公开(公告)号：WO2006010555A1

公开(公告)日：2006-02-02

申请号：PCT/EP2005/007943

申请日：2005-07-21

Applicant: MERCK PATENT GMBH ,  AVECIA LIMITED ,  BROWN, Beverley, Anne ,  LEEMING, Stephan, William ,  WILLIAMS, Richard

Inventor： BROWN, Beverley, Anne ,  LEEMING, Stephan, William ,  WILLIAMS, Richard

IPC: C07C211/54

CPC classification number: C07C211/54

Abstract: The invention relates to a compound of Formula (I): wherein: each of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 which may be the same or different on each triarylamine unit of Formula (1) and the same or different from one triarylamine unit of Formula (1) to another is independently hydrogen or an optionally substituted substituent; n is from 5 to 20; and a and b are each independently 0, 1, 2, 3 or 4. Also claimed are compositions comprising a compound of Formula (1) and a synthetic organic polymer resin, a process for preparing a compound of Formula (1), an organic semiconducting layer prepared from the composition, and electronic devices comprising the organic semiconducting layer.

Abstract translation: 本发明涉及式（I）的化合物：其中：R 1，

公开(公告)号：WO2005023737A1

公开(公告)日：2005-03-17

申请号：PCT/GB2004/003884

申请日：2004-09-10

Applicant: AVECIA LIMITED ,  MOODY, David, John ,  HÄRRÖD, Magnus ,  FIELDHOUSE, Robin

Inventor： MOODY, David, John ,  HÄRRÖD, Magnus ,  FIELDHOUSE, Robin

IPC: C07C29/149

CPC classification number: C07C29/149 ,  C07C67/31 ,  Y02P20/544 ,  C07C69/675 ,  C07C31/22 ,  C07C31/205

Abstract: There is provided a process for the hydrogenation of esters of alpha-substituted carboxylic acids which comprises reacting an ester of an alpha-substituted carboxylic acid with hydrogen in the presence of a catalyst under substantially homogeneous supercritical conditions. Preferably, the ester of an alpha-substituted carboxylic acids is an ester of formula (1): wherein: R 1 and R 2 are each independently an optionally substituted hydrocarbyl group or an optionally substituted heterocyclic group; and Y is a heteroatom or an optionally substituted heteroatom group. More preferably, the ester of an alpha-substituted is carboxylic acids is an ester of formula (2): wherein: R 3 is an optionally substituted hydrocarbyl group or an optionally substituted heterocyclic group; R 4 and R 5 are each independently hydrogen, an optionally substituted hydrocarbyl group or an optionally substituted heterocyclic group; Y is a heteroatom or an optionally substituted heteroatom group; Q is a functional group; and n 1. Most preferably, the ester of an alpha-substituted carboxylic acids is an ester of formula (3): wherein: R 3 and R 6 are each independently an optionally substituted hydrocarbyl group or an optionally substituted heterocyclic group; R 4 and R 5 are each independently hydrogen, an optionally substituted hydrocarbyl group or an optionally substituted heterocyclic group; Y is a heteroatom or an optionally substituted heteroatom group; and n 1.

Abstract translation: 提供了α-取代羧酸酯的氢化方法，其包括在催化剂存在下，在基本上均匀的超临界条件下使α-取代的羧酸的酯与氢反应。 优选地，α-取代的羧酸的酯是式（1）的酯：其中：R 1和R 2各自独立地为任选取代的烃基或任选取代的杂环基; 并且Y是杂原子或任选取代的杂原子基团。 更优选地，α-取代的酯是羧酸是式（2）的酯：其中：R 3是任选取代的烃基或任选取代的杂环基; R 4和R 5各自独立地为氢，任选取代的烃基或任选取代的杂环基; Y是杂原子或任选取代的杂原子基团; Q是功能组; 最优选地，α-取代的羧酸的酯是式（3）的酯：其中：R 3和R 6各自独立地是任选取代的烃基或任选取代的杂环基 ; R 4和R 5各自独立地为氢，任选取代的烃基或任选取代的杂环基; Y是杂原子或任选取代的杂原子基团; 和n 1。

