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公开(公告)号：WO2016092312A1
公开(公告)日：2016-06-16
申请号：PCT/GB2015/053784
申请日：2015-12-10
IPC分类号： C09D11/102 , C09D11/106 , C09D11/322 , C09D11/38
CPC分类号： C09D11/102 , C08L9/08 , C08L71/02 , C08L75/04 , C09D11/106 , C09D11/322 , C09D11/38 , Y02P20/582
摘要： An ink comprising: (a)from 1to25 parts of titanium dioxide pigment; (b)from 0to 8parts of a styrene butadiene latex binder; (c)from 0 to 8 parts of a polyurethane latex binder; (d)from 0 to 5 parts of a glycol selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol,dipropylene glycolor triethylene glycol; (e)from 1 to 10 parts of 2-pyrrolidone; (f)from 1 to 10 parts of glycerol; (g)from 0.01to 2parts ofan acetylenic surfactant; (h)from 0.001 to 5 parts of biocide; (i)from 0 to 10 parts of a viscosity modifier; and (j)the balance to 100 parts water; provided that (b) plus (c) is greater than 0. Also ink jet printing processes, ink-jet ink containers, printed substrates and ink-jet printers.
摘要翻译： 一种油墨，其包含：（a）1至25份二氧化钛颜料; （b）0至8份苯乙烯丁二烯胶乳粘合剂; （c）0至8份聚氨酯胶乳粘合剂; （d）0至5份选自乙二醇，二甘醇，丙二醇，二丙二醇或三甘醇的二醇; （e）1〜10份2-吡咯烷酮; （f）1至10份甘油; （g）0.01至2份炔属表面活性剂; （h）0.001〜5份杀生物剂; （i）0〜10份粘度调节剂; 和（j）余量为100份水; （b）加（c）大于0.此外，喷墨印刷工艺，喷墨墨水容器，印刷基板和喷墨打印机。
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公开(公告)号：WO2016092310A1
公开(公告)日：2016-06-16
申请号：PCT/GB2015/053782
申请日：2015-12-10
发明人： ORIAKHI, Christopher , SHANKAR, Ravi , WILSON, Eda , FINNEGAN, Michael , BAKER, Jerrold , DELANEY, Keith , FIUMENERO, Anthony , DOUBLE, Philip , SHIRAZI, Hamid
IPC分类号： C09D11/106 , C09D11/322 , C09D11/38
CPC分类号： C09D11/322 , C09D11/106 , C09D11/38
摘要： An ink comprising: (a) from 0.5 to 5 parts of a self-dispersible pigment; (b) from 1 to 10 parts of a styrene acrylic latex binder and/or styrene butadiene latex; (c) from 0 to 5 parts of a glycol selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol,dipropylene glycolor triethylene glycol; (d) from 1 to 10 parts of 2-pyrrolidone; (e) from 1 to 15 parts of glycerol; (f) from 0.1to 3 parts of an acetylenic surfactant; (g) from 0.001 to 5 parts of biocide; (h) from 0 to 10 parts of a viscosity modifier; and (i) the balance to 100 parts water. Also an ink-jet printing process, a printed substrate, an ink-jet printer ink container and an ink-jet printer with a re-circulating printer head.
