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    POLYMERIC HAIR DYES
    1.
    发明申请
    POLYMERIC HAIR DYES 审中-公开
    聚合物染发剂

    公开(公告)号：WO2011006946A2

    公开(公告)日：2011-01-20

    申请号：PCT/EP2010060175

    申请日：2010-07-15

    Applicant: BASF SE ,  CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    Inventor： CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    IPC: C09B26/04 ,  A61Q5/00 ,  C09B69/10

    CPC classification number: C09B26/04 ,  A61K8/84 ,  A61K2800/4324 ,  A61Q5/10 ,  C09B69/109

    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; which may be interrupted and/or terminated at one or both ends by one or more than one -C1C30alkylene- or -C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are -CR8- or -NR9+-; and at least one of Z1, Z2 or Z3 is -NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1- C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; -NO2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; or CH3-CO-NH-; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p = 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

    Abstract translation: 公开了式（1a），（1b）或（1c）的聚合物染料; 其中A和B彼此独立地表示聚合物骨架; X1和X2彼此独立地为选自-S - ， - SS - ， - N - ， - N = - ， - N（R5） - ， - S（O） - ， - SO2 - ， - （O） - ， - C（O）O - ， - OCO-，（式II）-CON（R 1） - ， -C（NR 1 R 2）2 - ， - （R 1）NC（O） - ， - C（S）R 1 - 其可以在一个或两个末端被一个或多个-C 1 -C 30亚烷基 - 或-C 2 -C 12亚烯基中断和/或终止; 或任选地包含至少一个杂原子的任选取代的饱和或不饱和的稠合或非稠合的芳族或非芳族（杂环）二价基团; 包含至少一个任选被C 1 -C 30烷基，C 1 -C 30烷氧基，C 2 -C 12烯基，C 5 -C 10芳基，C 5 -C 10环烷基，C 1 -C 10烷基（C 1 -C 10）烷基， C5-C10亚芳基），羟基或卤素; R1和R2彼此独立地为氢; 未取代或取代的直链或支链，单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 其中Z 1，Z 2和Z 3彼此独立地是-CR 8 - 或-NR 9 - ; - 并且Z 1，Z 2或Z 3中的至少一个是-NR 9 + - ; 其中Y 1和Y 2中的至少一个是有机染料的残基; R，R 3，R 4，R 5，R 6，R 7，R 8和R 9彼此独立地为氢; 羟基; C1-C5烷基; 羟基C1C5alkyl; C1C5alkoxy; NO 2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; 或CH 3 -CO-NH-; An1，An2和An3彼此独立地是阴离子; a和b彼此独立地是1至3的数字; m是从0到5000的数字; n是从0到5000的数字; p是1至5000的数字; 其中m + n + p = 3的总和。染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质，例如耐光性，洗发和摩擦。

    XANTHENE DYES
    2.
    发明申请
    XANTHENE DYES 审中-公开

    公开(公告)号：WO2007039502A3

    公开(公告)日：2007-05-24

    申请号：PCT/EP2006066673

    申请日：2006-09-25

    Applicant: CIBA SC HOLDING AG ,  ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    Inventor： ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    IPC: C09B11/24 ,  A61K8/00 ,  A61Q5/10 ,  C09B49/12

    CPC classification number: C09B49/126 ,  A61K8/49 ,  A61K8/498 ,  A61Q5/10 ,  C09B11/24 ,  C09B11/245

    Abstract: Disclosed are compounds of formula (1a), wherein R 1 is N + R 8 R 9 ; R 8 and/or R 9 independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 -alkyl; or R 8 and/or R 9 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 1 or C 2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R 2 is NR 10 R 11 ; or OR 10 ; R 10 and R 11 , independently from each other are hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C 4 alkyl; or R 10 and/or R 11 are a bivalent C 3 -C 6 alkylene radical which is linked to the carbon atoms C 3 or C 4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16- membered carbocyclic ring; or R 10 and R 11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R 3 , R 4 , R 5 , R 6 and R 7 independently form each other are hydrogen; C 1 -C 12 alkyl; halogen; NR 12 R 13 ; or a radical of formula (1a 1 ); R 12 and R 13 independently from each other are hydrogen; C 1 -C 12 alkyl; phenyl-C 1 -C 4 alkyl; or a radical of formula (1a 2 ); V is -O-; Or -NR 15 ; R 14 , R 15 R- 16 and R 17 independently from each other are hydrogen; or C 1 -C 5 alkyl; and Hal is a halogen atom; and wherein at least one of R 3 , R 4 , R 5 , R 6 and R 7 is hydrogen. The compounds are useful for dyeing of keratin-containing fibres with or without reducing agents.