公开(公告)号：WO2004113462A1

公开(公告)日：2004-12-29

申请号：PCT/GB2004/000899

申请日：2004-03-03

Applicant: AVECIA LIMITED ,  FOSTER, Clive, Edwin ,  MOSCROP, Clive ,  WRIGHT, Gavin ,  JAMES, Rachel, Anne

Inventor： FOSTER, Clive, Edwin ,  MOSCROP, Clive ,  WRIGHT, Gavin ,  JAMES, Rachel, Anne

IPC: C09D11/00

CPC classification number: C09D11/328 ,  C09B45/34

Abstract: A metal chelate compound of Formula: (1) or a salt thereof: [A-N=N-B] M (Formula (1)) wherein: A is an optionally substituted pyridyl ring; and B is of the Formula: (2): wherein: X and W are substituents other than H; M is a metal chelated to A-N=N-B; and n is 0 to 4, also claimed are compositions and inks containing a compound of Formula: (1), a process for ink jet printing using the inks and an ink jet pIinter cartridge containing the ink.

Abstract translation: 式（1）的金属螯合物或其盐：[A-N = N-B] M（式（1））其中：A为任选取代的吡啶环; 和B为式（2）：其中：X和W是H以外的取代基; M是螯合到A-N = N-B的金属; 和n为0至4，还要求的是含有式（1）化合物的组合物和油墨，使用该油墨的喷墨印刷方法和含有该油墨的喷墨印刷机墨盒。

公开(公告)号：WO2004033559A1

公开(公告)日：2004-04-22

申请号：PCT/GB2003/004024

申请日：2003-09-19

Applicant: AVECIA LIMITED ,  SHAWCROSS, Andrew, Paul ,  WIGHT, Paul

Inventor： SHAWCROSS, Andrew, Paul ,  WIGHT, Paul

IPC: C09B43/16

CPC classification number: C09D11/328 ,  C09B43/16

Abstract: A compound of Formula (1) and salts thereof; wherein: R 1 and R 3 are each independently H or optionally substituted alkyl; R 2 is optionally substituted alkyl; Y is OH, C0 2 H, S0 3 H or P0 3 H 2 ; and n and m each independently have a value of 0 or 1; provided that the compound of Formula (1) is free from fibre reactive groups. Also an ink-jet printing ink, an ink jet printing process, a printed material and an ink jet printer cartridge.

Abstract translation: 式（1）的化合物及其盐; 其中：R 1和R 3各自独立地为H或任选取代的烷基; R 2是任选取代的烷基; Y是OH，CO 2 H，SO 3 H或PO 3 H 2; 并且n和m各自独立地具有0或1的值; 条件是式（1）的化合物不含纤维反应性基团。 还有喷墨印刷油墨，喷墨印刷工艺，印刷材料和喷墨打印机墨盒。

公开(公告)号：WO2004026977A1

公开(公告)日：2004-04-01

申请号：PCT/GB2003/003697

申请日：2003-08-22

Applicant: AVECIA LIMITED ,  HOPPER, Alan, John ,  JAMES, Mark, Robert

Inventor： HOPPER, Alan, John ,  JAMES, Mark, Robert

IPC: C09D11/10

CPC classification number: C09D11/36 ,  C09D11/101 ,  H05K3/0076 ,  H05K3/061 ,  H05K2203/013 ,  Y10T428/24917

Abstract: A process for making an electronic device comprising a dielectric substrate laminated with an electrically conductive metal or alloy which comprises applying a non­-aqueous etch-resistant ink by ink jet printing to selected areas of the metal or alloy, exposing the etch-resistant ink to actinic radiation and/or particle beam radiation to effect polymerisation, removing exposed metal or alloy by a chemical etching process and then removing the polymerised etch-resistant ink by alkali wherein the etch-resistant ink is substantially solvent free and comprises the components: A) 30 to 90 parts acrylate functional monomers free from acid groups comprising mono or higher functionality wherein 5 - 95% by weight is one or more mono­functional monomers; B) 1 to 30 parts acrylate functional monomer containing one or more acid groups; C) 0 to 20 parts polymer or prepolymer; D) 0 to 20 parts radical initiator; E) 0 to 5 parts colorant; F) 0 to 5 parts surfactant; and wherein the ink has a viscosity of not greater than 30 cPs (mPa.s) at 40°C and all parts are by weight.

