公开(公告)号：WO1998023708A1

公开(公告)日：1998-06-04

申请号：PCT/US1996019112

申请日：1996-11-25

Applicant: ASHLAND INC. ,  MALONE, Donald, P.

Inventor： ASHLAND INC.

IPC: C10J03/06

CPC classification number: C01B17/162 ,  C10J3/57

Abstract: Hydrogen sulfide is produced by charging a sulfur containing feed to a molten metal bath containing over 3 wt.% dissolved carbon. Allowing dissolved carbon levels to build up in the bath, preferably by controlling oxygen addition to ensure a large inventory of dissolved carbon, creates a reducing "atmosphere" in the molten metal bath which allows most of the feed sulfur to be converted to H2S, which can be converted to elemental sulfur using a Claus unit or similar technology. Oxygen addition, to burn carbon from the bath, preferably occurs at a different time or place in the bath than the time or place of sulfur containing feed addition.

Abstract translation: 通过将含硫进料装入含有超过3重量％溶解碳的熔融金属浴来制备硫化氢。 允许溶解的碳水平在浴中积聚，优选通过控制氧气添加以确保大量溶解的碳储存，在熔融金属浴中产生减少的“气氛”，其允许大部分进料硫转化为H 2 S，其中 可以使用Claus单元或类似技术转化为元素硫。 从浴中燃烧碳的氧添加优选在与含硫进料添加的时间或地点相比在浴中不同的时间或地点进行。

公开(公告)号：WO1997046637A1

公开(公告)日：1997-12-11

申请号：PCT/US1996009062

申请日：1996-06-04

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  HETTINGER, William, P., Jr. ,  MAYO, Sharon, L.

IPC: C10G11/04

CPC classification number: C10G11/05

Abstract: An improved "magnetic hook"-promoted catalytic process, catalyst and method of manufacture for heavy hydrocarbon conversion, optionally in the presence of nickel and vanadium on the catalyst and in the feed stock to produce lighter molecular weight fractions, including more gasoline, lower olefins and higher isobutane than normally produced. This process is based on the discovery that two "magnetic hook" elements, namely manganese and chromium, previously employed as magnetic enhancement agents to facilitate removal of old catalyst, or to selectively retain expansive catalysts, can also themselves function as selective cracking catalysts, particularly when operating on feeds containing significant amounts of nickel and vanadium, and especially where economics require operating with high nickel- and vanadium- contaminated and containing catalysts. Under such conditions, these promoted catalysts are more hydrogen and coke selective, have greater activity, and maintain that activity and superior selectivity in the presence of large amounts of contaminant metal, while also making more gasoline at a given conversion.

Abstract translation: 改进的“磁性钩” - 催化过程，催化剂和重质烃转化的制备方法，任选地在催化剂和原料中存在镍和钒的情况下，以产生更轻的分子量级分，包括更多的汽油，低级烯烃 和高于正常生产的异丁烷。 该方法基于以下发现：先前用作磁性增强剂以促进除去旧催化剂或选择性保留膨胀性催化剂的两种“磁性钩”元素即锰和铬也可以用作选择性裂解催化剂，特别是 当对含有大量镍和钒的饲料进行操作时，特别是在需要经高镍和钒污染和含有催化剂操作的地方。 在这种条件下，这些促进的催化剂具有更多的氢和焦炭选择性，具有更大的活性，并且在大量的污染金属的存在下保持该活性和优异的选择性，同时在给定的转化率下制造更多的汽油。

公开(公告)号：WO1997037798A1

公开(公告)日：1997-10-16

申请号：PCT/US1997005749

申请日：1997-04-10

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  CHEN, Chia-hung ,  SCHNEIDER, James, T.

IPC: B22D29/00

CPC classification number: B22C1/2273 ,  C08G18/1891 ,  C08G18/302 ,  C08G18/3206

Abstract: A binder for a mold or core prepared via a cold box process eliminates the use of organic solvents, the presence of free formaldehyde or phenol emanating from binders containing phenolic resins and prevents premature curing by the use of a binder comprising a polyol and an organic polyisocyanate. The binder is mixed with a foundry aggregate to form a foundry mix which is shaped into a mold or core in the presence of a gaseous tertiary amine catalyst. The mold or core is utilized in metal casting.