摘要翻译： 一种油墨，其包含：（a）0.5至5份的自分散颜料; （b）1至10份苯乙烯丙烯酸胶乳粘合剂和/或苯乙烯丁二烯胶乳; （c）0-5份选自乙二醇，二甘醇，丙二醇，二丙二醇或三甘醇的二醇; （d）1〜10份2-吡咯烷酮; （e）1至15份甘油; （f）0.1〜3份炔属表面活性剂; （g）0.001〜5份杀生物剂; （h）0〜10份粘度调节剂; 和（i）余量为100份水。 还有一种喷墨印刷工艺，印刷基板，喷墨打印机墨水容器和具有再循环打印头的喷墨打印机。
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公开(公告)号：WO2016005727A1
公开(公告)日：2016-01-14
申请号：PCT/GB2015/051844
申请日：2015-06-25
IPC分类号： C09D11/00 , C09D11/30 , C09D11/322 , C09D11/324 , C09D11/326 , C09D11/40
CPC分类号： C09D11/326 , B41J2/01 , C09D5/14 , C09D11/03 , C09D11/322 , C09D11/324 , C09D11/38 , C09D11/40
摘要： A process for printing on a water-soluble material using a self-dispersible pigment which comprises a carboxy-functional dispersant crosslinked around a pigment core by a crosslinking agent having at least two groups selected from oxetane, carbodiimide, hydrazide, oxazoline, aziridine, isocyanate, N-methylol, keteneimine, isocyanurate and epoxy groups. Also inks, ink-sets, printed material and ink-jet printers.
摘要翻译： 一种使用自分散颜料在水溶性材料上印刷的方法，该方法包括通过具有至少两个选自氧杂环丁烷，碳二亚胺，酰肼，恶唑啉，氮丙啶，异氰酸酯基团的交联剂在颜料芯周围交联的羧基官能分散剂 ，N-羟甲基，烯酮亚胺，异氰脲酸酯和环氧基。 还有墨水，墨水，印刷品和喷墨打印机。
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公开(公告)号：WO2014174241A1
公开(公告)日：2014-10-30
申请号：PCT/GB2014/050946
申请日：2014-03-25
发明人： ORIAKHI, Christopher
IPC分类号： C09D11/00
CPC分类号： C09D11/322 , B32B3/00 , C08K5/23 , C08K5/3437 , C09D11/38
摘要： An ink comprising: (a) from 1to 25 parts of surface treated titanium dioxide; (b) from 8 to 25 parts of a first solvent selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol and dipropylene glycol; (c) from 2 to 12 parts of a second solvent selected from the group consisting of 2-pyrrolidone, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-cyclohexyl- 2-pyrrolidone and N,N-dimethylacetamide; (d) from 15 to 45 parts of glycerol; (e) from 0.1to 2 parts of an acetylenic surfactant; (f) from 0.001 to 2 parts of 1,2-benzisothiazolin-3-one; (g) from 0 to 20 parts of polymer particles; and (h) the balance to 100 parts water.
摘要翻译： 一种油墨，其包含：（a）1至25份表面处理的二氧化钛; （b）8至25份选自乙二醇，二甘醇，三甘醇和二丙二醇的第一溶剂; （c）2至12份选自2-吡咯烷酮，N-甲基-2-吡咯烷酮，N-乙基-2-吡咯烷酮，N-环己基-2-吡咯烷酮和N，N-二甲基甲酰胺的第二溶剂。 二甲基乙酰胺; （d）15至45份甘油; （e）0.1〜2份炔属表面活性剂; （f）0.001至2份1,2-苯并异噻唑啉-3-酮; （g）0〜20份聚合物颗粒; 和（h）余量为100份水。
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公开(公告)号：WO2014147373A2
公开(公告)日：2014-09-25
申请号：PCT/GB2014/050750
申请日：2014-03-13
IPC分类号： C09D11/00
CPC分类号： C09D11/30 , B41J2/01 , C09D11/10 , C09D11/102 , C09D11/107 , C09D11/108 , C09D11/322
摘要： An ink-jet printing process where the ink is printed onto a substrate using an ink-jet printer with an ink re-circulating print-head and where the ink comprises: (a) 0.1 to 10 parts of a self-dispersible pigment; (b) 1 to 20 parts of a latex binder; (c) 5 to 15 parts of one or more polar organic solvent(s) with a solubility parameter at 25°C greater than 27.5; (d) 0.1 to 3 parts of a surfactant; (e) 0.001 to 5 parts of biocide; (f) 0 to 10 parts of a viscosity modifier; (g) 0 to 5 parts of one or more organic solvents with a solubility parameter at 25°C less than 27.5; (h) 0 to 5 parts of a cross linking agent; (i) the balance to 100 parts water: and where the face plate of the ink re-circulating print-head shows a contact angle with water of less than 90°. Also printed substrates, inks, ink-jet ink containers and ink- jet printers.
