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    YELLOW CATIONIC DYES FOR DYING OF ORGANIC MATERIAL
    2.
    发明申请
    YELLOW CATIONIC DYES FOR DYING OF ORGANIC MATERIAL 审中-公开
    用于染色有机物的黄色阳离子染料

    公开(公告)号：WO2003060015A1

    公开(公告)日：2003-07-24

    申请号：PCT/EP2003/000068

    申请日：2003-01-07

    Applicant: CIBA SPECIALITY CHEMICALS HOLDING INC. ,  ELIU, Victor Paul ,  FRÖHLING, Beate ,  HAUSER, Julia

    Inventor： ELIU, Victor Paul ,  FRÖHLING, Beate ,  HAUSER, Julia

    IPC: C09B26/04

    CPC classification number: C09B26/04

    Abstract: The present invention relates to novel cationic yellow dyes of formula (1) wherein R 1 and R 2 are each independently of the other a C 1 -C 8 alkyl radical or an unsubstituted or substituted benzyl radical, R 3 is hydrogen, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, cyanide or halide, preferably hydrogen and X is an anion, with the proviso that at least one of the substitutents R 1 is a benzyl radical and R 2 is a methyl radical, R 2 is not hydrogen, also to compositions therof, especially comprising other dyes, to processes for the preparation therof and to the use therof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, especially keratin-containging fibres, cotton or nylon, and preferably human hair.

    Abstract translation: 本发明涉及式（1）的新型阳离子黄色染料，其中R1和R2各自独立地为C1-C8烷基或未取代或取代的苄基，R3为氢，C1-C8烷基，C1-C8烷氧基，氰化物 或卤化物，优选氢，X是阴离子，条件是至少一个取代基R 1是苄基，R 2是甲基，R 2不是氢，也包括其它染料的组合物，特别是其它染料 用于制备和用于染色有机材料如角蛋白，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，优选人发的用途。

    2,5-DIAMINO SUBSTITUTED AZO DYES
    4.
    发明申请
    2,5-DIAMINO SUBSTITUTED AZO DYES 审中-公开
    2,5-DIAMINO取代的AZO染料

    公开(公告)号：WO2005095522A2

    公开(公告)日：2005-10-13

    申请号：PCT/EP2005/051323

    申请日：2005-03-23

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  ELIU, Victor Paul ,  SAUDER, Thomas ,  KAUFFMANN, Dominique ,  FRÖHLING, Beate

    Inventor： ELIU, Victor Paul ,  SAUDER, Thomas ,  KAUFFMANN, Dominique ,  FRÖHLING, Beate

    IPC: C09B44/16

    CPC classification number: C09B44/16

    Abstract: Disclosed are azo dyes of formula (1) , wherein R 1 is hydrogen; C 1 -C 14 alkyl; hydroxy- C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a) -(CH 2 ) n1 -O-(CH 2 ) n2 -CH 3 ; a radical of formula (1b) C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R3 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 1 0aryl-C 1 -C 6 alkyl; or CO-R 6 ; R 4 is CO-R 6 ; R 5 is C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R 6 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; or C 6 -C 10 aryl; R 7 , R 8 , R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; m is 1; or 2; An - is an anion; If m = 1, R 2 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a); a radical of formula (1b) ; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; If m = 2, R 2 is the direct bond; or C 1 -C 14 alkylene, which is optionally substituted by one or more C 1 -C 4 alkyl, or which is optionally interrupted by C 5 -C 10 arylene, -O- or -NR 9 R 10 -; R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.

