REDUCTION OF BENZENE IN GASOLINES
    81.
    发明申请
    REDUCTION OF BENZENE IN GASOLINES 审中-公开
    降低汽油中苯的含量

    公开(公告)号:WO1992015655A1

    公开(公告)日:1992-09-17

    申请号:PCT/US1991001462

    申请日:1991-03-04

    CPC classification number: C10G45/64 C10G29/205

    Abstract: The benzene concentration in the gasoline pool of a petroleum refinery is decreased by alkylation of the benzene in a catalytic dewaxing reactor using the olefinic by-products from the dewaxing reaction as alkylating agents. The catalytic dewaxing is preferably carried out in the presence of an intermediate pore size zeolite such as ZSM-5 using a distillate or lube boiling range dewaxing feed. The benzene rich feed preferably contains less than about 2 % C7+ aromatics in order to reduce alkylation of non-objectionable species in the reformate.

    Abstract translation: 使用来自脱蜡反应的烯属副产物作为烷化剂,在催化脱蜡反应器中通过烷基化苯来降低炼油厂汽油池中的苯浓度。 催化脱蜡优选在中等孔径沸石如ZSM-5存在下使用馏出物或润滑沸点脱蜡进料进行。 富含苯的进料优选含有少于约2%的C 7+芳族化合物,以减少重整产物中不吸引物质的烷基化。

    METHOD FOR DETECTING FUEL DILUTION OF MARINE LUBRICATING OILS
    83.
    发明申请
    METHOD FOR DETECTING FUEL DILUTION OF MARINE LUBRICATING OILS 审中-公开
    用于检测海洋润滑油燃料稀释的方法

    公开(公告)号:WO1992008125A1

    公开(公告)日:1992-05-14

    申请号:PCT/US1991007677

    申请日:1991-10-25

    CPC classification number: G01N24/10 F02B3/06 G01R33/60 Y10T436/24

    Abstract: Vanadium in marine diesel lubricating oils resulting from raw fuel dilution is detected and quantified by means of an analytical technique employing electron spin resonance (ESR). Dilution of the lubricating oil with residual fuel oils results in the presence of vanadium in the lubricating oil in a form which is capable of being observed by ESR; by contrast, vanadium resulting from the presence of fuel oil combustion products (pentavalent vanadium) in the lubricating oil is not observed by ESR. The method therefore enables fuel vanadium, typically present as vanadyl porphyrins, to be differentiated from vanadium resulting from blow-by in the engine so that the operating condition of the engine may be monitored.

    METHOD FOR MAEASURING PROPPED FRACTURE HEIGHT USING ACOUSTIC LOGS
    85.
    发明申请
    METHOD FOR MAEASURING PROPPED FRACTURE HEIGHT USING ACOUSTIC LOGS 审中-公开
    使用声学记录进行预测的断裂高度的方法

    公开(公告)号:WO1992006391A1

    公开(公告)日:1992-04-16

    申请号:PCT/US1991006472

    申请日:1991-09-09

    CPC classification number: G01V1/44

    Abstract: A method for determining a propped fracture's (28) height (32) and width (30) wherein acoustic logging devices are used in a borehole. Compressional and shear wave velocities obtained by transmitting acoustic energy through the borehole (12) and into the formation are made at a plurality of locations before and after fracturing the formation. In-situ stresses are determined at the plurality of locations before and after fracturing the formation from velocities of the compressional and shear waves which were detecte before and after fracturing the formation. Differences between in-situ stresses obtained at each of said locations before and after fracturing the formation are used to predict a height and width of a propped fracture.

    Abstract translation: 一种用于确定支撑裂缝(28)高度(32)和宽度(30)的方法,其中在井眼中使用声学测井装置。 通过将声能透射穿过井眼(12)并进入地层而获得的压缩和剪切波速度在压裂地层之前和之后的多个位置处进行。 在压裂地层之前和之后的压缩和剪切波速度压裂地层之前和之后的多个位置确定原位应力。 使用在压裂地层之前和之后的每个所述位置处获得的原位应力之间的差异来预测支撑断裂的高度和宽度。

    SYNTHESIS OF CRYSTALLINE ZEOLITE ZSM-12
    86.
    发明申请
    SYNTHESIS OF CRYSTALLINE ZEOLITE ZSM-12 审中-公开
    晶体沸石ZSM-12的合成

    公开(公告)号:WO1992005232A1

    公开(公告)日:1992-04-02

    申请号:PCT/US1991006674

    申请日:1991-09-13

    CPC classification number: B01J29/7034 C01B37/02 C01B39/42 Y10S423/33

    Abstract: The zeolite ZSM-12 is synthesized by crystallizing a reaction mixture comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), water and hexamethyleneimine directing agent (R), and having a composition, in terms of mole ratios, within the following ranges: YO2/X2O3 60 to >2000; H2O/YO2 5 to 200; OH-/YO2 0.1 to 0.4; M/YO2 0.05 to 1.0; R/YO2 0.1 to 1.0. Crystallization is effected by maintaining the mixture at a temperature of 120 °C to 210 °C for 24 hours to 10 days.