摘要翻译： 一种喷墨印刷方法，其中使用具有油墨再循环打印头的喷墨打印机将油墨印刷到基材上，并且其中油墨包括：（a）0.1至10份自分散颜料; （b）1〜20份胶乳粘合剂; （c）5至15份一种或多种极性有机溶剂，其溶度参数在25℃大于27.5; （d）0.1〜3份表面活性剂; （e）0.001〜5份杀生物剂; （f）0〜10份粘度调节剂; （g）0至5份一种或多种在25℃下溶解度参数小于27.5的有机溶剂; （h）0〜5份交联剂; （i）余量为100份水，墨水再循环打印头的面板与水的接触角小于90°。 印刷基板，墨水，喷墨墨水容器和喷墨打印机。
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公开(公告)号：WO2018073560A1
公开(公告)日：2018-04-26
申请号：PCT/GB2017/052858
申请日：2017-09-25
发明人： WILSON, Eda , DIMOTAKIS, Emmanuel
IPC分类号： C09D11/102 , C09D11/106 , C09D11/322 , C09D11/38 , C09D11/40
摘要： An aqueous ink comprising: from 0.1 to 8 parts by weight of a self-dispersible pigment which comprises a carboxy-functional dispersant crosslinked around a pigment core by a crosslinking agent having at least two groups selected from oxetane, carbodiimide, hydrazide, oxazoline, aziridine, isocyanate, N-methylol, keteneimine, isocyanurate and epoxy groups; from 10 to 25 parts by weight of a first solvent selected from one or more of the group consisting of ethylene glycol, propylene glycol, dipropylene glycol and triethylene glycol; from 2 to 10 parts by weight of a second solvent selected from one or more of the group consisting of 2-pyrrolidone, N-methyl-2-pyrrolidone, N-ethyl-2- pyrrolidone, N-cyclohexyl-2-pyrrolidone and N,N-dimethylacetamide; from 20 to 45 parts by weight of glycerol; from 4 to 12 parts by weight of a styrene butadiene latex binder and/or a polyurethane latex binder; from 0.1 to 2 parts by weight of an acetylenic surfactant; from 0 to 2 parts by weight of 1,2-benzisothiazolin-3-one; and the balance to 100 parts by weight water. Also ink-jet printing processes, printed materials, ink containers and ink-sets.
摘要翻译： 一种水性油墨，其包含：0.1-8重量份的自分散颜料，其包含通过具有至少两个选自氧杂环丁烷的基团的交联剂在颜料核心周围交联的羧基官能分散剂 ，碳化二亚胺，酰肼，恶唑啉，氮丙啶，异氰酸酯，N-羟甲基，烯酮亚胺，异氰脲酸酯和环氧基; 10至25重量份的选自乙二醇，丙二醇，二丙二醇和三甘醇中的一种或多种的第一溶剂; 2-10重量份的第二溶剂，所述第二溶剂选自2-吡咯烷酮，N-甲基-2-吡咯烷酮，N-乙基-2-吡咯烷酮，N-环己基-2-吡咯烷酮和N ，N-二甲基乙酰胺; 20至45重量份的甘油; 4至12重量份的苯乙烯丁二烯胶乳粘合剂和/或聚氨酯胶乳粘合剂; 0.1至2重量份的炔属表面活性剂; 0-2重量份的1,2-苯并异噻唑啉-3-酮; 余量达到100重量份水。 还有喷墨印刷工艺，印刷材料，油墨容器和油墨套装。
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公开(公告)号：WO2014135843A1
公开(公告)日：2014-09-12
申请号：PCT/GB2014/050429
申请日：2014-02-14
发明人： ORIAKHI, Christopher
CPC分类号： C09D11/38 , C08K5/01 , C08K9/02 , C09D7/61 , C09D11/322
摘要： An ink comprising: (a) from 1 to 20 parts of surface treated titanium dioxide; (b) from 20 to 70 parts of viscosity modifier; (c) from 5 to 30 parts of one or more water miscible polar organic solvent(s); (d) from 0.1 to 3 parts of surfactant; (e) from 0.001 to 5 parts of biocide; (f) from 0 to 20 parts of polymer particles; (g) the balance to 100 parts water; wherein the ink has a viscosity in the range of from 10 to 25 mPa.s when measured at 32°C using a Brookfield spindle SOO at 3 or 12 rpm depending on whether the viscosity is 16 mPa.s. Also ink jet printing processes, printed substrates, ink containers and ink-jet printers.
