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    Thermoplastic Vulcanizate Including Rubber Block Interpolymer
    61.
    发明申请
    Thermoplastic Vulcanizate Including Rubber Block Interpolymer 审中-公开
    含橡胶嵌段共聚物的热塑性硫化橡胶

    公开(公告)号：WO2016105973A1

    公开(公告)日：2016-06-30

    申请号：PCT/US2015/065206

    申请日：2015-12-11

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： WU, Xiaosong ,  WALTON, Kim L. ,  LI PI SHAN, Colin

    IPC: C08F297/08 ,  C08L53/00 ,  C08L23/16 ,  C08L23/12

    CPC classification number: C08L53/00 ,  C08F297/08 ,  C08F297/086 ,  C08L23/12 ,  C08L23/16

    Abstract: A thermoplastic vulcanizate composition includes (a) a crystalline thermoplastic polyolefin comprising alpha-olefin monomers having from 2 to 5 carbon atoms, (b) a rubber block interpolymer comprising a first block and a second block having differing chemical or physical properties from the first block, the first block is derived from ethylene, a first alpha-olefin monomer having from 3 to 10 carbon atoms, and a first diene monomer having from 2 to 25 carbon atoms, the second block is derived from ethylene, a second alpha-olefin monomer having from 3 to 10 carbon atoms, and optionally a second diene monomer having from 2 to 25 carbon atoms, and an amount of the block interpolymer in the composition being greater than an amount of the thermoplastic polyolefin in the composition, and (c) a curative system.

    Abstract translation: 热塑性硫化橡胶组合物包括（a）包含具有2至5个碳原子的α-烯烃单体的结晶热塑性聚烯烃，（b）橡胶嵌段互聚物，其包含与第一嵌段不同的化学或物理性质的第一嵌段和第二嵌段 ，第一嵌段衍生自乙烯，具有3至10个碳原子的第一个α-烯烃单体和具有2至25个碳原子的第一个二烯单体，第二个嵌段衍生自乙烯，第二个α-烯烃单体 具有3至10个碳原子，和任选的具有2至25个碳原子的第二二烯单体，组合物中嵌段互聚物的量大于组合物中热塑性聚烯烃的量，和（c） 治疗系统。

    RHEOLOGY MODIFIED OLEFIN-BASED POLYMER COMPOSITION AND METHOD FOR MAKING IT
    62.
    发明申请
    RHEOLOGY MODIFIED OLEFIN-BASED POLYMER COMPOSITION AND METHOD FOR MAKING IT 审中-公开

    公开(公告)号：WO2022240932A1

    公开(公告)日：2022-11-17

    申请号：PCT/US2022/028687

    申请日：2022-05-11

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： MUNRO, Jeffrey C. ,  BAWISKAR, Santosh S. ,  LI PI SHAN, Colin ,  WILLIAMSON, Alexander ,  KARJALA, Teresa P.

    IPC: C08J3/28 ,  C08J3/24 ,  C08J2323/08

    Abstract: A process to form a rheology modified composition, the process comprising applying radiation, and optionally heat, to a composition that comprises at least the following component: a) an olefin-based polymer comprising a total unsaturation ≥ 0.20 /1000C; and wherein the radiation is applied using an electron beam (e-beam) at a dosage selected from 0.1 MRad to 1.5 MRad; and wherein component a is selected from a telechelic polyolefin of the formula A1L1L2A2, an unsaturated polyolefin of the formula A1L1, or an ethylene/alpha-olefin interpolymer. A process to form a rheology modified composition, the process comprising applying heat, and optionally radiation, to a composition that comprises at least the following components: a) an olefin-based polymer, as described above, comprising a total unsaturation ≥ 0.20 /1000C; b) from 1.0 to 100 ppm of a peroxide, based on the weight of the composition.

    COATED OLEFIN-BASED POLYMERS WITH REDUCED BLOCKING
    66.
    发明申请
    COATED OLEFIN-BASED POLYMERS WITH REDUCED BLOCKING 审中-公开

    公开(公告)号：WO2020006396A1

    公开(公告)日：2020-01-02

    申请号：PCT/US2019/039800

    申请日：2019-06-28

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： DHODAPKAR, Shrikant ,  TROTTIER, Remi A. ,  HAUN, JR, George W. ,  BOONE, Harold W. ,  HAMDAN, Intan M. ,  TURNER, Michael D.

    IPC: C08J3/12

    Abstract: A process to form coated polymer particles comprising polymer particles formed from a polymer composition comprising an olefin-based polymer, and a coating formed from a coating composition comprising an aqueous metal acid dispersion and an aqueous polysiloxane emulsion, said process comprising the following: mixing together the aqueous metal acid dispersion and the aqueous polysiloxane emulsion to form a dispersion/emulsion mixture; applying the dispersion/emulsion mixture to a portion of the surfaces of the polymer particles to form wet-coated polymer particles; drying the wet-coated polymer particles to form the coated polymer particles. The aqueous metal acid dispersion and the aqueous polysiloxane emulsion may also be applied, individually, in separate steps.