    Abstract translation: 公开了式（1）的偶氮染料，其中R 1是氢; ç<子> 1 -C <子> 14 烷基; 羟基-C 1 -C 14 - 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a） - （CH 2）n1 -O-（CH 2）n2 -n- CH <子> 3 ; 式（1b）C10芳基的基团; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R3是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; ç<子> 6 -C <子> 1 0aryl-C <子> 1 -C <子> 6 烷基; 或CO-R 6; R 4是CO-R 6; R 5是C 1 -C 14烷基; R 5是C 1 -C 14烷基。 ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R 6是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 或C≡C-C10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m是1; 或2; An - 是一个阴离子; 如果m = 1，则R 2是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a）的基团; 式（1b）的基团; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 如果m = 2，则R 2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基 ，或者任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10取代的亚苯基， > - ; R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; 并且n1，n2，n3和n4彼此独立地为0-5的数。所述化合物可用于染色有机材料，优选人发。

    CATIONIC DIRECT DYES
    5.
    发明申请
    CATIONIC DIRECT DYES 审中-公开
    阳光直射

    公开(公告)号：WO2005012437A1

    公开(公告)日：2005-02-10

    申请号：PCT/EP2004/051481

    申请日：2004-07-14

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  ELIU, Victor, Paul ,  FRÖHLING, Beate

    Inventor： ELIU, Victor, Paul ,  FRÖHLING, Beate

    IPC: C09B44/16

    CPC classification number: C09B44/16

    Abstract: The present invention relates to novel the cationic dyes of formula (1) wherein R 1 is an unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical; X - is an anion; R 3 is an unsubstituted or substituted C 1 -C 14 alkyl, aryl radical, C 1 -C 6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R 2 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl; or if n is 2, then R 2 is an unsubstituted or substituted C 1 -C 14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair.

    Abstract translation: 本发明涉及式（1）的阳离子染料，其中R 1是未取代或取代的C 1 -C 14烷基或芳基; X - 是阴离子; R 3是未取代或取代的C 1 -C 14烷基，芳基，C 1 -C 6烷氧基，氰基，硝基或卤素; n为1或2; 如果n为1，则R2为氢，未取代或取代的C 1 -C 14烷基; 或者如果n为2，则R2为未取代或取代的C1-C14亚烷基。 此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纸，纤维素或聚酰胺中的用途，以及 优选人发。

    CATIONIC DYES, THEIR PRODUCTION AND USE
    6.
    发明申请
    CATIONIC DYES, THEIR PRODUCTION AND USE 审中-公开
    阳光染色体，其生产和使用

    公开(公告)号：WO2004076564A1

    公开(公告)日：2004-09-10

    申请号：PCT/EP2004/050132

    申请日：2004-02-16

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  ELIU, Victor Paul ,  FRÖHLING, Beate

    Inventor： ELIU, Victor Paul ,  FRÖHLING, Beate

    IPC: C09B69/06

    CPC classification number: C09B69/065 ,  A61K8/4946 ,  A61Q5/065 ,  C09B44/103

    Abstract: The present invention relates to novel cationic dye of formula (1) wherein R 1 and R 7 are each independently of the other hydrogen, hydroxyl; unsubstituted or substituted C 1 -C 6 alkyl, aryl radical or C 1 I-C 6 alkoxy; or -NR 3 R 4 , wherein R 3 and R 4 are each independently of the other hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and R 2 is hydrogen, hydroxyl, unsubstituted or substituted C 1 ­C 6 alkyl, aryl radical or C 1 -C 6 alkoxy, - NR3R4 , or an organic radical of formula (2) wherein R 5 is hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, and preferably human hair.

    Abstract translation: 本发明涉及式（1）的新型阳离子染料，其中R 1和R 7各自独立地为氢，羟基; 未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基; 或-NR 3 R 4，其中R 3和R 4各自独立地为氢，未取代或取代的芳基或C 1 -C 6烷基，且R 2为氢，羟基，未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基，-NR 3 R 4或 式（2）的有机基团，其中R 5是氢，未取代或取代的芳基或C 1 -C 6烷基，X是阴离子。 此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纤维素或聚酰胺，优选人 头发。

