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公开(公告)号:WO2010056386A1
公开(公告)日:2010-05-20
申请号:PCT/US2009/038348
申请日:2009-03-26
CPC分类号: C25D9/04 , C09D5/08 , C09D5/4411 , C09D5/4484 , C25D5/48 , C25D11/02 , C25D11/26 , C25D11/34 , C25D11/36 , C25D11/38
摘要: This invention relates to a method for the post-treatment of metal layers, especially for the post-treatment of metal layers deposited on the surface of a substrate. With the invention a method for the post-treatment of a metal surface is proposed, wherein the metal surface is brought into contact with a corrosion resistance increasing solution, characterised in that during the contacting of the metal surface with the corrosion resistance increasing solution a current is applied between the surface and a counter electrode, whereby the surface is anodic contacted and the counter electrode is cathodic contacted.
摘要翻译: 本发明涉及金属层的后处理方法,特别是用于后处理沉积在基材表面上的金属层。 本发明提出了金属表面的后处理方法,其中金属表面与耐腐蚀性增加溶液接触,其特征在于,在金属表面与耐腐蚀性增加溶液的接触期间,电流 施加在表面和对电极之间,由此表面被阳极接触并且对电极是阴极接触的。
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公开(公告)号:WO2010057001A3
公开(公告)日:2010-08-19
申请号:PCT/US2009064394
申请日:2009-11-13
CPC分类号: C25D9/04 , C09D5/08 , C09D5/4411 , C09D5/4484 , C25D5/48 , C25D11/02 , C25D11/26 , C25D11/34 , C25D11/36 , C25D11/38
摘要: A process for treating the surface of a metal substrate comprising a constituent metal selected from the group consisting of Cr, Cu, Mn, Mo, Ag, Au, Pt, Pd, Rh, Pb, Sn, Ni, Zn, in some cases Fe, and alloys of these metals. An anodic potential is applied to the metal surface in an electrolytic circuit comprising the metal surface, a cathode, and an electrolytic solution that is in contact with the metal surface and in electrically conductive communication with the cathode. The electrolytic solution may contain an electrolyte comprising anions of phosphate, phosphonate, phosphite, phosphinate, nitrate, borate, silicate, molybdate, tungstate, carboxylate, oxalate and combinations thereof. The anion may comprise a polymer having a pendent moiety selected from the group consisting of phosphate, phosphonate, phosphite, phosphinate, sulfate, sulfonate, carboxylate and combinations thereof. The potential applied to the circuit is such that the substrate is anodically oxidized and reacts with the anion to form a composition that imparts an enhanced property to the metal surface. Preferably, the pH of the electrolytic solution is less than about 6.0, the potential applied is between about 0.5 and about 20 volts, and the current density is between about 0.01 and 2 amps/dm2 of the geometric surface area of metal in contact with the electrolytic solution and is controlled such that nascent cations of said constituent metal produced by anodic oxidation of said constituent metal react with said anions at the metal surface without significant formation of any oxide or hydroxide of said constituent metal.
摘要翻译: 处理包含选自Cr,Cu,Mn,Mo,Ag,Au,Pt,Pd,Rh,Pb,Sn,Ni,Zn的组成金属的金属基材的表面的方法,在一些情况下Fe ,以及这些金属的合金。 在包括金属表面,阴极和与金属表面接触并与阴极导电连通的电解溶液的电解电路中对金属表面施加阳极电位。 电解液可含有包含磷酸盐,膦酸盐,亚磷酸盐,次膦酸盐,硝酸盐,硼酸盐,硅酸盐,钼酸盐,钨酸盐,羧酸盐,草酸盐及其组合的阴离子的电解质。 阴离子可以包含具有选自磷酸酯,膦酸酯,亚磷酸酯,次膦酸酯,硫酸酯,磺酸酯,羧酸酯及其组合的侧挂部分的聚合物。 施加到电路上的电位使得衬底被阳极氧化并与阴离子反应以形成赋予金属表面增强性质的组合物。 优选地,电解溶液的pH值小于约6.0,施加的电位在约0.5和约20伏之间,电流密度在与金属接触的几何表面积的约0.01和2安培/平方分米之间 并且被控制为使得通过所述构成金属的阳极氧化产生的所述构成金属的新生阳离子与所述金属表面处的所述阴离子反应而不显着形成所述构成金属的任何氧化物或氢氧化物。
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公开(公告)号:WO2010057001A2
公开(公告)日:2010-05-20
申请号:PCT/US2009/064394
申请日:2009-11-13
申请人: ENTHONE INC. , ELBICK, Danica , PRINZ, Dr. Ulrich , KÖNIGSHOFEN, Dr. Andreas , DAHLHAUS, Markus
