公开(公告)号：WO2010149746A1

公开(公告)日：2010-12-29

申请号：PCT/EP2010/059009

申请日：2010-06-24

Applicant: BASF SE ,  OHRBOM, Walter H. ,  MENOVCIK, Gregory G. ,  MORMILE, Patrick J. ,  CAMPBELL, Donald H. ,  CRANFILL, David

Inventor： OHRBOM, Walter H. ,  MENOVCIK, Gregory G. ,  MORMILE, Patrick J. ,  CAMPBELL, Donald H. ,  CRANFILL, David

IPC: B05D1/36 ,  B05D7/00 ,  C09D4/00

CPC classification number: B05D1/36 ,  B05D7/52 ,  C09D4/00 ,  Y10T428/31507 ,  Y10T428/31515 ,  Y10T428/31536

Abstract: A paint coating system comprises a substrate and a first paint layer disposed on the substrate. The first paint layer is formed from a first composition comprising either a first decomplexing agent or a first organoborane complex. The paint coating system further comprises a second paint layer disposed on the first paint layer. The second paint layer is formed from a second composition comprising the other of the first decomplexing agent and the first organoborane complex. At least one of the first and second compositions further comprises a radical polymerizable compound. A method of producing a multilayered paint coating includes the steps of providing the substrate, applying a first paint layer on the substrate, applying a second paint layer on the first paint layer, and curing the at least one of the first and second paint layers.

Abstract translation: 涂料系统包括基材和设置在基材上的第一涂料层。 第一涂料层由包含第一解络剂或第一有机硼烷络合物的第一组合物形成。 涂料系统还包括设置在第一涂料层上的第二涂料层。 第二涂层由第二组合物形成，第二组合物包含第一解络剂和第一有机硼烷络合物中的另一种。 第一和第二组合物中的至少一种还包含自由基聚合性化合物。 制造多层涂料涂料的方法包括以下步骤：提供基材，在基材上施加第一涂料层，在第一涂料层上施加第二涂料层，并固化第一和第二涂料层中的至少一个。

公开(公告)号：WO2008036473A1

公开(公告)日：2008-03-27

申请号：PCT/US2007/075166

申请日：2007-08-03

Applicant: BASF CORPORATION ,  GREEN, Marvin L. ,  CAMPBELL, Donald H. ,  BOISSEAU, John E. ,  OERMANN, Bruce

Inventor： GREEN, Marvin L. ,  CAMPBELL, Donald H. ,  BOISSEAU, John E. ,  OERMANN, Bruce

IPC: C09D201/02

CPC classification number: C08J7/18 ,  C08J2377/12

Abstract: A coating composition is used to form a clearcoat layer of a film system including a basecoat layer and the clearcoat layer. The coating composition includes a carbamate functional polymer, a cross-linking agent reactive with the carbamate functional polymer, and an acid functional polymer substantially non-reactive with the carbamate functional polymer and the cross-linking agent. The acid functional polymer has an acid value of at least 50 mg KOH/g and contributes to an increased resistance to acid etch of the clearcoat layer. The acid functional polymer also contributes to an increased intercoat adhesion of the basecoat layer and the clearcoat layer thereby decreasing a possibility of separation/delamination of the basecoat layer and the clearcoat layer.

Abstract translation: 涂料组合物用于形成包括底涂层和透明涂层的膜系统的透明涂层。 涂料组合物包括氨基甲酸酯官能聚合物，与氨基甲酸酯官能聚合物反应的交联剂和与氨基甲酸酯官能聚合物和交联剂基本上不反应的酸官能聚合物。 酸官能聚合物具有至少50mg KOH / g的酸值，并且有助于增加对透明涂层的酸蚀刻的耐受性。 酸官能聚合物还有助于增加底涂层和透明涂层的层间粘附性，从而降低了底涂层和透明涂层的分离/分层的可能性。

公开(公告)号：WO2007044736A3

公开(公告)日：2007-11-01

申请号：PCT/US2006039585

申请日：2006-10-06

Applicant: BASF CORP ,  BOISSEAU JOHN E ,  CAMPBELL DONALD H ,  OHRBOM WALTER H ,  BALATAN SERGIO E ,  MENOVCIK GREGORY G