    TRICATIONIC DYES
    8.
    发明申请
    TRICATIONIC DYES 审中-公开

    公开(公告)号：WO2007144280A2

    公开(公告)日：2007-12-21

    申请号：PCT/EP2007055442

    申请日：2007-06-04

    Applicant: CIBA SC HOLDING AG ,  CREMER CHRISTIAN ,  WALLQUIST OLOF ,  ELIU VICTOR PAUL ,  NIVALKAR KISHOR RAMACHANDRA

    Inventor： CREMER CHRISTIAN ,  WALLQUIST OLOF ,  ELIU VICTOR PAUL ,  NIVALKAR KISHOR RAMACHANDRA

    CPC classification number: A61Q5/10 ,  A61K8/49 ,  A61K8/4926 ,  A61K8/4946 ,  A61K8/4966 ,  C09B23/145 ,  C09B26/04 ,  C09B44/005 ,  C09B44/08 ,  C09B44/126 ,  C09B44/16 ,  C09B55/002 ,  C09B55/004 ,  C09B69/001

    Abstract: Disclosed are compounds of formula (I); wherein D is an aromatic or a cationic heteroaromatic group, which is optionally substituted by C 1 -C 14 alkyl, C 1 -C 14 alkoxy, hydroxy-C 1 -C 14 alkyl, C 3 -C 8 cycloalkyl, -CN, NO 2 , -NR 3 R 4 , halogen, C 6 -C 10 aryl, which is optionally substituted or C 1 -C 14 alkyl, or by one or more groups Z; E 1 and E 2 independently from each other are =CH; or =N-; K is an aromatic or heteroaromatic group which is optionally substituted by C 1 -C 14 alkyl, C 1 -C 14 alkoxy, C 3 -C 8 cycloalkyl, C 6 -C 10 aryl, halogen, hydroxy, NO 2 , -NR 3 R 4 , -N(R 3 )(CO)R 4 , -SO 2 NR 1 R 2 , -SONR 1 R 2 or by one or more Z; or a radical of formula -NR 1 R 2 ; R 1 and R 2 independently from each other are hydrogen; C 1 -C 14 alkyl; cyclo-C 1 -C 14 alkyl; C 6 - C 10 aryl; an aromatic or heteroaromatic group which is optionally substituted by C 1 - C 14 alkyl, C 1 -C 14 alkoxy, C 3 -C 8 cycloalkyl, C 6 -C 10 aryl, halogen, hydroxy, -NR 5 R 6 , -N(R 5 )-(CO)R 5 or by Z; Z is a group of the formula (1 a) *- X 1 -Y 1 -W 1 , wherein X 1 is the direct bond; -NR 7 -; -0-; -NR 7 (C=O)-; -(CO)NR 7 -; -0(C=O)-; -(CO)O-; or -(C=O)-; Y 1 is the direct bond; C 1 -C 12 alkylene, which is optionally interrupted by -0-, -NR 8 , -S-, -(C=O)-, -0(C=O)-, (C=O)O-, -NR 7 (C=O)-, -(C=O)NR 7 -, and which may substituted by C 1 -C 14 alkyl, hydroxy-C 1 -C 14 alkyl, hydroxy, -NR 9 R 10 or halogen; or C 6 -C 10 arylene, which may substituted by C 1 -C 14 alkyl, hydroxy-C 1 -C 14 alkyl, hydroxy, amino or halogen; W 1 is a cationic group; and R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and R 10 independently from each other are hydrogen; C 1 -C 14 alkyl; or Z; and An 1 -, An 2 - and An 3 - independently from each other are an anion. The compounds are useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, more preferably human hair.