摘要翻译： 一种油墨，其包含：（a）1至20份表面处理的二氧化钛; （b）20〜70份粘度调节剂; （c）5至30份一种或多种水混溶极性有机溶剂; （d）0.1〜3份表面活性剂; （e）0.001〜5份杀生物剂; （f）0〜20份聚合物颗粒; （g）余量为100份水; 其中当在32℃下使用Brookfield主轴SOO以3或12rpm测量时，所述油墨具有在10至25mPa.s范围内的粘度，这取决于粘度为或大于或等于16mPa.s。 还有喷墨印刷工艺，印刷基板，油墨容器和喷墨打印机。
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公开(公告)号：WO2014027179A1
公开(公告)日：2014-02-20
申请号：PCT/GB2013/052086
申请日：2013-08-05
发明人： DOUBLE, Philip , CORDWELL, Janette , HOLMES, Marie , POPAT, Ajay
IPC分类号： C09D11/00
CPC分类号： C09D11/40 , C09D11/328 , C09D11/36 , C09D11/38 , Y10T428/24802
摘要： An ink composition comprising: a) 0.2 to 20 parts of one or more glycols selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol or dipropylene glycol; b) 30 to 50 parts of glycerol; c) 0.5 to 10 parts of 2-pyrrolidone; d) 0.5 to 9 parts of colorant; e) 30 to 70 parts of water; f) 0 to 3 parts of surfactant; g) 0 to 5 parts biocide; wherein all parts are by weight. Also ink-sets, printing processes and printed material.
摘要翻译： 一种油墨组合物，其包含：a）0.2至20份选自乙二醇，二甘醇，丙二醇或二丙二醇的一种或多种二醇; b）30至50份甘油; c）0.5〜10份2-吡咯烷酮; d）0.5至9份着色剂; e）30〜70份水; f）0〜3份表面活性剂; g）0至5份杀生物剂; 其中所有部分均为重量。 还有墨水，印刷工艺和印刷材料。
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公开(公告)号：WO2017068315A9
公开(公告)日：2017-07-27
申请号：PCT/GB2016000186
申请日：2016-10-14
发明人： DIMOTAKIS EMMANUEL , DELANEY KEITH , ORIAKHI CHRISTOPHER , DOUBLE PHILIP , SHANKAR RAVI , SHIRAZI HAMID , WILSON EDA
IPC分类号： D06P5/30 , B41M7/00 , C09D11/106 , C09D11/322 , C09D11/40
CPC分类号： D06P5/30 , B41M7/009 , C09B67/0013 , C09B67/009 , C09D11/106 , C09D11/322 , C09D11/38 , C09D11/40 , C09D11/54 , D06P1/44 , D06P1/5221 , D06P1/5257 , D06P1/5285
摘要： A process for printing on a textile substrate comprising the steps of: (I) preparing an ink comprising the following components: (a) from 1 to 8 parts of a self-dispersible pigment which comprises a carboxy-functional dispersant crosslinked around a pigment core by a crosslinking agent having at least two groups selected from oxetane, carbodiimide, hydrazide, oxazoline, aziridine, isocyanate, N-methylol, keteneimine, isocyanurate and epoxy groups; (b) from 0 to 16 parts of a binder selected from one or more of an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder wherein the binder has a Tg in the range of from -25°C to 35°C; (c) from 1 to 30 parts of one or more water-miscible organic solvents (d) from 0.1 to 3 parts of a