公开(公告)号：WO2011011492A3

公开(公告)日：2011-01-27

申请号：PCT/US2010/042715

申请日：2010-07-21

Applicant: CERAMATEC, INC. ,  BHAVARAJU, Sai ,  KARANJIKAR, Mukund ,  JOSHI, Ashok ,  HUNT, Joel ,  CHITTA, Pallavi

Inventor： BHAVARAJU, Sai ,  KARANJIKAR, Mukund ,  JOSHI, Ashok ,  HUNT, Joel ,  CHITTA, Pallavi

IPC: C25B9/08 ,  C25B3/10 ,  C07C1/207

Abstract: An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.

公开(公告)号：WO2011011492A2

公开(公告)日：2011-01-27

申请号：PCT/US2010042715

申请日：2010-07-21

Applicant: CERAMATEC INC ,  BHAVARAJU SAI ,  KARANJIKAR MUKUND ,  JOSHI ASHOK ,  HUNT JOEL ,  CHITTA PALLAVI

Inventor： BHAVARAJU SAI ,  KARANJIKAR MUKUND ,  JOSHI ASHOK ,  HUNT JOEL ,  CHITTA PALLAVI

IPC: C25B9/08 ,  C07C1/207 ,  C25B3/10

CPC classification number: C25B3/10 ,  C25B9/08

Abstract: An electrolytic cell produces coupled radical products. The method involves obtaining a carboxylic acid material from biomass and converting it into an alkali metal salt. The alkali metal salt is then used in an anolyte as part of an electrolytic cell. The electrolytic cell may include an alkali ion conducting membrane (such as a NaSICON membrane). When the cell is operated, the alkali metal salt of the carboxylic acid decarboxylates and forms radicals. Such radicals are then bonded to other radicals, thereby producing a coupled radical product such as a hydrocarbon. The produced hydrocarbon may be, for example, saturated, unsaturated, branched, or unbranched, depending upon the starting material.

Abstract translation: 电解池产生偶联的自由基产物。 该方法包括从生物质获得羧酸物质并将其转化为碱金属盐。 然后将碱金属盐用作阳极电解液作为电解池的一部分。 电解池可以包括碱离子传导膜（例如NaSICON膜）。 当电池操作时，羧酸的碱金属盐脱羧并形成自由基。 然后将这些基团与其它基团键合，由此产生偶联的基团产物如烃。 取决于起始原料，生成的烃可以是例如饱和的，不饱和的，支链的或非支链的。