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1.发明申请PROPYLENE OXIDE PROCESS USING MIXED PRECIOUS METAL CATALYST SUPPORTED ON ALKALINE EARTH METAL CARBONATE 审中-公开丙烯氧化物工艺使用混合的极性金属催化剂支持碱性金属碳酸盐
公开(公告)号：WO1998030552A1
公开(公告)日：1998-07-16
申请号：PCT/EP1997005449
申请日：1997-10-03
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , GAFFNEY, Anne , KAHN, Andrew , PITCHAI, Rangasamy
IPC: C07D301/10
CPC classification number: C07D301/10 , Y02P20/52
Abstract: Propylene is oxidized to propylene oxide in the vapor phase using oxygen and a supported catalyst comprising silver, gold, a potassium promoter such as potassium nitrate or potassium carbonate and a support comprised in whole or in substantial part of an alkaline earth metal carbonate.
Abstract translation: 使用氧气和含有银，金，钾促进剂如硝酸钾或碳酸钾的载体催化剂，以及包含在碱土金属碳酸盐的全部或大部分中的载体，丙烯在气相中被氧化成环氧丙烷。
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公开(公告)号：WO1998028072A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997006625
申请日：1997-11-27
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , CARROLL, Kevin, M. , MORALES, Edrick , HAN, Yuan-Zhang
IPC: B01J21/20
CPC classification number: B01J38/48 , B01J21/20 , C07D301/12 , Y02P20/584
Abstract: The catalytic activity of a titanium-containing heterogeneous catalyst such as titania-on-silica which has been used to catalyze olefin epoxidation is effectively restored by washing the catalyst with water, alcohol, ether, nitrile, ester, aromatic hydrocarbon, or ketone.
Abstract translation: 通过用水，醇，醚，腈，酯，芳烃或酮清洗催化剂，有效地恢复了用于催化烯烃环氧化的含钛非均相催化剂如二氧化钛 - 二氧化硅的催化活性。
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公开(公告)号：WO1998027044A1
公开(公告)日：1998-06-25
申请号：PCT/EP1997006626
申请日：1997-11-27
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , SHEN, Jianzhong , BA, Sujuan , BRAUNSTEIN, David, M. , KESLING, Haven, S., Jr.
IPC: C07C45/71
CPC classification number: C08G65/2663 , B01J27/26 , C07C45/71 , C08G65/2603 , C08G65/2612 , C07C49/84
Abstract: A process for alkoxylating phenols is disclosed. The process comprises reacting a carbonyl-functionalized phenol with an alkylene oxide in the presence of a substantially non-crystalline double metal cyanide (DMC) catalyst. The process offers fast reaction times at low catalyst levels, reduced problems with condensation side reactions, and low-color, low-viscosity, low-polydispersity alkoxylated phenols. The process enables efficient preparation of alkoxylated carbonyl-functonalized phenols that are especially valuable in the surfactant industry.
Abstract translation: 公开了一种烷氧基化酚的方法。 该方法包括在基本上非结晶的双金属氰化物（DMC）催化剂的存在下使羰基官能化的酚与烯化氧反应。 该方法在低催化剂水平下提供快速反应时间，减少冷凝副反应的问题，以及低色，低粘度，低多分散性烷氧基化酚。 该方法能够有效地制备在表面活性剂工业中特别有价值的烷氧基化羰基 - 官能化酚。
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公开(公告)号：WO1998003461A1
公开(公告)日：1998-01-29
申请号：PCT/EP1997003726
申请日：1997-07-12
IPC: C07C67/48
Abstract: The free fatty acid remaining in a reaction product obtained by esterification of a propoxylated glycerin with excess fatty acid may be reduced to low levels by treating the reaction product with a solid basic compound, preferably one having a small particle size and high surface area, and then filtering. The purified composition thus obtained contains little or no residual basic compound and is suitable for use as a reduced calorie fat substitute in the preparation of food products.