    Abstract translation: 公开了式（I）的化合物; 其中D是芳族或阳离子杂芳族基团，其任选被C 1 -C 14烷基，C 1 -C 14亚烷基 烷氧基，羟基-C 1 -C 14烷基，C 3 -C 8烷基，C 3 -C 14烷基， 环烷基，-CN，NO 2，-NR 3 R 4，卤素，C 6 -C 任选被取代的C 1 -C 14芳基或C 1 -C 14烷基，或一个或多个基团Z; E 1和E 2彼此独立地为= CH; 或= N- K是任选被C 1 -C 14烷基，C 1 -C 14烷基取代的芳族或杂芳族基团， C 1 -C 4烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基， NO 2 R 3，-NR 3 R 4，-N（R 3）（CO）R 3， 4，-SO 2，NR 1，R 2，-SONR 1 R 2， /或一个或多个Z; 或式-NR 1 R 2的基团; R 1和R 2彼此独立地是氢; ç 1 -C 14 烷基; 环-C 1 -C 14 烷基; C 6 -C 10芳基; 任选被C 1 -C 14烷基，C 1 -C 14烷基取代的芳族或杂芳族基团， 烷氧基，C 3 -C 8环烷基，C 6 -C 10芳基，卤素，羟基，-NR N（R 5） - （CO）R 5或Z; Z是式（1a）的基团* -X 1 -Y 1 -W 1，其中X 1， / SUB>是直接债券; -NR 7 - ; -0-; -NR 7 （C = O） - ; - （CO）NR 7 - ; -O（C = O） - ; - （CO）O-; 或 - （C = O） - ; Y 1是直接键; C 1 -C 12亚烷基，其任选被-O-， - NR 8 - ， - S - ， - （C = O ） - ， - （C = O） - ，（C = O）O-，-NR 7（C = O） - ， - （C = O）NR 7 其可以被C 1 -C 14烷基取代，且可以被C 1 -C 14烷基，羟基-C 1 -C 14烷基取代 烷基，羟基，-NR 9 R 10或卤素; 或C 6 -C 10亚芳基，其可以被C 1 -C 14烷基取代，羟基-C C 1 -C 14烷基，羟基，氨基或卤素; W 1是阳离子基团; 和R 3，R 4，R 5，R 6，R 7， R 8，R 9和R 10彼此独立地是氢; ç 1 -C 14 烷基; 或Z; 和An 1 - ，An 2 - 和An 3 - 彼此独立地是阴离子。 这些化合物可用于染色有机材料，例如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，更优选人发。

    XANTHENE DYES
    9.
    发明申请
    XANTHENE DYES 审中-公开

    公开(公告)号：WO2007039502A3

    公开(公告)日：2007-05-24

    申请号：PCT/EP2006066673

    申请日：2006-09-25

    Applicant: CIBA SC HOLDING AG ,  ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    Inventor： ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    IPC: C09B11/24 ,  A61K8/00 ,  A61Q5/10 ,  C09B49/12

    CPC classification number: C09B49/126 ,  A61K8/49 ,  A61K8/498 ,  A61Q5/10 ,  C09B11/24 ,  C09B11/245

    Abstract: Disclosed are compounds of formula (1a), wherein R 1 is N + R 8 R 9 ; R 8 and/or R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 -alkyl; or R 8 and/or R 9 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R 2 is NR 10 R 11 ; or OR 10 ; R 10 and R 11 , independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; or R 10 and/or R 11 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16- membered carbocyclic ring; or R 10 and R 11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R 3 , R 4 , R 5 , R 6 and R 7 independently form each other are hydrogen; C 1 -C 12 alkyl; halogen; NR 12 R 13 ; or a radical of formula (1a 1 ); R 12 and R 13 independently from each other are hydrogen; C 1 -C 12 alkyl; phenyl-C 1 -C 4 alkyl; or a radical of formula (1a 2 ); V is -O-; Or -NR 15 ; R 14 , R 15 R- 16 and R 17 independently from each other are hydrogen; or C 1 -C 5 alkyl; and Hal is a halogen atom; and wherein at least one of R 3 , R 4 , R 5 , R 6 and R 7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibres with or without reducing agents.

    Abstract translation: 公开了式（1a）的化合物，其中R 1是N + R 8 R 9; R 8和/或R 9彼此独立地是氢; ç 1 -C 12 烷基; 或苯基-C 1 -C 4 - 烷基; 或R 8和/或R 9是二价C 3 -C 6亚烷基，其与 分别为碳原子C 1或C 2，并与连接氮原子一起形成6至16元碳环; R 2是NR 10 R 11; 或OR 10; R 10和R 11彼此独立地是氢; ç 1 -C 12 烷基; 或苯基-C 1 -C 4烷基; 或R 10和/或R 11是二价C 3 -C 6亚烷基，其与 碳原子C 3或C 4分别与连接氮原子或氧原子一起形成6至16元碳环; 或R 10和R 11与连接氮原子一起形成4至8元碳环; R 3，R 4，R 5，R 6和R 7独立地是 形成彼此是氢; ç 1 -C 12 烷基; 卤素; NR 12 - [R 13 ; 或式（1a 1）的基团; R 12和R 13彼此独立地是氢; ç 1 -C 12 烷基; 苯基-C 1 -C 4 烷基; 或式（1a 2>）的基团; V是-O-; 或-NR 15。 R 14，R 15，R 16，R 17和R 17彼此独立地是氢; 或C 1 -C 5烷基; Hal是卤素原子; 并且其中R 3，R 4，R 5，R 6和R 3中的至少一个， 7是氢。 该化合物可用于用或不含还原剂染色含角蛋白的纤维。