Inventor： BOISSEAU JOHN E ,  CAMPBELL DONALD H ,  OHRBOM WALTER H ,  BALATAN SERGIO E ,  MENOVCIK GREGORY G

IPC: C08F20/10 ,  C08C19/22 ,  C08C19/28 ,  C08C19/30 ,  C08C19/34

CPC classification number: C09D133/066 ,  C08G18/6254 ,  C08G18/627 ,  C08G18/80 ,  C08K3/36 ,  C08K5/0008 ,  C09D133/06 ,  C09D175/04

Abstract: A clearcoat coating composition comprises a vinyl or acrylic polymeric resin prepared by reacting a functional group on a vinyl or acrylic polymer, wherein the polymer has a glass transition temperature (T g ) = 40 °C as calculated by the Fox equation, with a reactant that provides a curable functional group that is separated from the polymer backbone by at least two alkylene, cycloalkylene, or arylene groups of at least two carbons each long.

Abstract translation: 透明涂层涂料组合物包含通过在乙烯基或丙烯酸类聚合物上的官能团反应制备的乙烯基或丙烯酸类聚合物树脂，其中该聚合物的玻璃化转变温度（T gg）= 40℃， Fox方程与提供可固化官能团的反应物反应，所述可固化官能团通过至少两个每个长度至少两个碳的亚烷基，亚环烷基或亚芳基与聚合物主链分开。

公开(公告)号：WO2007037860A1

公开(公告)日：2007-04-05

申请号：PCT/US2006/033042

申请日：2006-08-24

Applicant: BASF CORPORATION ,  RAMESH, Swaminathan ,  CAMPBELL, Donald ,  GREEN, Marvin ,  RINK, Heinz-Peter

Inventor： RAMESH, Swaminathan ,  CAMPBELL, Donald ,  GREEN, Marvin ,  RINK, Heinz-Peter

IPC: C09D201/02 ,  C09D133/06

CPC classification number: C09D133/06 ,  C08F8/14 ,  C08F220/06 ,  C08F220/18 ,  C08F220/32 ,  C08F220/36 ,  C09D4/00 ,  C09D133/062 ,  C09D201/025 ,  C08L2666/02

Abstract: A coating composition including a copolymerization product of a mixture of monomers including one or more carbamate-functional monomers and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomers. The coating composition may be a solvent- borne clearcoat coating composition, preferably an automotive clearcoat coating composition, that may be applied over a water-borne basecoat coating composition.

Abstract translation: 一种涂料组合物，其包括包含一种或多种氨基甲酸酯官能单体和（甲基）丙烯酸单体的单体混合物的共聚产物，一些具有羧酸官能团。 单体混合物基本上不含羟基单体。 涂料组合物可以是可涂覆在水性底涂层组合物上的溶剂型透明涂料涂料组合物，优选汽车透明涂料涂料组合物。

公开(公告)号：WO2006039013A1

公开(公告)日：2006-04-13

申请号：PCT/US2005/030248

申请日：2005-08-26

Applicant: BASF CORPORATION ,  OHRBOM, Walter ,  CAMPBELL, Donald ,  ST. AUBIN, Donald ,  RAMESH, Swaminathan ,  HARRIS, Paul ,  RÖCKRATH, Ulrike

Inventor： OHRBOM, Walter ,  CAMPBELL, Donald ,  ST. AUBIN, Donald ,  RAMESH, Swaminathan ,  HARRIS, Paul ,  RÖCKRATH, Ulrike

IPC: C08F20/00

CPC classification number: C08F220/06 ,  C08F8/00 ,  C08F8/14 ,  C08F220/08 ,  C08F222/20 ,  C08F222/22 ,  C08L2312/00 ,  C09D133/14 ,  C09D201/025 ,  C08F265/06

Abstract: Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C=C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C=C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.