    Abstract translation: 公开了式（1a）的化合物，其中R 1是N + R 8 R 9; R 8和/或R 9彼此独立地是氢; ç 1 -C 12 烷基; 或苯基-C 1 -C 4 - 烷基; 或R 8和/或R 9是二价C 3 -C 6亚烷基，其与 分别为碳原子C 1或C 2，并与连接氮原子一起形成6至16元碳环; R 2是NR 10 R 11; 或OR 10; R 10和R 11彼此独立地是氢; ç 1 -C 12 烷基; 或苯基-C 1 -C 4烷基; 或R 10和/或R 11是二价C 3 -C 6亚烷基，其与 碳原子C 3或C 4分别与连接氮原子或氧原子一起形成6至16元碳环; 或R 10和R 11与连接氮原子一起形成4至8元碳环; R 3，R 4，R 5，R 6和R 7独立地是 形成彼此是氢; ç 1 -C 12 烷基; 卤素; NR 12 - [R 13 ; 或式（1a 1）的基团; R 12和R 13彼此独立地是氢; ç 1 -C 12 烷基; 苯基-C 1 -C 4 烷基; 或式（1a 2>）的基团; V是-O-; 或-NR 15。 R 14，R 15，R 16，R 17和R 17彼此独立地是氢; 或C 1 -C 5烷基; Hal是卤素原子; 并且其中R 3，R 4，R 5，R 6和R 3中的至少一个， 7是氢。 该化合物可用于用或不含还原剂染色含角蛋白的纤维。

    DISULFIDE DYES, COMPOSITION COMPRISING THEM AND METHOD OF DYEING HAIR
    3.
    发明申请
    DISULFIDE DYES, COMPOSITION COMPRISING THEM AND METHOD OF DYEING HAIR 审中-公开
    DISHFIDE DYES，包含它们的组合物和染发剂的方法

    公开(公告)号：WO2005097051A3

    公开(公告)日：2005-12-15

    申请号：PCT/EP2005051412

    申请日：2005-03-29

    Applicant: CIBA SC HOLDING AG ,  ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    Inventor： ELIU VICTOR PAUL ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    IPC: A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C09B44/16 ,  C09B44/20 ,  C09B49/00 ,  A61K7/13 ,  C07D403/12 ,  C09B62/78

    CPC classification number: C09B44/16 ,  A61K8/49 ,  A61K8/4926 ,  A61K8/4946 ,  A61K2800/94 ,  A61Q5/10 ,  C09B44/20 ,  C09B49/00

    Abstract: Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye; Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted -C1-C10alkylene-; -C5-C10cycloalkylene-; C5-C10arylene; or-C5-C10arylene-(C1-C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is -S-; with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1). Further, the present invention relates to novel disulfid compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.

    Abstract translation: 式（I）其中R1和R2各自独立地为有机染料的残基; Y1和Y2各自独立地为未取代或取代的直链或支链，间断或不间断的-C 1 -C 10亚烷基 - ; -C 5 -C C10cycloalkylene-; C5-C10arylene; 或-C5-C10arylene-（C1-C10alkylene） - ; Z 1和Z 2彼此独立地是式（II）各自独立地为氢; 或未取代或取代的直链或支链的单环或多环，间断或不间断的C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C6-C10芳基，C1-C10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; r，q和n彼此独立地为0或1，如果n为0，则Z 3为氢; 如果n为1，则Z 3为-S-; 条件是该方法不包括用蛋白质二硫代异构酶类型的EC（EC 5.3.4.1）处理纤维。 此外，本发明涉及新的二硫化物，其组合物，特别是其它染料，以及其制备方法。

    HAIR DYEING COMPOSITION
    5.
    发明申请
    HAIR DYEING COMPOSITION 审中-公开
    头发染色组合物

    公开(公告)号：WO2010097338A3

    公开(公告)日：2010-11-11

    申请号：PCT/EP2010052097

    申请日：2010-02-19

    Applicant: BASF SE ,  FROEHLING BEATE

    Inventor： FROEHLING BEATE

    IPC: A61K8/49 ,  A61K8/41 ,  A61Q5/10

    CPC classification number: A61K8/49 ,  A61K8/416 ,  A61K8/4926 ,  A61K8/494 ,  A61K8/4946 ,  A61K2800/4322 ,  A61K2800/4324 ,  A61Q5/065 ,  A61Q5/10