surfactant; (e) from 0 to 5 parts of biocide; (f) from 0 to 10 parts of a viscosity modifier; (g) from 0 to 10 parts of a polyurethane latex binder with a Tg in the range of from -25°C to 35°C; (h) from 0 to 6 parts of a cross linking agent; and (i) the balance to 100 parts water: (II) optionally preparing a latex binders solution comprising; i) from 1 to 16 parts of one or more latex binders selected from an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder where the latex binder(s) have a Tg in the range of from -25°C to 35°C; ii) from 0 to 6 parts of a polyurethane latex binder; and iii) from 0 to 5 parts of a cross linking agent: (III) printing the ink prepared in step (I) on to a textile substrate using a ink jet printer with a single pass print head and optionally pre-printing or overprinting with the latex binder solution from step (II) (IV) curing the printed textile substrate from step (III): provided that if component (b) in the ink prepared in step (a) is 0 then optional step (II) is compulsory. Also inks, ink-sets, ink containers and ink-jet printers.
摘要翻译： 一种在纺织品基材上印刷的方法，其包括以下步骤：（I）制备包含以下组分的油墨：（a）1至8份的自分散颜料，其包含围绕颜料芯交联的羧基官能分散剂 通过具有至少两个选自氧杂环丁烷，碳化二亚胺，酰肼，恶唑啉，氮丙啶，异氰酸酯，N-羟甲基，烯酮亚胺，异氰脲酸酯和环氧基的基团的交联剂; （b）0-16份选自一种或多种丙烯酸胶乳粘合剂，苯乙烯丙烯酸胶乳粘合剂和苯乙烯丁二烯胶乳粘合剂的粘合剂，其中粘合剂的Tg范围为-25℃至35℃ C; （c）1至30份的一种或多种水混溶性有机溶剂（d）0.1至3份的表面活性剂; （e）0-5份杀生物剂; （f）0至10份粘度调节剂; （g）0-10份Tg为-25℃至35℃的聚氨酯胶乳粘合剂; （h）0至6份交联剂; 和（i）余量为100份水：（II）任选地制备胶乳粘合剂溶液，其包含： i）1-16份选自丙烯酸胶乳粘合剂，苯乙烯丙烯酸胶乳粘合剂和苯乙烯丁二烯胶乳粘合剂的一种或多种胶乳粘合剂，其中胶乳粘合剂的Tg为-25℃ 到35°C; ii）0至6份聚氨酯胶乳粘合剂; 和iii）0至5份交联剂：（III）使用具有单程打印头的喷墨打印机将步骤（I）中制备的油墨印刷到纺织品基材上，并且任选地预印刷或套印 步骤（II）（IV）的胶乳粘合剂溶液固化来自步骤（III）的印刷的纺织品基材：条件是如果步骤（a）中制备的油墨中的组分（b）为0，则任选步骤（II）是强制性的。 还有墨水，墨水，墨水容器和喷墨打印机。
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公开(公告)号：WO2017068315A1
公开(公告)日：2017-04-27
申请号：PCT/GB2016/000186
申请日：2016-10-14
发明人： DIMOTAKIS, Emmanuel , DELANEY, Keith , ORIAKHI, Christopher , DOUBLE, Philip , SHANKAR, Ravi , SHIRAZI, Hamid , WILSON, Eda
IPC分类号： D06P5/30 , C09D11/106 , C09D11/322 , C09D11/40 , B41M7/00
CPC分类号： D06P5/30 , B41M7/009 , C09B67/0013 , C09B67/009 , C09D11/106 , C09D11/322 , C09D11/38 , C09D11/40 , C09D11/54 , D06P1/44 , D06P1/5221 , D06P1/5257 , D06P1/5285
