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    POLYFLUOROETHER BASED POLYMERS
    1.
    发明申请
    POLYFLUOROETHER BASED POLYMERS 审中-公开
    基于聚氟乙烯的聚合物

    公开(公告)号：WO2008060354A1

    公开(公告)日：2008-05-22

    申请号：PCT/US2007/020531

    申请日：2007-09-21

    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  PENG, Sheng ,  GETTY, Stephen, James ,  HOPKINS, Timothy, Edward ,  WANG, Ying

    Inventor： PENG, Sheng ,  GETTY, Stephen, James ,  HOPKINS, Timothy, Edward ,  WANG, Ying

    IPC: C08G18/28 ,  D06M15/576 ,  C08G18/12

    CPC classification number: D06M15/576 ,  C08G18/283 ,  C08G18/2885 ,  C08G18/792 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/2933 ,  Y10T428/31551 ,  Y10T428/31558 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31591 ,  Y10T442/198

    Abstract: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1 ) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula (I): R f -O(CF 2 CF 2 ) r (CH 2 CH 2 )q(R 1 ) s XH wherein R f is a linear or branched C 1 to C 7 perfluoroalkyl optionally interrupted by one to three oxygen atoms; r is 1 to 3, q is 1 to 3, s is O or 1; X is O, S, or NR 2 wherein R 2 is H, or C 1 to C 6 alkyl; and R 1 is a divalent radical selected from -S(CH 2 ) n -; Formula (II) or Formule (III) p is 1 to 50, and R 3 , R 4 and R 5 are each independently H or C 1 to C 6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.

    Abstract translation: 提供对包含含有至少一个脲键的聚合物的基材的表面效果的组合物，其通过以下步骤制备：（i）使（1）至少一种有机二硫氰酸酯，多异氰酸酯或其混合物反应，和（2）至少一种式 I）：R f -O（CF 2 CH 2）2（CH 2） 其中R 1是直链或支链的C 1 -C 12烷基，其中R 1是直链或支链的C 1 -C 12烷基， 任选地被一至三个氧原子间隔的C 1至C 7全氟烷基; r为1至3，q为1至3，s为O或1; X是O，S或NR 2，其中R 2是H或C 1至C 6烷基 ; 并且R 1是选自-S（CH 2）n - 的二价基团。 式（II）或式（III）化合物p为1至50，R 3，R 4和R 5各自独立地为H或 C 1 -C 6烷基; （ii），然后与（3）水，连接剂或其混合物反应。

    HYDROPHILIC STAIN RELEASE AGENTS
    2.
    发明申请
    HYDROPHILIC STAIN RELEASE AGENTS 审中-公开
    疏水性脱色剂

    公开(公告)号：WO2007133531A3

    公开(公告)日：2008-03-06

    申请号：PCT/US2007011084

    申请日：2007-05-08

    Applicant: DU PONT ,  WANG YING ,  HOPKINS TIMOTHY EDWARD ,  FRANCHINA JUSTINE GABRIELLE

    Inventor： WANG YING ,  HOPKINS TIMOTHY EDWARD ,  FRANCHINA JUSTINE GABRIELLE

    IPC: C08G18/28 ,  C07C275/62 ,  C08G18/12 ,  C08G18/78 ,  C11D3/37 ,  D06M15/576

    CPC classification number: C11D3/323 ,  C08G18/283 ,  C08G18/2885 ,  C08G18/7831 ,  C09D175/04 ,  C11D3/3726 ,  D06M15/576

    Abstract: A composition comprising a self-emulsifiable or self-dispersible aqueous solution or dispersion of at least one urea linkage-containing alkoxypolyoxyalkylene fluorocarbamate prepared by contacting (a) at least one polyisocyanate which contains at least three isocyanate groups per molecule, (b) at least one fluorochemical reagent of the formula F(CF 2 ) a CH 2 CH 2 OH, wherein a is 4, 6, or 8, or mixtures thereof, provided that a is a maximum of 50% of 8, and (c) at least one hydrophilic, water-solvatable reagent which contains per molecule a single functional group which has at least one reactive Zerewitinoff hydrogen atom, said hydrophilic, and thereafter with (d) water, the equivalent weight of said polyisocyanate and said reagents (b) and (c) being such that said reagents react with 55% to 95% of said isocyanate groups, and water reacts with all of the remaining isocyanate groups, said composition imparting durable hydrophilicity and stain release properties to a substrate treated therewith is disclosed.

    Abstract translation: 一种组合物，其包含至少一种含脲键的烷氧基聚氧化烯氟代氨基甲酸酯的自乳化或自分散水溶液或分散体，其通过使（a）至少一种每分子含有至少三个异氰酸酯基团的多异氰酸酯（b）至少 一种氟化学试剂，其分子式为F（CF 2）2 CH 2 CH 2 OH，其中a为4 ，6或8，或其混合物，条件是a最大为8的50％，和（c）至少一种亲水性水溶性试剂，其每分子含有单个官能团，其具有至少一个反应性Zerewitinoff 氢原子，所述亲水性，然后用（d）水，所述多异氰酸酯和所述试剂（b）和（c）的当量使所述试剂与55％至95％的所述异氰酸酯基团反应，水反应 与所有剩余的异氰酸酯基团，所述组合物赋予持久的亲水性和污渍释放 公开了对其处理的基材的性质。

    FLUOROPOLYMER COMPOSITIONS AND TREATED SUBSTRATES
    3.
    发明申请
    FLUOROPOLYMER COMPOSITIONS AND TREATED SUBSTRATES 审中-公开
    氟聚合物组合物和处理的基材

