢的第二馏分。 将第二级分进一步分离成富含氟化氢的级分和含全氯氯苯的富含有机物的级分，然后将其再循环。 回收的二氯三氟乙烷可用于制备五氟乙烷。
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公开(公告)号：WO2007068967A1
公开(公告)日：2007-06-21
申请号：PCT/GB2006/004763
申请日：2006-12-18
Inventor： GIDIS, Clive, Robert , STEWART, Paul, Hendry
CPC classification number: C07C17/206 , C07C17/21 , C07C19/08 , C07C19/12
Abstract: A process for the production of dichlorotrifluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride (HF) at elevated temperature in the vapour phase in at least one reactor in the presence of a fluorination catalyst. The process is operated so that the increase in temperature across the or each reactor from the inlet side to the outlet side is controlled. The dichlorotrifluoroethane may be purified and then used as it is or used to prepare pentafluoroethane.
Abstract translation: 描述了制备二氯三氟乙烷的方法。 该方法包括在升温的温度下，在氟化催化剂存在下，在至少一个反应器中，使气相中的全氯乙烯与氟化氢（HF）反应。 操作该过程使得控制从入口侧到出口侧的每个反应器的温度升高。 二氯三氟乙烷可以纯化，然后原样使用或用于制备五氟乙烷。
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公开(公告)号：WO2002018304A3
公开(公告)日：2002-03-07
申请号：PCT/GB2001/003945
申请日：2001-09-03
Inventor： GIDDIS, Clive, Robert , STEWART, Paul, Hendry
IPC: C07C19/08
Abstract: A process for the production of a hydrofluoroalkane, which process comprises contacting a hydrochlorofluoroethane of formula CC1XYCFHZ, wherein X and Y are each independently chlorine or fluorine and Z is chlorine, fluorine or hydrogen, in the liquid phase with hydrogen fluoride and a fluorination catalyst and recovering a hydrofluoroalkane from the resulting products.
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公开(公告)号：WO2007068962A3
公开(公告)日：2007-07-26
申请号：PCT/GB2006004738
申请日：2006-12-18
Applicant: INEOS FLUOR HOLDINGS LTD , GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
Inventor： GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
CPC classification number: C07C17/206 , C07C17/21 , C07C19/08 , C07C19/12
Abstract: A process for the production of pentafluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride in the vapour phase in a first reactor or a first plurality of reactors in the presence of a fluorination catalyst to produce a composition comprising dichlorotrifluoroethane, hydrogen chloride, unreacted hydrogen fluoride and perchloroethylene. This composition is subjected to a separation step to yield a purified composition comprising at least 95 weight % of dichlorotrifluoroethane and less than 0.5 weight % of compounds having the formula C 2 C 16-X F X , where x is an integer of from 0 to 6, based on the total weight of organic compounds in the composition. The composition from the separation step is then reacted with hydrogen fluoride in the vapour phase in a second reactor or a second plurality of reactors in the presence of a fluorination catalyst to produce a composition comprising pentafluoroethane and less than 0.5 weight % of chloropentafluoroethane, based on the total weight of organic compounds in the composition.
Abstract translation: 描述了生产五氟乙烷的方法。 该方法包括在氟化催化剂存在下，在第一反应器或第一多个反应器中，使气相中的全氯乙烯与氟化氢反应，生成包含二氯三氟乙烷，氯化氢，未反应的氟化氢和全氯乙烯的组合物。 将该组合物进行分离步骤以产生包含至少95重量％的二氯三氟乙烷和小于0.5重量％的具有式C 2 C 16-16的化合物的纯化组合物， 基于组合物中有机化合物的总重量，其中x是0至6的整数。 然后在氟化催化剂的存在下，在第二反应器或第二多个反应器中，分离步骤的组合物与气相中的氟化氢反应，以产生包含五氟乙烷和小于0.5重量％氯五氟乙烷的组合物，基于 组合物中有机化合物的总重量。
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公开(公告)号：WO2007068965A3
公开(公告)日：2007-07-26
申请号：PCT/GB2006004748
申请日：2006-12-18
Applicant: INEOS FLUOR HOLDINGS LTD , GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
Inventor： GIDDIS CLIVE ROBERT , STEWART PAUL HENDRY
CPC classification number: C07C19/12 , C07C17/206 , C07C17/21 , C07C19/08
Abstract: A process for the production of dichlorotrifluoroethane is described. The process comprises reacting perchloroethylene with hydrogen fluoride (HF) at elevated temperature in the vapour phase in at least one reactor in the presence of a fluorination catalyst. The process is operated so that 30 weight % or more of the perchloroethylene reactant that is fed to the at least one reactor remains unreacted having passed through the or each reactor. The dichlorotrifluoroethane may be purified and then used as it is or used to prepare pentafiuoroethane.
Abstract translation: 描述了生产二氯三氟乙烷的方法。 该方法包括在氟化催化剂存在下，在至少一个反应器中在高温下在气相中使全氯乙烯与氟化氢（HF）反应。 该方法操作使得加入到至少一个反应器中的30重量％或更多的全氯乙烯反应物保持未反应并穿过该反应器或每个反应器。 二氯三氟乙烷可以被纯化，然后直接使用或用于制备五氟乙烷。
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