    Abstract: Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is -CH= -O-; -S-; or -N(R7)-; R1, R2, R3 end R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH-, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; or phenyl; R8 is hydrogen; C1-C4alkyl; Cl; or nitro; R10 is hydrogen; C1-C4alkyl; Cl; nitro; amino; or C1-C4mono- or C1-C4dialkylamino; R11 is hydrogen; C1-C4alkyl; or CN; R12 is unsubstituted or OH- or CN-substituted C1-C4alkyl; R13 is hydrogen; or C1-C4alkyl; R14 and R15 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or R14 and R15 together with the nitrogen and carbon atoms joining them together form a 5- or 6- membered ring; R16 and R20 independently from each other are hydrogen; C1-C4alkyl; hydroxy; Cl; nitro; amino, C1-C4mono- or dialkylamino; R17, R18, R19, R21, R22 and R23 independently from each other are hydrogen; or C1-C4alkyl; R24 is hydrogen; or C1-C4alkyl; and An- is a colorless anion.

    Abstract translation: 染发组合物，其包含（a）式（1）（b）的染料至少一种选自式（2）（3）（4）的化合物的染料，其中D是式（2a）的重氮组分的基团 ）（2b）（2c）（2d）K是选自苯胺衍生物的偶联成分的基团; 苯酚衍生物; 萘衍生物 X是-CH = -O-; -S-; 或-N（R 7） - ; R1，R2，R3端R4彼此独立地为氢; 或C 1 -C 4烷基; R5和R6彼此独立地是氢; C1-C4烷基; 或C 1 -C 4烷氧基; R 7和R 9彼此独立地是未取代的或OH-，C 1 -C 4烷氧基 - ，卤素 - ，氨基 - ，C 1 -C 4 - 单或二烷基氨基取代的C 1 -C 4烷基; 或苯基; R8是氢; C1-C4烷基; 氯; 或硝基; R10是氢; C1-C4烷基; 氯; 硝基; 氨基; 或C 1 -C 4单 - 或C 1 -C 4二烷基氨基; R11为氢; C1-C4烷基; 或CN; R 12是未取代的或OH-或CN-取代的C 1 -C 4烷基; R13是氢; 或C 1 -C 4烷基; R 14和R 15彼此独立地是氢; C1-C4烷基; 或C 1 -C 4烷氧基; 或R 14和R 15与连接在一起的氮原子和碳原子一起形成5-或6-元环; R 16和R 20彼此独立地是氢; C1-C4烷基; 羟基; 氯; 硝基; 氨基，C1-C4单 - 或二烷基氨基; R 17，R 18，R 19，R 21，R 22和R 23彼此独立地为氢; 或C 1 -C 4烷基; R24是氢; 或C 1 -C 4烷基; 而An-是无色阴离子。

    THIOL DERIVATIVE DYES
    8.
    发明申请
    THIOL DERIVATIVE DYES 审中-公开
    THIOL衍生染发剂

    公开(公告)号：WO2008019977A2

    公开(公告)日：2008-02-21

    申请号：PCT/EP2007058224

    申请日：2007-08-08

    Applicant: CIBA SC HOLDING AG ,  ELIU VICTOR ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    Inventor： ELIU VICTOR ,  FROEHLING BEATE ,  KAUFFMANN DOMINIQUE

    IPC: C09B49/00 ,  A61Q5/06 ,  A61Q5/10 ,  C09B44/16 ,  C09B55/00 ,  C09B56/18

    CPC classification number: C09B44/16 ,  A61K8/4946 ,  A61Q5/065 ,  A61Q5/10 ,  C09B49/00 ,  C09B55/003 ,  C09B56/18

    Abstract: Disclosed are thiol dyes of formula (1 ) wherein L1 is hydrogen; C 1 -C 12 alkyl; or phenyl-C 1 -C4alkyl; X is C 1 -C 12 alkylene, C 2 -C 12 alkenylene, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene, or C 5 -C 10 arylene-C 1 -C 10 alkylene, which may by interrupted by -O-, -NH-, -S-, -CO-, o -SO 2 -; Y is the residue of an organic dye Z is a group of formula (1b) or -C?N; wherein A is O; S; or N-L 2 ; B is L 3 ; -OL 3 ; -NL 3 L 4; or -SL 3 ; and L 2 , L 3 and L 4 , indepently from other are are hydrogen; C 1 -C 12 alkyl; C 5 -C 12 aryl-C 1 -C 12 alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.

