CHEMICAL OXIDATIVE PREPARATION OF CONDUCTIVE POLYMERS

    公开(公告)号:WO2002036858A3

    公开(公告)日:2002-05-10

    申请号:PCT/US2001/032640

    申请日:2001-10-25

    IPC分类号: H01G9/025

    摘要: An intrinsically conductive polymer is prepared with a chemical oxidative process. The polymer is prepared by first dipping or coating a substrate with an Fe(III)-containing oxidizer solution and drying. The substrate is then dipped or coated with a monomer, such as 3,4-ethylenedioxythiophene solution and reacted to form the conductive polymer. The monomer is dissolved in a solvent in which it has a high solubility but in which the Fe(III)-containing oxidizer has low solubility. This minimizes cross-contamination of the monomer and oxidizer dipping solutions thereby making this process suitable for high volume production. Dissolving the monomer in a solvent allows control over the stoichiometric ration of monomer to oxidizer and prevents an excess of monomer thereby facilitating the removal of any unreacted monomer by water. The substrate is then dipped in an aqueous solution of para-toluenesulfonic acid to facilitate the removal of Fe(II) byproducts by enhancing their solubility in water and then the substrate may be washed with an aqueous solution of pure water. The process produces low ESR and low leakage valve metal capacitors with conductive polymer cathodes.

    PROCESS FOR SOLID ELECTROLYTIC CAPACITORS USING POLYMER SLURRIES
    5.
    发明申请
    PROCESS FOR SOLID ELECTROLYTIC CAPACITORS USING POLYMER SLURRIES 审中-公开
    用聚合物浆料制造固体电解电容器的方法

    公开(公告)号:WO2012037362A2

    公开(公告)日:2012-03-22

    申请号:PCT/US2011/051781

    申请日:2011-09-15

    IPC分类号: H01G9/042 H01G9/022 C08L37/00

    摘要: A process for forming a solid electrolytic capacitor and an electrolytic capacitor formed by the process. The process includes: providing an anode wherein the anode comprises a porous body and an anode wire extending from the porous body; applying a thin polymer layer onto the dielectric, and forming a dielectric on the porous body to form an anodized anode; applying a first slurry to the anodized anode to form a blocking layer wherein the first slurry comprises a first conducting polymer with an median particle size of at least 0.05 µm forming a layer of crosslinker on the blocking layer; and applying a layer of a second conducting polymer on the layer of crosslinker.

    摘要翻译: 用于形成固体电解质电容器的工艺和通过该工艺形成的电解电容器。 该方法包括:提供阳极,其中阳极包含多孔体和从多孔体延伸的阳极线; 在电介质上施加薄聚合物层,并在多孔体上形成电介质以形成阳极氧化阳极; 将第一浆料施加到所述阳极氧化阳极以形成阻挡层,其中所述第一浆料包含中值粒度为至少0.05微米的第一导电聚合物,在所述阻挡层上形成交联剂层; 并在交联剂层上施加第二导电聚合物层。