Abstract translation: 通过用过量脂肪酸酯化丙氧基化甘油而获得的反应产物中残留的游离脂肪酸可以通过用固体碱性化合物，优选具有小粒径和高表面积的固体碱性化合物处理反应产物而降低至低水平，以及 然后过滤。 由此获得的纯化组合物含有很少或没有残留的碱性化合物，并且适合用作制备食品中的低热量脂肪替代物。
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5.发明申请POLYURETHANE/UREA HEAT-CURED AND MOISTURE-CURED ELASTOMERS WITH IMPROVED PHYSICAL PROPERTIES 审中-公开具有改善物理性能的聚氨酯/尿素热固化和湿固化弹性体
公开(公告)号：WO1998002475A1
公开(公告)日：1998-01-22
申请号：PCT/EP1997003736
申请日：1997-07-12
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , BARKSBY, Nigel , LAWREY, Bruce , CLIFT, Susan
IPC: C08G18/66
CPC classification number: C08G18/6674 , C08G18/10 , C08G18/4866 , C08G18/307 , C08G18/3808
Abstract: Elastomers with improved physical properties, particularly hardness and rebound, may be prepared by the diamine chain extension or moisture cure of low isocynate group content, toluene diisocyanate-based prepolymers prepared from a polyol component comprising a high molecular weight, low unsaturation polyoxypropylene diol and a low molecular weight diol. The elastomers are useful for applications such as rollers and other applications where hardness and rebound are important.
Abstract translation: 具有改善的物理性质，特别是硬度和回弹性的弹性体可以通过二异氰酸酯链延伸或低异氰酸酯基含量的水分固化，由包含高分子量，低不饱和聚氧丙烯二醇的多元醇组分制备的甲苯二异氰酸酯基预聚物和 低分子量二醇。 弹性体可用于诸如辊和其它应用的应用，其中硬度和回弹是重要的。
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Patent Agency Ranking
公开(公告)号：WO1997035814A1
公开(公告)日：1997-10-02
申请号：PCT/EP1997001445
申请日：1997-03-21
IPC: C04B24/32
CPC classification number: C04B24/2647 , C04B24/267 , C08F8/14 , C08L71/02 , C08L2666/04
Abstract: Substances useful as water reducing and superplasticizer additives for cement compositions are formed by reaction of carboxylic acid polymers with a polyether, preferably a mixture of monofunctional and difunctional polyethers, derived from C2-C4 epoxides wherein partial cleavage of the polyethers and esterification of the polyethers and the cleavage products thereof by the other reactant are achieved. In one embodiment, a sulfonic acid is used to catalyze the reaction of poly(acrylic acid), a monofunctional ethylene oxide-propylene oxide copolymer, and a difunctional poly(propylene glycol), at a temperature in excess of 140 DEG C.
Abstract translation: 可用作水泥组合物的减水剂和超增塑剂添加剂的物质是通过羧酸聚合物与衍生自C 2 -C 4环氧化物的聚醚，优选单官能和双官能聚醚的混合物的反应形成的，其中聚醚的部分裂解和聚醚的酯化和 实现了其它反应物的裂解产物。 在一个实施方案中，磺酸用于在超过140℃的温度下催化聚（丙烯酸），单官能环氧乙烷 - 环氧丙烷共聚物和双官能聚（丙二醇）的反应。
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7.发明申请PROCESS FOR THE PREPARATION OF POLYOXYALKYLENE POLYETHER POLYOLS HAVING LOW LEVELS OF TRANSITION METALS, PREPARED USING DOUBLE METAL CYANIDE COMPLEX CATALYST 审中-公开使用双金属氰化物复合催化剂制备具有低水平金属过渡金属的聚羟基聚乙烯多元醇的方法
公开(公告)号：WO1997023544A1
公开(公告)日：1997-07-03
申请号：PCT/EP1996005708
申请日：1996-12-19
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , TELEVANTOS, Yiannakis , LE-KHAC, Bi
IPC: C08G65/10
CPC classification number: C08G65/2663 , Y02P20/584
Abstract: Substantially transition metal-free polyoxyalkylene polyethers may be prepared by double metal cyanide complex-catalyzed oxyalkylation of a suitable hydric oxyalkylation initiator molecule by employing 15 ppm or less of a double metal cyanide complex oxyalkylation catalyst having a propylene oxide polymerization rate greater than 5g propylene oxide/minute. The induction periods associated with oxyalkylation employing double metal cyanide complex catalysts may be reduced by preparing preactivated master batches and by increasing the oxyalkylation reactor temperature during at least the induction period.
