摘要:
A composition and method for producing a tertiary amine is disclosed. The tertiary amine is contacted with an inert gas. The inert gas is nitrogen or more preferably argon. The amine composition is useful in producing polyurethane foam with lower levels of chemical emissions particularly lower emissions of toxic chemicals.
摘要:
A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH# 1100 as cell opening aides for 2-cyanoacetamide or other similar molecules containing active methylene or methine groups to make a polyurethane foam is also disclosed. The advantage of using cell opener aids results in a) no foam shrinkage; b) lower use levels of cell opener; c) foam performance reproducibility d) optimum physical properties. In addition, combining the acid blocked amine catalyst together with the cell opener and the cell opener aid results in a less corrosive mixture as well as provides a method that does not require mechanical crushing for cell opening.
摘要:
A catalyst composition for making polyurethane foam, the catalyst composition including a compound having a general formula R 1 R 2 R 3 N, wherein each of R 1 , R 2 and R 3 are independently selected from the group consisting of: a compound according to formula (I): wherein n = 1 to 5; and R4, R5 and R6 are each independently hydrogen, methyl, ethyl and propyl groups; hydrogen, a C1 -C6 alkyl group compound, a C1 -C6 cycloalkyl group compound, a C1 -C6 alkenyl group compound, a C1 -C6 alkynyl group compound, a C1 -C6 aryl group compound, and a C1 -C6 aralkyl group compound, each group being substituted or unsubstituted; wherein at least one of R 1 , R 2 and R 3 is a compound according to formula (I). A polyurethane composition and method for forming a polyurethane foam are also disclosed.
摘要:
This invention disclosure relates to a process to make flexible open cell polyurethane foam with optimum mechanical properties and lowest chemical emissions. Using the selection of tertiary amine catalysts together with a group of carboxylic acids according to this disclosure can produce foam products with optimum properties and lowest chemical emanations.
摘要:
Polyurethane foam compositions and processes to make flexible polyurethane foams are disclosed. Polyurethane foam is produced in the presence of additives comprising guanidine derivatives. Improvements in physical properties such as air flow, dimensional stability, tensile, tear, elongation and foam hardness is observed when these additives are present in polyurethane formulations. In addition, these additives can minimize polymer degradation under humid ageing conditions resulting in foam products with better mechanical properties.
摘要:
A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH#
摘要:
An additive composition for making polyurethane foam where the additive composition is defined as at least one compound selected from the following groups: a. Aromatic ethers of general formula R-(CH2)x-Z-(CH2)y-R' where R = substituted or unsubstituted aryl group; Z = O or R"-N with R" = Ci-C8 alkyl group, and preferentially methyl or benzyl; x = 0-3; y = 0-3; and R' = substituted or unsubstituted aryl group where the substituents are non- isocyanate reactive groups or a Ci-C8 alkyl group; b. Aromatic ethers of general formula R-O-Aryl-O-R' where R = C1-C6 hydrocarbon; R' = CrC6 hydrocarbon; and aryl = alkyl/aryl substituted or unsubstituted where the substituents are non-isocyanate reactive groups; c. Aromatic esters of general formula R-02C-Aryl-C02-R' where R = CrC6 hydrocarbon; R' = CrC6 hydrocarbon; and aryl = substituted or unsubstituted aryl group where the substituents are non-isocyanate reactive groups; and d. Substituted aromatic compounds of the general formula Rx-Aryl where R = Ci-C6 hydrocarbon; x = 1 -6; and aryl = substituted or unsubstituted aromatic derived from benzene, naphthalene, anthracene, or phenanthrene. A polyurethane composition and method for forming a polyurethane foam is also disclosed.
摘要:
A composition and method for producing a tertiary amine is disclosed. The tertiary amine is contacted with an inert gas. The inert gas is nitrogen or more preferably argon. The amine composition is useful in producing polyurethane foam with lower levels of chemical emissions particularly lower emissions of toxic chemicals.
摘要:
Disclosed are processes, products, and compositions having tetraalkylguanidine salt of aromatic acid. The processes include providing a pre-mix comprising an aromatic carboxylic acid component and contacting a tetraalkylguanidine with the aromatic carboxylic acid component in the pre-mix to form the tetraalkylguanidine salt of aromatic carboxylic acid or producing a catalyst composition by contacting the tetraalkylguanidine with the aromatic carboxylic acid component to form the tetraalkylguanidine salt of aromatic carboxylic acid. The compositions include the tetraalkylguanidine salt of aromatic carboxylic acid. The product is formed by the tetraalkylguanidine salt of aromatic carboxylic acid.
摘要:
Disclosed are a process of producing a polyurethane foam product, a polyurethane foam product pre-mix, polyurethane foam product formulation, and a polyurethane foam product. The process of producing the polyurethane foam product includes contacting a halohydrin component with a polyurethane foam product pre-mix. The polyurethane foam product pre-mix includes the halohydrin component. The polyurethane foam product formulation includes a polyol component, an isocyanate component, and a halohydrin component. The polyurethane foam product is formed by the pre-mix having the halohydrin component.