    REACTOR QUENCHING FOR CATALYTIC OLEFIN HYDRATION IN ETHER PRODUCTION
    87.
    发明申请
    REACTOR QUENCHING FOR CATALYTIC OLEFIN HYDRATION IN ETHER PRODUCTION 审中-公开
    用于催化烯烃水合反应生成的反应器

    公开(公告)号:WO1992001661A1

    公开(公告)日:1992-02-06

    申请号:PCT/US1991005193

    申请日:1991-06-23

    CPC classification number: C07C41/05 Y02P20/582 C07C43/04

    Abstract: A process for production of ether by catalytic hydration and etherification of olefinic feedstock containing at least one lower alkene by contacting the olefinic feedstock and water in a plurality of catalytic reaction zones containing porous solid metal oxide acidic olefin hydration and etherification catalyst under hydration and etherification conditions. Improved operation is achieved by recovering a first effluent stream from at least one fixed bed hydration zone; splitting the first effluent stream into a product recovery stream and a plurality of recycle streams; and passing at least a portion of cooled recycle streams comprising olefin, alcohol and ether in effluent stream component proportions for quenching at least one fixed bed reaction zone along with hot effluent from a preceding reaction zone.

    PROCESS AND APPARATUS FOR CONTROL OF MULTISTAGE CATALYST REGENERATION WITH PARTIAL CO COMBUSTION
    88.
    发明申请
    PROCESS AND APPARATUS FOR CONTROL OF MULTISTAGE CATALYST REGENERATION WITH PARTIAL CO COMBUSTION 审中-公开
    多部分催化剂再生控制方法与装置

    公开(公告)号:WO1992001512A1

    公开(公告)日:1992-02-06

    申请号:PCT/US1991004897

    申请日:1991-07-11

    CPC classification number: C10G11/187 C10G11/18 C10G11/182

    Abstract: A process and apparatus (Figs. 1, 2, 3 and 4) for controlled, multi-stage regeneration of FCC catalyst is disclosed. A modified high-efficiency catalyst regenerator (80), with a fast fluidized bed coke combustor (62), dilute phase transport riser (83), and second fluidized bed (82) regenerates the catalyst in at least two stages. The primary stage of regeneration is in the coke combustor (62). Second stage catalyst regeneration occurs in the second fluidized bed (82). The amount of combustion air added to both regeneration stages is set to maintain partial CO combustion in both stages. Controlled multi-stage regeneration reduces the steaming or deactivation of catalyst during regeneration, maximizes coke burning capacity of the regenerator (80), and minimizes or eliminates NOx emissions.

    PROCESS AND APPARATUS FOR CONTROL OF MULTISTAGE CATALYST REGENERATION WITH FULL CO COMBUSTION
    89.
    发明申请
    PROCESS AND APPARATUS FOR CONTROL OF MULTISTAGE CATALYST REGENERATION WITH FULL CO COMBUSTION 审中-公开
    用于全面燃烧的多级催化剂再生控制方法及装置

    公开(公告)号:WO1992001511A1

    公开(公告)日:1992-02-06

    申请号:PCT/US1991005019

    申请日:1991-07-16

    CPC classification number: B01J38/34 B01J29/90 B01J38/36 C10G11/182 C10G11/187

    Abstract: A process and apparatus for controlled, multi-stage, regeneration of FCC catalyst is disclosed. A modified high efficiency catalyst regenerator, with a fast fluidized bed coke combustor, dilute phase transport riser, and second fluidized bed regenerates the catalyst in at least two zones, both operating with complete CO combustion. The primary stage of regeneration is in the coke combustor. Second stage catalyst regeneration occurs in the second fluidized bed. The amount of combustion gas, and/or the feed rate, feed preheat, catalyst recirculation to the coke combustor and rate of CO oxidation promoter addition are controlled to maintain complete CO combustion in both zones. Controlled multi-stage regeneration reduces the steaming or deactivation of catalyst during regeneration, increases coke burning capacity of the regenerator, and maximizes efficiency of SOx getters.

    Abstract translation: 公开了用于FCC催化剂的受控,多级再生的方法和装置。 改进的高效催化剂再生器,具有快速流化床焦炭燃烧器,稀相运输提升管和第二流化床,在至少两个区域中再生催化剂,两个区域都用完全CO燃烧运行。 再生的主要阶段是焦炭燃烧器。 第二阶段催化剂再生发生在第二流化床中。 控制燃烧气体量和/或进料速率,进料预热,对焦炭燃烧器的催化剂再循环和CO氧化促进剂添加速率,以在两个区域中保持完全的CO燃烧。 控制的多级再生减少了再生过程中催化剂的蒸发或失活,提高了再生器的焦炭燃烧能力,并使SOx吸气剂的效率最大化。

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