    Abstract translation: 公开了式（1）的硫醇染料，其中L 1是氢; ç 1 -C 12 烷基; 或苯基-C 1 -C 4烷基; X是C 1 -C 12亚烷基，C 2 -C 12亚烯基，C 5 - C 1 -C 10亚环烷基，C 5 -C 10亚芳基或C 5 -C 3亚芳基 其可以被-O - ， - NH - ， - S - ， - CO-中间体取代，亚芳基-C 1 -C 10亚烷基， o -SO 2 - ; Y是有机染料的残基Z是式（1b）或-C≡N的基团; 其中A为O; S; 或N-L 2个; B是L 3 3; -OL 3 ; -NL 3 <3L 4;或-SL 3; 和L 2，L 3和L 4独立地是氢; ç 1 -C 12 烷基; ç 5 -C 12 芳基-C 1 -C 12 烷基。 该化合物可用于染色有机材料，例如角蛋白纤维，优选人发。

    POLYMERIC HAIR DYES
    9.
    发明申请
    POLYMERIC HAIR DYES 审中-公开
    聚合物染发剂

    公开(公告)号：WO2011006946A3

    公开(公告)日：2011-03-31

    申请号：PCT/EP2010060175

    申请日：2010-07-15

    Applicant: BASF SE ,  CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    Inventor： CREMER CHRISTIAN ,  BECHERER OLIVER ,  FROEHLING BEATE

    IPC: C09B26/04 ,  A61Q5/00 ,  C09B69/10

    CPC classification number: C09B26/04 ,  A61K8/84 ,  A61K2800/4324 ,  A61Q5/10 ,  C09B69/109

    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R5)-, -S(O)-, -SO2-, -(CH2CH2-O)1-5-, -(CH2CH2CH2-O)1-5-, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R1)-, -C(NR1R2)2-, -(R1)NC(O)-, -C(S)R1-; which may be interrupted and/or terminated at one or both ends by one or more than one -C1C30alkylene- or -C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1- C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1- C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl- C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z1, Z2 and Z3, independently from each other are -CR8- or -NR9+-; and at least one of Z1, Z2 or Z3 is -NR9+-; wherein at least one of Y1 and Y2 is a residue of an organic dye; R, R3, R4, R5, R6, R7, R8 and R9 independently from each other are hydrogen; hydroxy; C1- C5alkyl; hydroxy-C1C5alkyl; C1C5alkoxy; -NO2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; or CH3-CO-NH-; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p = 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

    Abstract translation: 公开了式（1a），（1b）或（1c）的聚合染料; 其中A和B彼此独立地表示聚合物主链; X1和X2彼此独立地是选自-S - ， - S - ， - N - ， - N = - ， - N（R5） - ， - S（O） - ， - SO2-， - （ CH 2 CH 2 -O）1-5 - ， - （CH 2 CH 2 CH 2 -O）1-5 - ， - C（O） - ， - C（O）O - ， - OCO-，（式II）-CON -C（NR 1 R 2）2 - ， - （R 1）NC（O） - ， - C（S） 其可以在一个或两个末端被一个或多于一个-C 1 -C 30亚烷基 - 或-C 2 -C 12亚烯基 - 或任选包含至少一个杂原子的任选取代的，饱和或不饱和的稠合或非稠合芳族或非芳族（杂环）二价基团; 饱和或不饱和的，稠合或非稠合的芳族或非芳族二价基团，其包含至少一个杂原子，其任选被C 1 -C 30烷基，C 1 -C 30烷氧基，C 2 -C 12烯基，C 5 -C 10芳基，C 5 -C 10环烷基，C 1 -C 10烷基 C5-C10亚芳基），羟基或卤素; R1和R2彼此独立地是氢; 未取代或取代的直链或支链，单环或多环，中断或不间断C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C 6 -C 10芳基-C 1 -C 10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是选自式（1d）的腙染料的有机染料的残基，其中Z 1，Z 2和Z 3彼此独立地是-CR 8 - 或-NR 9 + - ; 并且Z 1，Z 2或Z 3中的至少一个为-NR 9 +。 其中Y 1和Y 2中的至少一个是有机染料的残基; R，R 3，R 4，R 5，R 6，R 7，R 8和R 9彼此独立地为氢; 羟基; C 1-5烷基; 羟基C1C5alkyl; C1C5alkoxy; NO 2; -Cl; -Br; -COOH; -SO3H; -CN; NH2; 或CH 3 -CO-NH-; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到5000的数字; n是从0到5000的数字; p是从1到5000的数字; 其中m + n + p = 3的总和。这些染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质，例如，耐光牢度，洗发剂和摩擦性。

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