HERBICIDAL HETEROCYCLICALLY ANNULATED BENZOYLISOTHIAZOLES
    92.
    发明申请
    HERBICIDAL HETEROCYCLICALLY ANNULATED BENZOYLISOTHIAZOLES 审中-公开
    除草剂杂环稠合的benzoylisothiazoles

    公开(公告)号:WO1997038988A1

    公开(公告)日:1997-10-23

    申请号:PCT/EP1997001858

    申请日:1997-04-14

    CPC classification number: C07D275/06 A01N43/80 C07D417/06

    Abstract: 4-benzoylisothiazoles have the general formula (1), in which the substituents have the following meanings: X stands for oxygen or sulphur; R stands for hydrogen, alkyl, alkenyl, alkinyl, optionally substituted alkoxycarbonyl, aryl, heterocyclyl or hetaryl; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cyclalkenyl, aryl, hetaryl or heterocyclyl; and R stands for a radical of general formulas (2a-d), in which n, A, B and the R , R and R substituents have the meanings given in claim 1. Also disclosed are the salts commonly used in agriculture of the 4-benzoylisothiazoles of general formula (1), a process for preparing the same and their use as herbicides.

    Abstract translation: 4- benzoylisothiazoles通式(1),其中取代基具有以下含义:X是氧或硫; [R <1>是氢,烷基,烯基,炔基; 未取代的或取代的。 烷; 未取代的或取代的。 的芳基,未取代的或取代的。 杂环基或未取代的或取代的。 杂芳基; [R <2>是氢,烷基,烯基,炔基,环烷基或环烯基,芳基,杂芳基,或杂环基; [R <3>基为通式(2a-d)的其中n,A,B和取代基R <4>,R <5>和R <6>具有权利要求1所示的含义,和农业上的习惯 4- benzoylisothiazoles通式(1)的盐,它们的制备方法和它们作为除草剂的用途。

    2-HETAROYLCYCLOHEXANE-1,3-DIONES
    93.
    发明申请
    2-HETAROYLCYCLOHEXANE-1,3-DIONES 审中-公开
    2- HETAROYLCYCLOHEXAN -1,3-二酮

    公开(公告)号:WO1997030986A1

    公开(公告)日:1997-08-28

    申请号:PCT/EP1997000802

    申请日:1997-02-20

    CPC classification number: A01N43/32 C07D327/06 C07D339/08

    Abstract: The invention concerns hetaroyl derivatives of formula (I) in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, wherein these groups can optionally be substituted by between one and five halogen atoms or C1-C4 alkoxy; halogen, cyano, nitro; X is oxygen or sulphur which can be substituted by one or two oxygens; n is zero, one, two; and Q, R , R , R , R have the meanings given in claim 1. The invention further concerns a process for preparing the hetaroyl derivatives, agents containing the latter, and the use of these derivatives or agents containing them for weed control.

    Abstract translation: 式(I),其中取代基具有以下含义的杂芳酰基衍生物:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可以是至多5个卤素原子或C1-C4烷氧基; 卤素,氰基,硝基; X是氧或可以与一个或两个氧被取代的硫; n是零,一,二; Q,R <1>,R <2>,R <3>,R <4>具有权利要求1中所示的含义,用于制备的杂芳酰基衍生物的方法,含有它们的组合物以及使用这些衍生物或组合物,其包括 控制杂草。

    2-CYANO-1,3-DIONE DERIVATIVES, THE PRODUCTION OF SAME AND THEIR USE AS HERBICIDES
    94.
    发明申请
    2-CYANO-1,3-DIONE DERIVATIVES, THE PRODUCTION OF SAME AND THEIR USE AS HERBICIDES 审中-公开
    2-氰基-1,3-二酮衍生物,其制备方法及其作为除草剂

    公开(公告)号:WO1997019071A1

    公开(公告)日:1997-05-29

    申请号:PCT/EP1996005065

    申请日:1996-11-18

    Abstract: The disclosure relates to phenyl diketone derivatives of formula I in which the substituents have the following meanings: L, M - hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(A)m-S(O)nR group or a -(A)m-CO-R group; Y - a group consisting of C=O, C=N-R , CR -NR R , CR -OR , CR R , CR -OR , hydrogen- or C1-C4-alkyl-substituted 1,3-dioxanyl or 1,3-dioxolanyl, a heteroatom selected from the group comprising oxygen, sulphur and nitrogen; X consists of a chain (-CR R -), (-CR R -CR R -), (-CR =CR -), (CR R -CR =CR -), or NR ; the bond between X and Y can be saturated or unsaturated; A - O, NR ; m is 0 or 1; n is 0, 1 or 2; R is cyclopropyl, 1-methylcyclopropyl; 1-méthylthiocyclopropyl or tert. butyl; when Y = C=O, X is different from NR . R to R and R to R have the meanings indicated in claim 1. Also disclosed are processes for producing these phenyl diketone derivatives, agents containing them and the use of the derivatives or agents containing them for weed control.

