公开(公告)号：WO2016138165A1

公开(公告)日：2016-09-01

申请号：PCT/US2016/019402

申请日：2016-02-24

Applicant: SGC ENERGIA S.A. (FORMERLY-GI-GASIFICATION INTERNATIONAL S.A.) ,  INGA, Juan, R. ,  HEMMINGS, John ,  BONNELL, Leo

Inventor： INGA, Juan, R. ,  HEMMINGS, John ,  BONNELL, Leo

IPC: C07C1/02 ,  C07C1/04 ,  C10G2/00

CPC classification number: B01J19/245 ,  B01J8/02 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/04 ,  B01J8/065 ,  B01J8/067 ,  B01J8/22 ,  B01J19/0093 ,  B01J19/249 ,  B01J2208/00176 ,  B01J2208/065 ,  B01J2219/0004 ,  B01J2219/00781 ,  B01J2219/00792 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00867 ,  B01J2219/00873 ,  B01J2219/2462 ,  B01J2219/2479 ,  B01J2219/2481 ,  C10G2/00 ,  C10G2/341

Abstract: Methods, systems and apparatuses are disclosed for a Fischer-Tropsch ("FT") operation including a first FT stage comprising at least one FT reactor having a first FT catalyst and a first heat transfer surface area to catalyst volume configured to receive a first feed comprising synthesis gas and to convert a first portion of the synthesis gas in the first feed into first FT products. The disclosure also provides for a separation apparatus configured to separate the first FT products into first liquid FT hydrocarbons and first FT tail gas comprising unreacted syngas and for a second FT stage comprising at least one second FT reactor, having a second FT catalyst and a second heat transfer surface area to catalyst volume different from the first heat transfer surface area to catalyst volume, and configured to receive a second feed comprising the first FT tail gas and to convert at least a portion of the second feed into a second FT products.

Abstract translation: 公开了费 - 托（“FT”）操作的方法，系统和装置，包括第一FT阶段，其包括具有第一FT催化剂的至少一个FT反应器和被配置为接收第一进料的催化剂体积的第一传热表面积 包括合成气并将第一进料中的合成气的第一部分转化成第一FT产物。 本公开还提供了一种分离装置，其被配置为将第一FT产物分离成第一液体FT烃和包含未反应合成气的第一FT尾气，以及包含至少一个具有第二FT催化剂的第二FT反应器的第二FT级， 传热表面积与不同于第一传热表面积到催化剂体积的催化剂体积，并且构造成接收包含第一FT尾气的第二进料并将第二进料的至少一部分转化为第二FT产物。

公开(公告)号：WO2015027043A4

公开(公告)日：2015-02-26

申请号：PCT/US2014/052052

申请日：2014-08-21

Applicant: GI-GASIFICATION INTERNATIONAL (LUXEMBOURG), S.A. ,  HEMMINGS, John ,  INGA, Juan, R.

Inventor： HEMMINGS, John ,  INGA, Juan, R.

IPC: C07C1/04

Abstract: A process for hydrogenating a Fischer-Tropseh ("FT") wax includes placing hydrogenation catalyst particles within a low-temperature hydrogenation reactor having a mixing sub-system and a vent at the top for excess hydrogen, placing the FT wax at a low temperature up to a predetermined level within the Sow-temperature, hydrogenation reactor, leaving a vapor space above the predetermined level, adding hydrogen under a desired pressure into the low-temperature hydrogenation reactor, mixing the input FT wax, the hydrogen gas and the hydrogenating catalyst particles together to create a mixture using the mixing subsystem and continuing the mixing until the FT wax has hydrogenated, stopping the mixing to allow the hydrogenation catalyst particles to settle, and removing an hydrogenated FT wax with residual hydrogenating catalyst particles from the low-temperature hydrogenation reactor. The hydrogenated FT wax may he filtered and subjected to vacuum distillation. Other embodiments are also disclosed.