Abstract translation: 公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。 该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C = C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C = C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。 还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

公开(公告)号：WO2002086001A1

公开(公告)日：2002-10-31

申请号：PCT/US2002/012845

申请日：2002-04-23

Applicant: BASF CORPORATION ,  CAMPBELL, Donald ,  COOK, Vincent ,  OERMANN, Bruce ,  BEARYMAN, William

Inventor： CAMPBELL, Donald ,  COOK, Vincent ,  OERMANN, Bruce ,  BEARYMAN, William

IPC: C09D201/02

CPC classification number: C09D201/025 ,  C08L61/32 ,  C09D133/14 ,  C09D161/20 ,  C09D161/34 ,  C09D175/04 ,  Y10T428/31551 ,  C08L2666/16

Abstract: The invention provides coating compositions having improved scratch and mar resistance. The curable coating compositions of the invention comprise a film-forming component (A) comprising one or more active hydrogen containing components (a), and one or more curing agents (b) comprising at least one aminoplast resin (bi) having from 0.5 to 3.5 moles of NH per mole of aminoplast resin (bi), a blocked acid catalyst (B) having a blocking agent which is not a tertiary amine, and a tertiary amine (C) present in an amount equal to 10 to 150% by weight of the blocking agent. The invention further provides a method of making cured coated substrates having improved scratch and mar resistance as well as a method of making multilayer coating compositions.

Abstract translation: 本发明提供了具有改善的耐划伤性和耐擦伤性的涂料组合物。 本发明的可固化涂料组合物包含含有一种或多种含活性氢成分（a）的成膜组分（A）和一种或多种包含至少一种具有0.5至 3.5摩尔NH /摩尔氨基塑料树脂（bi），具有不是叔胺的封闭剂的封闭酸催化剂（B）和等于10至150重量％的叔胺（C） 的阻断剂。 本发明还提供了一种制备具有改善的耐划伤性和耐擦伤性的固化的涂覆基材的方法以及制备多层涂料组合物的方法。

公开(公告)号：WO2002085540A1

公开(公告)日：2002-10-31

申请号：PCT/US2002/012846

申请日：2002-04-23

Applicant: BASF CORPORATION ,  CAMPBELL, Donald ,  COOK, Vincent ,  OERMANN, Bruce ,  BEARYMAN, William

Inventor： CAMPBELL, Donald ,  COOK, Vincent ,  OERMANN, Bruce ,  BEARYMAN, William

IPC: B05D1/36

CPC classification number: B05D7/536 ,  C09D161/20 ,  C09D161/32 ,  C09D201/00 ,  C09D201/025 ,  C08L2666/14

Abstract: The invention provides curable coating compositions which have improved compatibility with other coating compositions and which provide improved scratch and mar resistance. The compositions comprise a film-forming component (A), a catalyst (B) for the film-forming reaction comprising one or more strong acids having a pK a of 2.5 or less, and a volatile catalyst carrier (C) comprising one or more tertiary amines having a boiling point of 100 degrees C. The film-forming component (A) comprises one or more crosslinking agents (b) at least one of which is an aminoplast curing agent (bi) having from 0.5 to 3.5 moles of NH per mole of aminoplast curing agent (bi). The invention also provides a method of making thermally cured films having improved scratch and mar as well as a method of making multilayer-cured films.

Abstract translation: 本发明提供了具有改善的与其它涂料组合物的相容性并且提供改善的耐刮擦和耐擦伤性的可固化涂料组合物 组合物包含成膜组分（A），用于成膜反应的催化剂（B），其包含一种或多种pKa为2.5或更小的强酸，和包含一种或多种叔碳酸酯的挥发性催化剂载体（C） 沸点为100℃的胺。成膜组分（A）包含一种或多种交联剂（b），其中至少一种是每摩尔0.5至3.5摩尔NH的氨基塑料固化剂（bi） 的氨基塑料固化剂（bi）。 本发明还提供一种制备具有改进的划痕和耐磨性的热固化膜的方法以及制备多层固化膜的方法。

公开(公告)号：WO2012145241A1

公开(公告)日：2012-10-26

申请号：PCT/US2012/033528

申请日：2012-04-13

Applicant: DOW TECHNOLOGY INVESTMENTS LLC ,  BASF SE ,  EISENSCHMID, Thomas, C. ,  BECKER, Michael, C. ,  CAMPBELL, Donald, L. ,  BRAMMER, Michael, A. ,  MILLER, Glenn, A. ,  LORD, Adrian ,  RUDOLPH, Jens ,  REEH, Hans-Rudiger

Inventor： EISENSCHMID, Thomas, C. ,  BECKER, Michael, C. ,  CAMPBELL, Donald, L. ,  BRAMMER, Michael, A. ,  MILLER, Glenn, A. ,  LORD, Adrian ,  RUDOLPH, Jens ,  REEH, Hans-Rudiger