    DETERMINATION OF THE AMORPHOUS CONTENT OF POLYMERS
    67.
    发明申请
    DETERMINATION OF THE AMORPHOUS CONTENT OF POLYMERS 审中-公开

    公开(公告)号：WO2020005953A1

    公开(公告)日：2020-01-02

    申请号：PCT/US2019/039003

    申请日：2019-06-25

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： CONG, Rongjuan ,  BAILEY, Kimberly, L. ,  RICCA, Vickie

    IPC: G01N25/14 ,  G01N30/46 ,  G01N30/54 ,  G01N33/44 ,  G01N30/00 ,  G01N30/30

    Abstract: A method to determine the weight percent of an "amorphous" fraction in an olefin-based polymer composition, comprising one or more olefin-based polymers; said method comprising the following steps: a) dissolving the olefin-based polymer composition in an organic solvent to form a polymer solution; b) injecting at least a portion of the polymer solution onto a support material, and wherein the support material has a Co-crystallization Index (CI) value from 0.70 to 1.20; c) cooling the support material at a rate greater than, or equal to, 0.2C/min; d) increasing the temperature of the support material to elute the polymers of the olefin-based polymer composition; e) generating a chromatogram; f) determining the peak area of the first elution from its lower integration limit to its upper integration limit; g) calculating the "amorphous" fraction" based on the following Equation A below: wt% "amorphous" fraction = PA amorphous /PA total x100 (Eqn. A); wherein PA amorp = peak area of the first elution, and PAtotal#191 = total peak area of the polymers of the olefin-based polymer composition.

    SILICON-TERMINATED ORGANO-METAL COMPOUNDS AND PROCESSES FOR PREPARING THE SAME
    69.
    发明申请
    SILICON-TERMINATED ORGANO-METAL COMPOUNDS AND PROCESSES FOR PREPARING THE SAME 审中-公开

    公开(公告)号：WO2019182988A1

    公开(公告)日：2019-09-26

    申请号：PCT/US2019/022784

    申请日：2019-03-18

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： SUN, Lixin ,  HUSTAD, Phillip D.

    IPC: C07F7/08

    Abstract: The present disclosure is directed to a silicon-terminated organo-metal composition comprising a compound of formula (I). Embodiments relate to a process for preparing the silicon-terminated organo-metal composition comprising the compound of formula (I), the process comprising combining starting materials comprising (A) a vinyl-terminated silicon-based compound, (B) a chain shuttling agent, (C) a procatalyst, and (D) an activator, thereby obtaining a product comprising the silicon-terminated organo-metal composition. In further embodiments, the starting materials of the process may further comprise (E) a solvent and/or (F) a scavenger.

    PROCESS TO FORM A TILE USING LOW TEMPERATURE HEAT LAMINATION
    70.
    发明申请
    PROCESS TO FORM A TILE USING LOW TEMPERATURE HEAT LAMINATION 审中-公开

    公开(公告)号：WO2019035907A1

    公开(公告)日：2019-02-21

    申请号：PCT/US2018/000175

    申请日：2018-08-16

    Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  DOW SILICONES CORPORATION

    Inventor： HU, Yushan ,  WEEKS, Ronald, J. ,  JABLONKA, Mark, T. ,  LIU, Lizhi

    IPC: B32B37/06 ,  B32B33/00 ,  B32B27/32

    Abstract: A method to produce a tile comprising at least the following layered sections: a wear layered section, a decor layered section and a base layered section; and wherein the wear layered section comprises the following: A) a compositional layer A formed from a composition A comprising at least one olefin-based polymer; wherein the decor layered section comprises the following: B1) a compositional layer B1 formed from a composition B1 comprising a propylene-based polymer; B2) a compositional layer B2 formed from a composition B2 comprising an olefin-based polymer; wherein the base layered section comprises the following: C) a compositional layer C formed from a composition C comprising an olefin- based polymer; wherein the method comprises the following step(s): i) heat laminating compositional layer A to compositional layer B1, at a temperature T1 ≤ 140°C; and wherein, for a continuous production of the tile, T1 is the temperature at the surface of the compositional layer with the highest, or equivalent, surface temperature; and for a batch production of the tile, T1 is the interfacial temperature between the two compositional layers; ii) heat laminating compositional layer B2 to compositional layer C, at a interfacial temperature T2 ≤ 140°C; and wherein, for a continuous production of the tile, T2 is the temperature at the surface of the compositional layer with the highest, or equivalent, surface temperature; and for a batch production of the tile, T2 is the interfacial temperature between the two compositional layers.

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