CPC分类号: C25D9/04 , C09D5/08 , C09D5/4411 , C09D5/4484 , C25D5/48 , C25D11/02 , C25D11/26 , C25D11/34 , C25D11/36 , C25D11/38
摘要: A process for treating the surface of a metal substrate comprising a constituent metal selected from the group consisting of Cr, Cu, Mn, Mo, Ag, Au, Pt, Pd, Rh, Pb, Sn, Ni, Zn, in some cases Fe, and alloys of these metals. An anodic potential is applied to the metal surface in an electrolytic circuit comprising the metal surface, a cathode, and an electrolytic solution that is in contact with the metal surface and in electrically conductive communication with the cathode. The electrolytic solution may contain an electrolyte comprising anions of phosphate, phosphonate, phosphite, phosphinate, nitrate, borate, silicate, molybdate, tungstate, carboxylate, oxalate and combinations thereof. The anion may comprise a polymer having a pendent moiety selected from the group consisting of phosphate, phosphonate, phosphite, phosphinate, sulfate, sulfonate, carboxylate and combinations thereof. The potential applied to the circuit is such that the substrate is anodically oxidized and reacts with the anion to form a composition that imparts an enhanced property to the metal surface. Preferably, the pH of the electrolytic solution is less than about 6.0, the potential applied is between about 0.5 and about 20 volts, and the current density is between about 0.01 and 2 amps/dm 2 of the geometric surface area of metal in contact with the electrolytic solution and is controlled such that nascent cations of said constituent metal produced by anodic oxidation of said constituent metal react with said anions at the metal surface without significant formation of any oxide or hydroxide of said constituent metal.
摘要翻译: 一种用于处理包括选自Cr,Cu,Mn,Mo,Ag,Au,Pt,Pd,Rh,Pb,Sn,Ni,Zn中的组成金属的金属基材的表面的方法,在某些情况下为Fe ,以及这些金属的合金。 在包括金属表面,阴极和与金属表面接触并与阴极导电连通的电解液的电解电路中,将金属表面施加阳极电位。 电解液可以含有包含磷酸盐,膦酸盐,亚磷酸盐,次膦酸盐,硝酸盐,硼酸盐,硅酸盐,钼酸盐,钨酸盐,羧酸盐,草酸盐及其组合的阴离子的电解质。 阴离子可以包含具有选自磷酸盐,膦酸盐,亚磷酸盐,次膦酸盐,硫酸盐,磺酸盐,羧酸盐及其组合的侧悬链部分的聚合物。 施加到电路的电位使得基板被阳极氧化并与阴离子反应形成赋予金属表面增强性能的组合物。 优选地,电解溶液的pH值小于约6.0,所施加的电位在约0.5至约20伏特之间,并且电流密度介于金属的几何表面积的约0.01和2安培/ dm 2之间 并且被控制,使得通过所述构成金属的阳极氧化产生的所述构成金属的初生阳离子与金属表面上的所述阴离子反应,而不显着形成所述组成金属的任何氧化物或氢氧化物。
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公开(公告)号:WO0151681A3
公开(公告)日:2001-12-27
申请号:PCT/EP0100232
申请日:2001-01-09
发明人: JUELICHER PETER , DAHLHAUS MARKUS
CPC分类号: C23C22/53 , C23C2/04 , C23C30/00 , C23C2222/10 , C25D3/00
摘要: The invention relates to an object with a coated surface, said coating is either made from a metal, or from a metal coating with a conversion layer, whereby the surface contains a visibly fluorescent or phosphorescent material. The coated surface can contain one or several of the following elements: nickel, zinc, chromium, gold, silver, ruthenium, palladium or copper. Said surface, however, can also contain brass, phosphate, nickel, copper or gold. The coated surface can contain a metal oxide. The metal can be aluminium, titanium or magnesium. In a method for the production of said object, the coating is applied by means of a galvanic or chemical method. The coating can also be applied by anodisation or by vacuum coating. The fluorescent or phosphorescent material is applied in the form of microcapsules in the solution, or is in the form of a pigment and applied as a suspension in the solution.
摘要翻译: 在具有涂层的表面的制品,其中所述涂层由任一金属的或通过用转换层上的金属涂层形成时,表面可见含有荧光或磷光材料。 涂覆的表面可以是一个或多个下列元素:镍,锌,铬,金,银,钌,钯,铜。 但它也可以包含黄铜或磷,镍,铜或金。 涂覆的表面可包括金属氧化物。 该金属可以是铝,钛或镁。 在用于制造这种制品的方法,该涂层是通过电镀工艺或化学的手段施加。 该涂层也可以通过阳极氧化产生的或通过真空沉积涂布。 荧光或磷光材料在溶液中的微胶囊的形式被引入,或者它是在颜料前的形式,并且被引入作为在溶液中的悬浮液。
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