Abstract translation: 用于通过冷箱方法制备的模具或芯的粘合剂消除了使用有机溶剂，由含有酚醛树脂的粘合剂发出的游离甲醛或苯酚的存在，并通过使用包含多元醇和有机多异氰酸酯的粘合剂来防止过早固化 。 将粘合剂与铸造集料混合以形成在气态叔胺催化剂存在下成形为模具或芯体的铸造混合物。 模具或芯体用于金属铸造。

公开(公告)号：WO1996034913A1

公开(公告)日：1996-11-07

申请号：PCT/US1996005924

申请日：1996-04-29

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  HLIVKA, Linda, M. ,  WAI, George, K.

IPC: C08L05/00

CPC classification number: D21H21/02 ,  D21C9/086 ,  D21H17/32 ,  D21H17/53 ,  D21H17/72

Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) a nonionic polymer. The invention also relates to a process for inhibiting pitch deposition in pulp and papermaking systems and on papermaking equipment.

Abstract translation: 本发明涉及一种用于控制纸浆和造纸中沥青沉积的液体组合物，其包含（1）衍生的阳离子瓜尔胶的水溶液和（2）非离子聚合物。 本发明还涉及一种抑制纸浆和造纸系统和造纸设备中沥青沉积的方法。

公开(公告)号：WO1995026321A1

公开(公告)日：1995-10-05

申请号：PCT/US1995003251

申请日：1995-03-16

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  TWARDOWSKA, Helena, J. ,  LANGER, Heimo, J.

IPC: C04B12/04

CPC classification number: C04B28/26 ,  B22C1/186 ,  C04B12/005 ,  C04B2111/00939 ,  Y02P40/165 ,  C04B14/041 ,  C04B24/2623 ,  C04B40/0263

Abstract: This invention relates to heat curable foundry binder systems comprising as separate components (a) a caustic solution of an alkali silicate and (b) hydrated aluminum silicate. The solution is mixed with sand to form a foundry mix. The resulting foundry mix is shaped and heated at an elevated temperature to form a cured foundry shape. Heat is applied by warm air, baking in an oven, microwave, or preferably from hot-box equipment.

Abstract translation: 本发明涉及包含作为单独组分（a）碱性硅酸盐和（b）水合硅酸铝的苛性碱溶液的热可固化铸造粘合剂体系。 该溶液与砂混合形成铸造混合物。 所得的铸造混合物在升高的温度下成形和加热以形成固化的铸造形状。 热量通过暖风，烘箱，微波炉或热箱设备进行烘烤。

公开(公告)号：WO1998023709A1

公开(公告)日：1998-06-04

申请号：PCT/US1996019115

申请日：1996-11-25

Applicant: ASHLAND INC. ,  MALONE, Donald, P.

Inventor： ASHLAND INC.

IPC: C10J03/06

CPC classification number: C10J3/57

Abstract: Sequential processing of hydrogen rich and hydrogen deficient feeds (14 and 16) in a heat balanced, single molten metal bath (40) to produce both 90+ mole % hydrogen (90) and one or more lower purity vapor streams (140) is disclosed. The molten metal bath is heated by oxygen addition (18) to burn dissolved carbon from the bath and then cooled by sequential addition of two feeds with differing hydrogen contents. Preferably a 98 % hydrogen product with a pressure of at least 2 atm., absolute is obtained, along with a lower purity hydrogen containing stream and a separate carbon oxides flue gas stream.

Abstract translation: 公开了在热平衡的单一熔融金属浴（40）中富氢和缺氢进料（14和16）的顺序处理以产生90+摩尔％的氢气（90）和一种或多种较低纯度的蒸汽流（140） 。 通过加氧（18）将熔融金属浴加热以从浴中燃烧溶解的碳，然后通过连续添加具有不同氢含量的两种进料来冷却。 优选地，获得具有至少2个大气压的绝对压力为98％的氢产物，以及较低纯度的含氢气流和单独的碳氧化物烟道气流。

公开(公告)号：WO1998022385A1

公开(公告)日：1998-05-28

申请号：PCT/US1996018749

申请日：1996-11-22

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  MALONE, Donald, P.