摘要： A process for printing on a textile substrate comprising the steps of: (I) preparing an ink comprising the following components: (a) from 1 to 8 parts of a self-dispersible pigment which comprises a carboxy-functional dispersant crosslinked around a pigment core by a crosslinking agent having at least two groups selected from oxetane, carbodiimide, hydrazide, oxazoline, aziridine, isocyanate, N-methylol, keteneimine, isocyanurate and epoxy groups; (b) from 0 to 16 parts of a binder selected from one or more of an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder wherein the binder has a Tg in the range of from -25°C to 35°C; (c) from 1 to 30 parts of one or more water-miscible organic solvents (d) from 0.1 to 3 parts of a surfactant; (e) from 0 to 5 parts of biocide; (f) from 0 to 10 parts of a viscosity modifier; (g) from 0 to 10 parts of a polyurethane latex binder with a Tg in the range of from -25°C to 35°C; (h) from 0 to 6 parts of a cross linking agent; and (i) the balance to 100 parts water: (II) optionally preparing a latex binders solution comprising; i) from 1 to 16 parts of one or more latex binders selected from an acrylic latex binder, a styrene acrylic latex binder and a styrene butadiene latex binder where the latex binder(s) have a Tg in the range of from -25°C to 35°C; ii) from 0 to 6 parts of a polyurethane latex binder; and iii) from 0 to 5 parts of a cross linking agent: (III) printing the ink prepared in step (I) on to a textile substrate using a ink jet printer with a single pass print head and optionally pre-printing or overprinting with the latex binder solution from step (II) (IV) curing the printed textile substrate from step (III): provided that if component (b) in the ink prepared in step (a) is 0 then optional step (II) is compulsory. Also inks, ink-sets, ink containers and ink-jet printers.
摘要翻译： 包括以下步骤：（I）制备包含以下组分的油墨：（a）1至8份包含羧基的自分散颜料， 通过具有至少两个选自氧杂环丁烷，碳化二亚胺，酰肼，恶唑啉，氮丙啶，异氰酸酯，N-羟甲基，烯酮亚胺，异氰脲酸酯和环氧基的基团的交联剂在颜料核心周围交联的官能分散剂; （b）0-16份选自一种或多种丙烯酸胶乳粘合剂，苯乙烯丙烯酸胶乳粘合剂和苯乙烯丁二烯胶乳粘合剂的粘合剂，其中粘合剂的Tg为-25℃至35℃ ;C; （c）1至30份的一种或多种水混溶性有机溶剂（d）0.1至3份的表面活性剂; （e）0-5份杀生物剂; （f）0至10份粘度调节剂; （g）0-10份Tg为-25℃至35℃的聚氨酯胶乳粘合剂; （h）0至6份交联剂; 和（i）余量为100份水：（II）任选地制备胶乳粘合剂溶液，其包含： i）1至16份的一种或多种选自丙烯酸胶乳粘合剂，苯乙烯丙烯酸胶乳粘合剂和苯乙烯丁二烯胶乳粘合剂的胶乳粘合剂，其中胶乳粘合剂的Tg为-25℃至+ 至35℃; ii）0至6份聚氨酯胶乳粘合剂; 和iii）0至5份交联剂：（III）使用具有单程打印头的喷墨打印机将步骤（I）中制备的油墨印刷到纺织品基材上，并且任选地预印刷或套印 步骤（II）（IV）的胶乳粘合剂溶液固化来自步骤（III）的印刷的纺织品基材：条件是如果步骤（a）中制备的油墨中的组分（b）为0，则任选步骤（II）是强制性的。 还有墨水，墨水，墨水容器和喷墨打印机。
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