IPC: B01J31/18 ,  C07C45/50 ,  C07C45/80 ,  C07F9/02

CPC classification number: B01J31/0255 ,  B01J31/185 ,  B01J31/186 ,  B01J2231/321 ,  B01J2531/822 ,  C07F9/5721 ,  C07F9/5728 ,  Y02P20/582

Abstract: The catalyst solution used in a hydroformylation process is prepared for storage by first reducing its acid concentration and/or water content, and then storing the solution under a blanket of syngas and/or an inert gas. Alternatively, or in addition to, the catalyst solution can be stored with an aqueous buffer comprising materials that will neutralize and/or absorb the acid species within the catalyst solution.

Abstract translation: 通过首先降低其酸浓度和/或水含量，然后将溶液储存在合成气和/或惰性气体的毯子下，制备用于加氢甲酰化方法的催化剂溶液用于储存。 或者，或除此之外，催化剂溶液可以与包含将中和和/或吸收催化剂溶液中的酸物质的材料的含水缓冲液一起储存。

公开(公告)号：WO2010149637A1

公开(公告)日：2010-12-29

申请号：PCT/EP2010/058773

申请日：2010-06-22

Applicant: BASF SE ,  GUTOWSKI, Keith E. ,  OHRBOM, Walter H. ,  CRANFILL, David ,  CAMPBELL, Donald H.

Inventor： GUTOWSKI, Keith E. ,  OHRBOM, Walter H. ,  CRANFILL, David ,  CAMPBELL, Donald H.

IPC: C09D4/00 ,  C09D133/08 ,  C08K5/55 ,  C08J3/24 ,  C08K5/00

CPC classification number: C09D133/08 ,  C08J3/24 ,  C08K5/55 ,  C09D4/00

Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.

Abstract translation: 提供固化涂料组合物的方法和在汽车部件上形成固化涂层的方法。 涂料组合物包含可自由基聚合的化合物和具有有机硼烷引发剂，胺封闭剂和水的有机硼烷 - 胺络合物。 固化涂料组合物的方法包括将有机硼烷 - 胺络合物，可自由基聚合的化合物和水组合以形成涂料组合物的步骤。 在形成涂料组合物之前，将二氧化碳引入涂料组合物或包含至少一种有机硼烷 - 胺络合物，可自由基聚合的化合物和水的组合物。 碳酸通过水和二氧化碳的反应在涂料组合物中原位形成。 有机硼烷 - 胺络合物与碳酸分解，从而分离有机硼烷引发剂和胺封闭剂。 使用有机硼烷引发剂在氧的存在下使自由基聚合性化合物聚合。

公开(公告)号：WO2010085627A1

公开(公告)日：2010-07-29

申请号：PCT/US2010/021775

申请日：2010-01-22

Applicant: TUTCO, INC. ,  CARLAY, Ronald, L. ,  CAMPBELL, Donald, Bradley

Inventor： CARLAY, Ronald, L. ,  CAMPBELL, Donald, Bradley

IPC: F16L11/04

CPC classification number: F16L11/045 ,  B32B1/08 ,  B32B5/022 ,  B32B27/08 ,  F16L11/081 ,  F16L2011/047 ,  F24F13/0218 ,  Y10T29/49822 ,  Y10T29/53

Abstract: A flexible HVAC duct is made with a support structure-containing duct liner, insulation layer, and reinforcing layer-containing vapor barrier. At least the duct liner and vapor barrier are constructed of polymer materials that enable them to be placed in one or more recycling streams once the flexible HVAC duct is removed from its installed location. The insulation layer can also be made of a polymer material compatible with that used for the duct liner and vapor barrier so that the entire duct can be recycled once removed.

Abstract translation: 柔性HVAC管道由具有支撑结构的管道衬套，绝缘层和含增强层的蒸汽阻挡层制成。 至少导管衬里和蒸汽屏障由聚合物材料构成，使得一旦将柔性HVAC导管从其安装位置移除就能将它们放置在一个或多个再循环流中。 绝缘层还可以由与用于管道衬垫和蒸气阻挡层的材料相容的聚合物材料制成，使得整个管道可以一旦被去除就被再循环。