公开(公告)号：WO2016044857A8

公开(公告)日：2016-03-24

申请号：PCT/US2015/058738

申请日：2015-11-03

Applicant: POWERMERS INC. ,  KARUSHEV, Mikhail P. ,  BELOUS, Svetlana A. ,  LAVROVA, Tatyana S. ,  CHEPURNAYA, Irina A. ,  TIMONOV, Alexander M. ,  KOGAN, Seymon

Inventor： KARUSHEV, Mikhail P. ,  BELOUS, Svetlana A. ,  LAVROVA, Tatyana S. ,  CHEPURNAYA, Irina A. ,  TIMONOV, Alexander M. ,  KOGAN, Seymon

IPC: H01M4/36

Abstract: A metal air battery. In one embodiment, the metal air battery includes a metal anode; a metal ion solid electrolyte; and a cathode including a porous carbon structure coated with a transition metal polymer complex, wherein the metal polymer complex comprises a substituted tetradentate Schiff base ligand. In one embodiment, the cathode is constructed as a highly porous carbon structure coated with a nanolayer of a polymer transition metal complex.

公开(公告)号：WO2016028589A1

公开(公告)日：2016-02-25

申请号：PCT/US2015/044997

申请日：2015-08-13

Applicant: POWERMERS INC. ,  KARUSHEV, Mikhail P. ,  BELOUS, Svetlana A. ,  LAVROVA, Tatyana S. ,  CHEPURNAYA, Irina A. ,  TIMONOV, Alexander M. ,  KOGAN, Seymon

Inventor： KARUSHEV, Mikhail P. ,  BELOUS, Svetlana A. ,  LAVROVA, Tatyana S. ,  CHEPURNAYA, Irina A. ,  TIMONOV, Alexander M. ,  KOGAN, Seymon

IPC: C07F15/04 ,  C01B31/02 ,  C07F1/08 ,  C08G83/00 ,  C08J9/36 ,  C09D201/00 ,  C25B11/14 ,  C08L101/00 ,  C25B3/02 ,  H01M4/00

CPC classification number: H01M4/8652 ,  B01J20/20 ,  B01J20/226 ,  B01J20/3204 ,  C01B32/05 ,  C07F1/005 ,  C07F15/045 ,  C25B3/12 ,  H01M4/364 ,  H01M4/366 ,  H01M4/625 ,  H01M4/8673 ,  H01M4/9075

Abstract: Claimed is a method for creating a metal-carbon composite. The method includes the steps of providing a polymer Schiff base transition metal film precursor having a chemical structure of the formula [M(Schiff)], where M is selected from the group consisting of nickel, palladium, platinum, cobalt, copper, iron; In the above Markush formula, the bridge Y has the following structure: in Salen in Saltmen in Salphen R is selected from the group consisting of H-, and carbon-containing substituents, preferably CH3-, C 2 H 5 -, CH 3 O-, C 2 H 5 O-. Disclosed is a method of depositing the Schiff base transition metal onto a support substrate, and electropolymerizing the material to a film, followed by heating the polymeric Schiff base transition metal film on the support substrate in a furnace under an inert atmospher to obtain a porous metal-carbon material with favorable properties for use as electrode material in devices such as fuel cells, double layer capacitors, lithium-ion and lithium polymer batteries.

Abstract translation: 所要求的是用于制造金属 - 碳复合材料的方法。 该方法包括提供具有式[M（Schiff）]化学结构的聚合物希夫碱过渡金属膜前体的步骤，其中M选自镍，钯，铂，钴，铜，铁; 在上述马库什公式中，桥Y具有以下结构：在Salphen R的Salmen的Salen选自H和含碳取代基，优选CH 3 - ，C 2 H 5 - ，CH 3 O - ，C 2 H 5 O-。 公开了一种将席夫碱过渡金属沉积到支撑基底上并将该材料电聚合成膜，然后在惰性气氛下在炉中将支撑基底上的聚合物席夫碱过渡金属膜加热以获得多孔金属 碳材料，具有良好的性能，用作诸如燃料电池，双层电容器，锂离子和锂聚合物电池的器件中的电极材料。

公开(公告)号：WO2016044857A1

公开(公告)日：2016-03-24

申请号：PCT/US2015058738

申请日：2015-11-03

Applicant: POWERMERS INC ,  KARUSHEV MIKHAIL P ,  BELOUS SVETLANA A ,  LAVROVA TATYANA S ,  CHEPURNAYA IRINA A ,  TIMONOV ALEXANDER M ,  KOGAN SEYMON

Inventor： KARUSHEV MIKHAIL P ,  BELOUS SVETLANA A ,  LAVROVA TATYANA S ,  CHEPURNAYA IRINA A ,  TIMONOV ALEXANDER M ,  KOGAN SEYMON

IPC: H01M4/36

CPC classification number: H01M4/9008 ,  H01M4/9083 ,  H01M12/08 ,  Y02E60/128

Abstract: A metal air battery. In one embodiment, the metal air battery includes a metal anode; a metal ion solid electrolyte; and a cathode including a porous carbon structure coated with a transition metal polymer complex, wherein the metal polymer complex comprises a substituted tetradentate Schiff base ligand. In one embodiment, the cathode is constructed as a highly porous carbon structure coated with a nanolayer of a polymer transition metal complex.

Abstract translation: 金属空气电池。 在一个实施例中，金属空气电池包括金属阳极; 金属离子固体电解质; 以及包含涂覆有过渡金属聚合物复合物的多孔碳结构的阴极，其中所述金属聚合物复合物包含取代的四齿希夫碱配体。 在一个实施方案中，阴极构造为涂覆有聚合物过渡金属络合物的纳米层的高度多孔碳结构。