Abstract translation: 通过使用15ppm或更少的具有大于5g环氧丙烷的环氧丙烷聚合速率的双金属氰化物络合物烷氧基化催化剂，可以通过合适的羟基烷氧基化引发剂分子的双金属氰化物络合物催化的烷氧基化制备基本上无过渡金属的聚氧化烯聚醚 /分钟。 与使用双金属氰化物配合物催化剂的烷氧基化相关的诱导期可以通过制备预活化的母料和在至少诱导期间增加烷氧基化反应器温度来降低。
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公开(公告)号：WO1998016310A1
公开(公告)日：1998-04-23
申请号：PCT/EP1997005638
申请日：1997-10-14
IPC: B01J27/06
CPC classification number: C08G65/2663 , B01J27/26 , B01J31/06 , B01J31/22 , B01J31/2208 , B01J2531/26 , C08G18/4866
Abstract: Double metal cyanide (DMC) catalysts useful for epoxide polymerizations are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, and from about 2 to about 80 wt.% of a functionalized polymer or a water-soluble salt derived from the polymer. The catalysts are easy to prepare and isolate, are substantially non-crystalline, and have high activity for polymerizing epoxides. Polyols made from the catalysts have exceptionally low unsaturations, low viscosities, and reduced levels of high molecular weight polyol tail.
Abstract translation: 公开了可用于环氧化物聚合的双金属氰化物（DMC）催化剂。 催化剂包括DMC化合物，有机络合剂和约2-约80重量％的官能化聚合物或衍生自聚合物的水溶性盐。 催化剂易于制备和分离，基本上是非结晶的，并且具有高的聚合环氧化物的活性。 由催化剂制成的多元醇具有非常低的不饱和度，低粘度和降低的高分子量多元醇尾巴的水平。
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公开(公告)号：WO1997046545A1
公开(公告)日：1997-12-11
申请号：PCT/EP1997002844
申请日：1997-06-01
Inventor： ARCO CHEMICAL TECHNOLOGY, L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , ALBAL, Rajendra , EVANS, Thomas , WENTZHEIMER, Wayne , DONN, Allen , GELB, Morris
IPC: C07D301/32
CPC classification number: C07D301/19 , B01J27/232 , B01J31/08 , B01J31/26 , B01J31/34 , B01J31/4015 , B01J31/4092 , B01J2231/72 , B01J2531/96 , Y02P20/584
Abstract: An aqueous epoxidation process stream containing molybdenum and sodium values and organics is treated for organics removal as by incineration and an aqueous solution containing molybdenum and sodium is recovered, cooled, acidified and contacted with activated carbon and an aqueous stream reduced in molybdenum is recovered, further molybdenum reduction can be achieved by treatment with basic ion exchange resin.
Abstract translation: 处理包含钼和钠值的有机物的水性环氧化工艺流，通过焚化处理去除有机物，回收含有钼和钠的水溶液，冷却，酸化并与活性炭接触，并回收钼中还原的水流。 通过用碱性离子交换树脂处理可以实现钼还原。
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公开(公告)号：WO1997033852A1
公开(公告)日：1997-09-18
申请号：PCT/EP1997001182
申请日：1997-03-08
Inventor： ARCO CHEMICAL TECHNOLOGY L.P. , ARCO CHEMIE TECHNOLOGIE NEDERLAND B.V. , TRAUTH, Daniel , SHAWL, Edward
IPC: C07C41/38
Abstract: Monoalkyl glycol ether is separated from dialkyl glycol ether by phase separation using a hydrocarbon solvent, preferably with the addition also of water.
Abstract translation: 单烷基乙二醇醚通过使用烃溶剂的相分离与二烷基二醇醚分离，优选还加入水。
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