Abstract translation: 一种用于制造电子器件的方法，该电子器件包括层叠有导电金属或合金的电介质基底，其包括通过喷墨印刷将非水性耐蚀刻油墨施加到金属或合金的选定区域，将耐蚀刻油墨暴露于 光化辐射和/或粒子束辐射以进行聚合，通过化学蚀刻方法去除暴露的金属或合金，然后通过碱除去聚合的耐蚀刻油墨，其中耐蚀刻油墨基本上无溶剂并且包含组分：A） 30至90份不含包含单官能或更高官能度的酸基的丙烯酸酯官能单体，其中5-95重量％是一种或多种单官能单体; B）1至30份含有一个或多个酸基的丙烯酸酯官能单体; C）0至20份聚合物或预聚物; D）0〜20份自由基引发剂; E）0-5份着色剂; F）0-5份表面活性剂; 并且其中所述油墨在40℃下的粘度不大于30cPs（mPa.s），并且所有份数均为重量份。

公开(公告)号：WO2003106572A1

公开(公告)日：2003-12-24

申请号：PCT/GB2003/001575

申请日：2003-04-11

Applicant: AVECIA LIMITED ,  BRADBURY, Roy ,  DICKINSON, Alan ,  DOUBLE, Philip, John ,  GREGORY, Peter ,  HADJISOTERIOU, Maria, Soteri ,  PAUL, Thomas ,  POPAT, Ajay, Haridas ,  THOMPSON, Neil, James ,  WIGHT, Paul

Inventor： BRADBURY, Roy ,  DICKINSON, Alan ,  DOUBLE, Philip, John ,  GREGORY, Peter ,  HADJISOTERIOU, Maria, Soteri ,  PAUL, Thomas ,  POPAT, Ajay, Haridas ,  THOMPSON, Neil, James ,  WIGHT, Paul

IPC: C09D11/00

CPC classification number: D06P5/30 ,  C09B33/22 ,  C09B35/40 ,  C09B35/52 ,  C09B35/58 ,  C09B35/60 ,  C09B35/64 ,  C09B45/24 ,  C09D11/328 ,  C09D11/40 ,  D06P1/18

Abstract: A process for printing an image on a substrate comprising applying thereto a composition comprising a liquid medium and a compound of Formula (1): T-Q-N=N-L-T wherein each T independently is an azo group; Q is an optionally substituted, optionally metallised 1,8-dihydroxy-naphthyl group; and L is a divalent organic linker group. Also claimed are compositions and dyes.

Abstract translation: 一种用于在基材上印刷图像的方法，包括向其施加包含液体介质和式（1）的化合物的组合物：T-Q-N = N-L-T，其中每个T独立地为偶氮基; Q是任选取代的，任选金属化的1,8-二羟基 - 萘基; L是二价有机连接基团。 还要求的是组合物和染料。

公开(公告)号：WO2003095562A1

公开(公告)日：2003-11-20

申请号：PCT/GB2003/001981

申请日：2003-05-08

Applicant: AVECIA LIMITED ,  MISTRY, Prahalad, Manibhai ,  BRADBURY, Roy

Inventor： MISTRY, Prahalad, Manibhai ,  BRADBURY, Roy

IPC: C09B31/28

CPC classification number: C09D11/328 ,  C09B31/28 ,  Y10T428/24802

Abstract: A composition comprising a liquid medium and a compound of Formula (1) or salt thereof: Formula (1) wherein: A is optionally substituted phenyl or naphthyl provided A is not 2-sulpho-4-methoxyphenyl; B is optionally substituted phenylene or naphthylene; n is 0 or 1; D is a pyrazolonyl group; and wherein the liquid medium comprises an organic solvent. Also claimed are inks comprising said compositions and processes for printing.