    Abstract translation: 式(I)中,Phenyldiketonderivate其中取代基具有以下含义:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可以是至多5个卤素原子或C1-C4烷氧基; 卤素,氰基,硝基,基团 - (A)的M-S(O)NR <1>或基团 - (A)的M-CO-R <2>; Y是选自C = O,C = NR <3>,CR <7> -NR <5> - [R <6>,CR <7>是-OR <8>,CR <10> - [R <11>,CR基团 <7> -SR <8>; 用氢或C1-C4烷基取代的1,3-二氧杂环己烷或1,3-二氧戊环基; 选自氧,硫和氮中选择的杂原子; X包括一个链(-CR <12> - [R <13> - )的,(-CR <12> - [R <13> -CR <21> - [R <22> - ),( - CR <12> = CR <13 > - ),( - CR <12> - [R <13> -CR <12> = CR <13> - ); NR <23>是X和Y可以是饱和的或不饱和的之间的键; A为O,NR <14>; m是0或1; n是零,1或2; [R <15>环丙基,1-甲基环丙基,1- Methylthiocyclopropyl或叔丁基; 其中,在Y = C = O,X是除NR <23>,R其它事件<1>至R <14>和R <16>至R <23>具有权利要求1给出的相同含义; 一种用于制备Phenyldiketonderivate的,含有这些药剂,以及使用这些衍生物或含有它们的禾本科杂草/杂草控制组合物的过程。

    HERBICIDAL BENZOYL DERIVATIVES
    96.
    发明申请
    HERBICIDAL BENZOYL DERIVATIVES 审中-公开
    除草剂苯甲酰

    公开(公告)号:WO1996026200A1

    公开(公告)日:1996-08-29

    申请号:PCT/EP1996000593

    申请日:1996-02-13

    Abstract: The invention concerns benzoyl derivatives of formula (I) in which the substituents have the following meanings: L and M represent hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy (these groups being optionally substituted by one to five halogen atoms or C1-C4 alkoxy), halogen, cyano, nitro, a -(Y)n-S(O)mR or -(Y)n-CO-R group; Z represents a five to six-membered heterocyclic saturated or unsaturated group containing one to three heteroatoms selected from the group comprising oxygen, sulphur and nitrogen and which can optionally be substituted by halogen, cyano, nitro, a -CO-R group, C1-C4 alkyl, C1-C4 alkyl halide, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 alkoxy halide, C1-C4 alkyl thio, C1-C4 alkyl thio halide, di-C1-C4 alkyl amino, phenyl optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, or an oxo group which can be present in the tautomeric form as a hydroxy group, is substituted or, together with a condensation-bound phenyl ring which is optionally substituted by halogen or, cyano, nitro, C1-C4 alkyl or C1-C4 alkyl halide, with a condensation-bound carbocycle or with a condensation-bound second heterocycle which can optionally be substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4 alkyl amino, C1-C4 alkoxy, C1-C4 alkoxy halide or a C1-C4 alkyl halide, forms a bicyclic system; Y represents O or NR ; n is 0 or 1; m is 0, 1 or 2; R represents C1-C4 alkyl, C1-C4 alkyl halide or NR R ; R represents C1-C4 alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or NR R ; R represents hydrogen or C1-C4 alkyl; R represents C1-C4 alkyl; Q represents a cyclohexane-1,2-dione ring connected at position 2 and of formula (II) in which R , R , R and R represent hydrogen or C1-C4 alkyl, R represents hydrogen, C1-C4 alkyl or a -COOR group, R represents hydrogen, C1-C4 alkyl, C3-C6 cycloalkyl, these groups optionally including one to three of the following substituents: halogen, C1-C4 alkyl thio, C1-C4 alkoxy, or R represents tetrahydropropanyl-3, tetrahydropropanyl-4 or tetrahydrothiopyranyl-3, or R and R together form a bond or a three to six-membered carbocyclic ring. The invention also concerns standard agricultural salts of compounds of formula (I) usually utilized in agriculture.

    Abstract translation: 式(I),其中取代基具有以下含义的苯甲酰衍生物:L,M是氢,C1-C6烷基,C2-C6链烯基,C2-C6炔基,C1-C4烷氧基,这些基团任选地被一个取代 可被取代到5个卤素原子或C1-C4烷氧基,卤素,氰基,硝基,基团 - (Y)N S(O)MR <7>或基团 - (Y)N-CO-R <8>,一个 5-或6-元杂环的饱和或含有选自氧,硫或氮中选择的一至三个杂原子的不饱和基团,其任选被卤素,氰基,硝基,基团-CO-R取代的<8>,C1- C4烷基,C1-C4卤代烷基,C3-C8环烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷硫基,C1-C4卤代烷硫基,二-C 1 -C 4 - 烷基氨基,任选地被取代的 卤素,氰基,硝基,C1-C4烷基或C1-C4卤代烷基取代的苯基或氧代基团,其也可以任选地以互变异构形式作为羟基存在,或在一个被取代的 稠合的,任选地被卤素,氰基,硝基,C1-C4烷基或C1-C4卤代烷基的苯环,稠合碳环或稠合的,任选被卤素取代,氰基,硝基,C1-C4烷基,二C1-C4取代的 烷基氨基,C1-C4烷氧基,C1-C4卤代烷氧基,或C1-C4卤代烷基取代的杂环第二形成双环体系; Y是O,NR <9>; n是0或1; m是零,1或2; [R <7> C1-C4烷基,C1-C4卤代烷基,或NR <9> - [R <10>; [R <8> C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,或NR <9> - [R <10>; [R <9>是氢或C1-C4烷基; [R <10> C1-C4烷基; Q,R <4>和R <6>表示一个在式环己烷-1,3-二酮环的2位连接(II)其中R <1>,R <2>是氢或C1-C4烷基, [R <5>是氢,C1-C4烷基或基团-COOR <10>,R <3>为氢,C1-C4烷基,C3-C6环烷基,这些基团任选地具有1至3个如下取代基取代的 可以:卤素,C1-C4烷硫基或C1-C4烷氧基,或R <3>为四氢吡喃基-3,四氢吡喃基-4或四氢噻喃基-3,或R <3>和R <5>一起代表一个键或 形成三至六元碳环,和化合物(I)的可农用常用盐。

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