IPC: C01B03/24

CPC classification number: C10J3/57 ,  C01B3/24 ,  C01B32/40 ,  C10J3/723 ,  C10J2300/1621 ,  C10J2300/1884 ,  C10K1/002 ,  C10K1/004 ,  C10K1/08 ,  Y02E60/36

Abstract: One or more (preferably three) simple single-chamber crucibles contain molten metal and are successively fed hydrocarbon feed to produce hydrogen, then fed oxygen-containing gas to produce CO, then fed hydrocarbon again, etc. Operation is controlled by a swing valving sequence under timer or composition control.

Abstract translation: 一个或多个（优选三个）简单的单室坩埚含有熔融金属，并且连续地进料烃进料以产生氢气，然后加入含氧气体以产生CO，然后再次进料碳氢化合物等。操作由摆动阀门序列 在定时器或组合控制下。

公开(公告)号：WO1998019808A1

公开(公告)日：1998-05-14

申请号：PCT/US1997019123

申请日：1997-10-20

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  SINGH, Rina ,  DAMMANN, Laurence, G.

IPC: B22C01/22

CPC classification number: B22C1/2273 ,  C08G18/2865 ,  C08G18/542 ,  C08G18/725

Abstract: The invention relates to amine modified polyisocyanates having urea linkages and their use in foundry binder systems. The modified polyisocyanates are prepared by reacting a polyisocyanate with an aliphatic primary or secondary amine. These amine modified polyisocyanates, along with a phenolic resole resin, are added to a foundry aggregate to form a foundry mix which is shaped and cured with an amine curing catalyst.

Abstract translation: 本发明涉及具有脲键的胺改性多异氰酸酯及其在铸造粘合剂体系中的用途。 改性的多异氰酸酯是通过使多异氰酸酯与脂族伯胺或仲胺反应来制备的。 将这些胺改性的多异氰酸酯与酚醛树脂树脂一起加入到铸造集料中以形成用胺固化催化剂成型和固化的铸造混合物。

公开(公告)号：WO1998014280A1

公开(公告)日：1998-04-09

申请号：PCT/US1997017563

申请日：1997-09-29

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  RUDY, Rosanna, Pall ,  ROMANO, Andrew, Anthony

IPC: B05D03/02

CPC classification number: C09D5/08 ,  C09D133/04 ,  C08L2666/28 ,  C08L2666/54

Abstract: This invention relates to a water-based coating comprising as separate components (A) a grind component comprising in admixture (1) a water compatible overbased alkaline earth alkyl-aryl sulfonate, (2) an organic amine, and (3) an inorganic borate corrosion inhibitor; and (B) a liquid component comprising (1) water, (2) an acrylic emulsion, (3) an organic amine. The coatings are particularly useful for coating ferrous metal surfaces.

Abstract translation: 本发明涉及一种水性涂料，其包含作为分离组分（A）的研磨组分，所述研磨组分包含（1）水溶性高碱性碱土烷基 - 芳基磺酸盐，（2）有机胺和（3）无机硼酸盐 缓蚀剂; 和（B）液体组分，其包含（1）水，（2）丙烯酸乳液，（3）有机胺。 涂层对于涂覆黑色金属表面特别有用。

公开(公告)号：WO1997018913A1

公开(公告)日：1997-05-29

申请号：PCT/US1996018595

申请日：1996-11-20

Applicant: ASHLAND INC.

Inventor： ASHLAND INC. ,  URREIZTIETA, Santiago, Prat ,  CASTELLANOS, Marco, Antonio, Mendizabel

IPC: B22C01/22

CPC classification number: B22C1/2253 ,  B22C9/123

Abstract: The invention relates to a cold-box process for preparing foundry shapes. The process involves curing a foundry shape by subjecting it to carbon dioxide and heat. The foundry shape is made by mixing an aggregate with a foundry binder comprising: (a) an aqueous basic solution of a phenolic resole resin; and (b) preferably a compound which is a source of an oxyanion. The invention also relates to a process of making metal castings with the foundry shapes.

Abstract translation: 本发明涉及用于制备铸造形状的冷箱方法。 该方法涉及通过使其成为二氧化碳和加热来固化铸造形状。 铸造形状通过将骨料与铸造粘合剂混合而制成，所述铸造粘合剂包括：（a）酚醛树脂树脂的碱性水溶液; 和（b）优选是作为氧阴离子源的化合物。 本发明还涉及制造具有铸造形状的金属铸件的方法。