Abstract translation: 包含液体介质和式（1）化合物或其盐的组合物：式（1）其中：A是任选取代的苯基或萘基，提供A不是2-磺基-4-甲氧基苯基; B是任选取代的亚苯基或亚萘基; n为0或1; D是吡唑啉酮基; 并且其中所述液体介质包含有机溶剂。 还要求保护的是包含所述组合物和印刷方法的油墨。

公开(公告)号：WO2003093302A3

公开(公告)日：2003-11-13

申请号：PCT/GB2003/001949

申请日：2003-05-02

Applicant: AVECIA LIMITED ,  EVANS, David, John ,  SIMPKIN, Dean, Steven, Anthony ,  WELLINGS, Donald, Alfred ,  ATHERTON, Eric

Inventor： EVANS, David, John ,  SIMPKIN, Dean, Steven, Anthony ,  WELLINGS, Donald, Alfred ,  ATHERTON, Eric

IPC: C07K1/00

Abstract: A process is provided for the solid-phase synthesis of a peptide amide which comprises attaching a α-nitrogen protected Cα-carboxamide amino acid to a solid support by its side chain, removing the α-nitrogen protecting group, assembling a peptide chain on said α-nitrogen and then cleaving the assembled peptide amide from the solid support. Novel amino acid analogues, peptide amides and solid-phase supports are also provided.

公开(公告)号：WO2003066709A1

公开(公告)日：2003-08-14

申请号：PCT/GB2003/000011

申请日：2003-01-06

Applicant: AVECIA LIMITED ,  ANNABLE, Tom ,  HALL, Denise ,  YEATES, Stephen, George

Inventor： ANNABLE, Tom ,  HALL, Denise ,  YEATES, Stephen, George

IPC: C08G85/00

CPC classification number: B41M5/0017 ,  B41J11/0015 ,  B41M5/5245 ,  B41M7/0027 ,  C08F8/30 ,  C09D11/30

Abstract: A process for forming a chain extended thermoplastic polymer which comprises reacting: (i) a prepolymer comprising one or more guanidinium or biguanidinium units and having at least one reactive end group; and (ii) a chain extender having at least two groups able to react with reactive end group(s) in (i). The polymers may be used as fixing agents to reduce highlighter smear of prints prepared by ink jet printing.

Abstract translation: 一种形成链延长热塑性聚合物的方法，其包括使（i）包含一种或多种胍或双胍单元并具有至少一个反应性端基的预聚物; 和（ii）具有至少两个能够与（i）中的反应性末端基反应的扩链剂。 聚合物可以用作固定剂，以减少通过喷墨印刷制备的印刷品的荧光笔涂片。

公开(公告)号：WO2003033606A1

公开(公告)日：2003-04-24

申请号：PCT/GB2002/004467

申请日：2002-10-02

Applicant: AVECIA LIMITED ,  ANNABLE, Tom ,  KENWORTHY, Mark ,  YEATES, Stephen, George

Inventor： ANNABLE, Tom ,  KENWORTHY, Mark ,  YEATES, Stephen, George

IPC: C09D179/00

CPC classification number: C09D179/00 ,  B41M5/52 ,  B41M5/5245

Abstract: A coating composition comprising pigment, medium and a binder characterised in that (i) the binder comprises a cationic polymer comprising a repeat unit of formula (I): wherein: X and Y are the same or different and represent divalent organic linking groups; and (ii) the weight ratio of pigment to binder in the composition is at least 2:1. The compositions are useful for preparing ink jet recording materials with good water resistance, print quality and dry time.

Abstract translation: 一种包含颜料，介质和粘合剂的涂料组合物，其特征在于（i）所述粘合剂包含包含式（I）的重复单元的阳离子聚合物：其中：X和Y相同或不同，表示二价有机连接基团; 和（ii）组合物中颜料与粘合剂的重量比为至少2:1。 该组合物可用于制备具有良好耐水性，印刷质量和干燥时间的喷墨记录材料。