NOVEL PHOSPHOR SYSTEMS FOR A WHITE LIGHT EMITTING DIODE (LED)

    公开(公告)号:WO2006022793A3

    公开(公告)日:2006-03-02

    申请号:PCT/US2004/039705

    申请日:2004-11-24

    Abstract: Novel phosphor systems for a white LED are disclosed. The phosphor systems are excited by a non-visible to near-UV radiation source having an excitation wavelength ranging from about 250 to 420 nm. The phosphor system may comprise one phosphor, two phosphors, and may include optionally a third and even a fourth phosphor. In one embodiment of the present invention, the phosphor is a two phosphor system having a blue phosphor and a yellow phosphor, wherein the long wavelength end of the blue phosphor is substantially the same wavelength as the short wavelength end of the yellow phosphor. Alternatively, there may be a wavelength gap between the yellow and blue phosphors. The yellow phosphor may be phosphate or silicate-based, and the blue phosphor may be silicate or aluminate-based. Single phosphor systems excited by non-visible radiation are also disclosed. In other embodiments of present invention, a single phosphor is used to produce white light illumination, the single phosphor having a broad emission spectrum with a peak intensity ranging from about 520 to 560 nm.

    NITRIDE PHOSPHORS WITH INTERSTITIAL CATIONS FOR CHARGE BALANCE
    14.
    发明申请
    NITRIDE PHOSPHORS WITH INTERSTITIAL CATIONS FOR CHARGE BALANCE 审中-公开
    硝酸盐磷酸盐与电荷平衡相互作用

    公开(公告)号:WO2013102222A1

    公开(公告)日:2013-07-04

    申请号:PCT/US2012/072336

    申请日:2012-12-31

    CPC classification number: C09K11/7734 C09K11/0883 C09K11/7731

    Abstract: Phosphors comprising a nitride-based composition represented by the chemical formula: M (x/v) (M' a M" b )Si (c-x) A1 x N d :RE, wherein: M is a divalent or trivalent metal with valence v; M' is at least one divalent metal; M" is at least one trivalent metal; 2a + 3b + 4c = 3d; and RE is at least one element selected from the group consisting of Eu, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb. Furthermore, the nitride-based composition may have the general crystalline structure of M' a M" b Si c N d , where A1 substitutes for Si within the crystalline structure and M is located within the crystalline structure substantially at the interstitial sites.

    Abstract translation: 包含由化学式M(x / v)(M'aM“b)Si(cx)Al x N d:RE表示的氮化物基组合物的荧光体,其中:M是价数v的二价或三价金属; M' 至少一种二价金属; M“是至少一种三价金属; 2a + 3b + 4c = 3d; RE为选自Eu,Ce,Pr,Nd,Sm,Gd,Tb,Dy,Ho,Er,Tm,Yb中的至少一种元素。 此外,基于氮化物的组合物可以具有M'aM“bSicNd”的一般结晶结构,其中A1代替晶体结构内的Si,并且M基本上位于间隙位置的晶体结构内。

    NITRIDE-BASED RED PHOSPHORS
    15.
    发明申请
    NITRIDE-BASED RED PHOSPHORS 审中-公开
    基于硝酸的红色磷光体

    公开(公告)号:WO2009142992A1

    公开(公告)日:2009-11-26

    申请号:PCT/US2009/043990

    申请日:2009-05-14

    CPC classification number: C09K11/0883 C09K11/7734 Y02B20/181

    Abstract: A nitride-based deep red phosphor having at least one of the following features: 1) an oxygen content less than about 2 percent by weight, and 2) a halogen content. Such phosphors are useful in the white light illumination industry, which utilizes the so-called "white LED." The selection and use of a rare earth halide as a raw material source of not only the activator for the phosphor, but also the halogen, is a feature of the present embodiments. The phosphors have the general formula MaMbBc(N,D):Eu2+, where Ma is a divalent alkaline earth metal such as Mg, Ca, Sr, Ba; Mb is a trivalent metal such as Al, Ga, Bi, Y, La, and Sm; and Mc is a tetravalent element such as Si, Ge, P, and B; N is nitrogen, and D is a halogen such as F, Cl, or Br. An exemplary compound is CaAlSi(N1-xFx): Eu2+.

    Abstract translation: 一种基于氮化物的深红色荧光体,其具有以下特征中的至少一个:1)氧含量小于约2重量%,和2)卤素含量。 这种荧光体在白光照明工业中是有用的,其利用了所谓的“白光LED”。 稀土卤化物作为不仅荧光体的活化剂,而且是卤素的原料来源的选择和使用是本实施方案的特征。 荧光体具有通式MaMbBc(N,D):Eu2 +,其中Ma是二价碱土金属如Mg,Ca,Sr,Ba; Mb是诸如Al,Ga,Bi,Y,La和Sm的三价金属; 并且Mc是四价元素如Si,Ge,P和B; N是氮,D是卤素如F,Cl或Br。 示例性化合物是CaAlSi(N1-xFx):Eu2 +。

    MULTIPLE-CHIP EXCITATION SYSTEMS FOR WHITE LIGHT EMITTING DIODES (LEDS)
    16.
    发明申请
    MULTIPLE-CHIP EXCITATION SYSTEMS FOR WHITE LIGHT EMITTING DIODES (LEDS) 审中-公开
    白光发光二极管(LED)的多芯片激励系统

    公开(公告)号:WO2009114390A2

    公开(公告)日:2009-09-17

    申请号:PCT/US2009/036214

    申请日:2009-03-05

    Abstract: Embodiments of the invention are directed toward white light illumination systems (so called 'white LEDs') that comprise a multi-chip excitation source and a phosphor package. In a two-chip source, the two LEDs may be UV-emitting and blue emitting, or blue-emitting and green-emitting. The phosphor package is configured to emit photoluminescence in wavelengths ranging from about 440 nm to about 700 nm upon co-excitation from the first and second radiation sources. The photoluminescence emitted by the phosphors is at least 40 percent of the total power in the white light illumination, and the portion of the total power in the white light illumination contributed by the first and second radiation sources (LEDs) is less than about 60 percent. This ratio can vary in alternative embodiments, and includes 50/50, 60/40, 70/30, and 80/20, respectively. The white light illumination emitted by the system has in one embodiment a color rendering index (CRI) greater than about 90.

    Abstract translation: 本发明的实施例涉及包括多芯片激励源和磷光体封装的白光照明系统(所谓的“白色LED”)。 在双芯片源中,两个LED可以是UV发射和蓝色发射,或发蓝光和绿色发射。 磷光体封装被配置为在从第一和第二辐射源共激发时发射波长为约440nm至约700nm的光致发光。 由荧光体发射的光致发光是白光照射中总功率的至少40%,由第一和第二辐射源(LED)贡献的白光照射中的总功率的部分小于约60% 。 该比例可以在替代实施例中变化,并且分别包括50/50,60 / 40,70 / 30和80/20。 系统发出的白光照明在一个实施例中是显色指数(CRI)大于约90。

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