    XANTHENE DYES
    10.
    发明申请
    XANTHENE DYES 审中-公开
    黄嘌呤染料

    公开(公告)号：WO2007039502A2

    公开(公告)日：2007-04-12

    申请号：PCT/EP2006/066673

    申请日：2006-09-25

    Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  ELIU, Victor Paul ,  FRÖHLING, Beate ,  KAUFFMANN, Dominique

    Inventor： ELIU, Victor Paul ,  FRÖHLING, Beate ,  KAUFFMANN, Dominique

    CPC classification number: C09B49/126 ,  A61K8/49 ,  A61K8/498 ,  A61Q5/10 ,  C09B11/24 ,  C09B11/245

    Abstract: Disclosed are compounds of formula (1a), wherein R 1 is N + R 8 R 9 ; R 8 and/or R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 -alkyl; or R 8 and/or R 9 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R 2 is NR 10 R 11 ; or OR 10 ; R 10 and R 11 , independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; or R 10 and/or R 11 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16- membered carbocyclic ring; or R 10 and R 11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R 3 , R 4 , R 5 , R 6 and R 7 independently form each other are hydrogen; C 1 -C 12 alkyl; halogen; NR 12 R 13 ; or a radical of formula (1a 1 ); R 12 and R 13 independently from each other are hydrogen; C 1 -C 12 alkyl; phenyl-C 1 -C 4 alkyl; or a radical of formula (1a 2 ); V is -O-; Or -NR 15 ; R 14 , R 15 R- 16 and R 17 independently from each other are hydrogen; or C 1 -C 5 alkyl; and Hal is a halogen atom; and wherein at least one of R 3 , R 4 , R 5 , R 6 and R 7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibres with or without reducing agents.

    Abstract translation: 公开了式（1a）的化合物，其中R 1是N + 8 R 8 R 8， 9 ; R 8和/或R 9彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4 - 烷基;或苯基-C 1 -C 4 - 烷基。 或R 8和/或R 9是二价C 3 -C 6亚烷基，其连接到 碳原子C 1或C 2分别与连接的氮原子一起形成6至16元碳环; R 2 = NR 10 R 11; 或OR 10 ; R 10和R 11彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 或苯基-C 1 -C 4烷基;或苯基-C 1 -C 4烷基。 或R 10和/或R 11是二价C 3 -C 6亚烷基，其连接到 碳原子C 3或C 4分别与连接的氮或氧原子一起形成6至16元碳环; 或者R 10和R 11与连接的氮原子一起形成4至8元碳环; R 3，R 4，R 5，R 6和R 7各自独立地 彼此形成氢; ç<子> 1 -C <子> 12 烷基; 卤素; NR <子> 12 ř<子> 13 ; 或式（1a1）的基团; R 12和R 13彼此独立地为氢; ç<子> 1 -C <子> 12 烷基; 苯基-C <子> 1 -C <子> 4 烷基; 或式（1a2）的基团; V是-O-; 或-NR 15 15; R 14，R 15，R 16和R 17彼此独立地为氢; R 14，R 15，R 16和R 17彼此独立地为氢; 或C 1 -C 5烷基; Hal是卤素原子; 并且其中R 3，R 4，R 5，R 6和R 6中的至少一个为氢， 7是氢。 该化合物可用于含或不含还原剂的含角蛋白纤维的染色。

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