    公开(公告)号：WO2009076108A1

    公开(公告)日：2009-06-18

    申请号：PCT/US2008/085296

    申请日：2008-12-03

    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  BROWN, Gerald, Oronde ,  HERZOG, Axel, Hans-Joachim ,  HOPKINS, Timothy, Edward

    Inventor： BROWN, Gerald, Oronde ,  HERZOG, Axel, Hans-Joachim ,  HOPKINS, Timothy, Edward

    IPC: C08G18/28 ,  C08G18/38 ,  D06M15/576

    CPC classification number: C08G18/2885 ,  C08G18/3895 ,  C08G18/8087 ,  D06M11/44 ,  D06M11/45 ,  D06M11/46 ,  D06M11/485 ,  D06M11/79 ,  D06M15/576 ,  D06M23/08 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T428/2933 ,  Y10T428/2969 ,  Y10T428/31504 ,  Y10T428/31562 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31583 ,  Y10T442/2172

    Abstract: A composition comprising a polymer prepared by: reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf 1 -L-X wherein Rf 1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to 100 carbon atoms; optionally interrupted by 1 to 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 to 20 carbon atoms, said linking group optionally interrupted by 1 to 4 hetero-radicals selected from the group consisting of -O-, -NR-, -S-, -SO-, -SO 2 -, -N(R)C(O)- wherein R is H or C 1 -C 6 alkyl, and said linking group optionally substituted with CH 2 Cl; X is an isocyanate-reactive group selected from the group consisting of OH, -N(R)H, and SH wherein R is H or C 1 -C 6 alkyl; and thereafter reacting with (c) water and (d) an isocyanate-reactive non-fluorinated particulate component.

    Abstract translation: 一种包含聚合物的组合物，其通过：（a）至少一种具有异氰酸酯基团的二异氰酸酯，多异氰酸酯或其混合物，和（b）至少一种选自式（I）的氟化化合物：Rf1-LX，其中Rf1为 具有2至100个碳原子的一价，部分或完全氟化的直链或支链烷基; 任选地被1至50个氧原子中断; 其中碳原子与氧原子的比例为至少2:1，并且没有氧原子彼此键合; L是具有1至20个碳原子的键或直链或支链二价连接基团，所述连接基团任选被1-4个选自-O - ， - NR - ， - S - ， - SO - ， - SO 2 - ， - N（R）C（O） - ，其中R是H或C 1 -C 6烷基，所述连接基团任选地被CH 2 Cl取代; X是选自OH，-N（R）H和SH的异氰酸酯反应性基团，其中R是H或C 1 -C 6烷基; 然后与（c）水和（d）异氰酸酯反应性非氟化颗粒组分反应。

    HYDROPHILIC STAIN RELEASE AGENTS
    5.
    发明申请
    HYDROPHILIC STAIN RELEASE AGENTS 审中-公开
    疏水性脱色剂

    公开(公告)号：WO2007133531A2

    公开(公告)日：2007-11-22

    申请号：PCT/US2007/011084

    申请日：2007-05-08

    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY ,  WANG, Ying ,  HOPKINS, Timothy, Edward ,  FRANCHINA, Justine, Gabrielle

    Inventor： WANG, Ying ,  HOPKINS, Timothy, Edward ,  FRANCHINA, Justine, Gabrielle

    CPC classification number: C11D3/323 ,  C08G18/283 ,  C08G18/2885 ,  C08G18/7831 ,  C09D175/04 ,  C11D3/3726 ,  D06M15/576

    Abstract: A composition comprising a self-emulsifiable or self-dispersible aqueous solution or dispersion of at least one urea linkage-containing alkoxypolyoxyalkylene fluorocarbamate prepared by contacting (a) at least one polyisocyanate which contains at least three isocyanate groups per molecule, (b) at least one fluorochemical reagent of the formula F(CF 2 ) a CH 2 CH 2 OH, wherein a is 4, 6, or 8, or mixtures thereof, provided that a is a maximum of 50% of 8, and (c) at least one hydrophilic, water-solvatable reagent which contains per molecule a single functional group which has at least one reactive Zerewitinoff hydrogen atom, said hydrophilic, and thereafter with (d) water, the equivalent weight of said polyisocyanate and said reagents (b) and (c) being such that said reagents react with 55% to 95% of said isocyanate groups, and water reacts with all of the remaining isocyanate groups, said composition imparting durable hydrophilicity and stain release properties to a substrate treated therewith is disclosed.

    Abstract translation: 一种组合物，其包含至少一种含脲键的烷氧基聚氧化烯氟代氨基甲酸酯的自乳化或自分散水溶液或分散体，其通过使（a）至少一种每分子含有至少三个异氰酸酯基团的多异氰酸酯（b）至少 一种氟化学试剂，其分子式为F（CF 2）2 CH 2 CH 2 OH，其中a为4 ，6或8，或其混合物，条件是a最大为8的50％，和（c）至少一种亲水性水溶性试剂，其每分子含有单个官能团，其具有至少一个反应性Zerewitinoff 氢原子，所述亲水性，然后用（d）水，所述多异氰酸酯和所述试剂（b）和（c）的当量使所述试剂与55％至95％的所述异氰酸酯基团反应，水反应 与所有剩余的异氰酸酯基团，所述组合物赋予持久的亲水性和污渍释放 公开了对其处理的基材的性质。

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