公开(公告)号：WO2014144855A2

公开(公告)日：2014-09-18

申请号：PCT/US2014/029442

申请日：2014-03-14

Applicant: INGA, Juan, R. ,  GI-GASIFICATION INTERNATIONAL(LUXEMBOURG) S.A.

Inventor： INGA, Juan, R.

IPC: B01J38/50

CPC classification number: B01J38/50 ,  B01J23/74 ,  B01J23/94 ,  B01J38/10 ,  B01J38/12 ,  B01J38/48 ,  B01J38/56 ,  C10G2/332 ,  C10G2/34 ,  C10G2300/70

Abstract: Systems, methods and apparatuses for regenerating a Fischer-Tropseh ("FT") catalyst thai is to be regenerated with a first wash fluid comprising at least one hydrocarbon and contacting the washed FT catalyst with a gas comprising hydrogen. Other embodiments are also disclosed.

Abstract translation: 用于再生Fischer-Tropseh（“FT”）催化剂的系统，方法和装置将用包含至少一种烃的第一洗涤流体再生，并将洗涤的FT催化剂与包含氢气的气体接触。 还公开了其他实施例。

公开(公告)号：WO2012166167A1

公开(公告)日：2012-12-06

申请号：PCT/US2011/049959

申请日：2011-08-31

Applicant: GI GASIFICATION INTERNATIONAL, S.A. ,  INGA, Juan R.

Inventor： INGA, Juan R.

IPC: B01J37/00 ,  C10G2/00 ,  B01J29/00 ,  C07C1/04

CPC classification number: B01J8/0278 ,  B01J8/001 ,  B01J23/75 ,  B01J37/16 ,  B01J37/18 ,  B01J2208/00628 ,  B01J2208/00893 ,  C01B3/50 ,  C01B13/11 ,  C01B2201/14 ,  C01B2203/0233 ,  C01B2203/04 ,  C01B2203/062 ,  C01B2203/1241 ,  C10G2/332 ,  C10G2300/703 ,  Y02P20/582

Abstract: A Fischer-Tropsch catalyst activation system including separation apparatus configured for separating a product gas comprising primarily hydrogen from a gas stream comprising hydrogen, an activation reactor fluidly connected with the separation apparatus via an activation gas inlet line whereby the product gas may be introduced into the activation reactor, and a circulation loop fluidly connecting a gas outlet of the activation reactor with the activation gas inlet line or with another gas inlet of the activation reactor and fluidly connecting the activation reactor with one or more apparatus configured for removal of H 2 O. A method of activating a Fischer-Tropsch catalyst is also provided.

Abstract translation: 一种费 - 托催化剂活化系统，包括分离装置，其被配置用于从包含氢的气流中分离主要包含氢的产物气体，经由活化气体入口管线与分离装置流体连接的活化反应器，由此可将产物气体引入 活化反应器和将活化反应器的气体出口流体连接到活化气体入口管线或与活化反应器的另一气体入口流体连接的循环回路，并将活化反应器与配置用于除去H 2 O的一种或多种装置流体连接。 还提供了活化费 - 托催化剂的方法。

公开(公告)号：WO2015027043A1

公开(公告)日：2015-02-26

申请号：PCT/US2014052052

申请日：2014-08-21

Applicant: GI GASIFICATION INTERNAT LUXEMBOURG S A ,  HEMMINGS JOHN ,  INGA JUAN R

Inventor： HEMMINGS JOHN ,  INGA JUAN R

IPC: C07C1/04

CPC classification number: C10G45/00 ,  B01J8/006 ,  B01J8/226 ,  B01J8/228 ,  B01J2208/00212 ,  B01J2208/0084 ,  B01J2208/00867 ,  B01J2208/025 ,  C10G2/33 ,  C10G45/02 ,  C10G45/16 ,  C10G45/22 ,  C10G45/58 ,  C10G45/66 ,  C10G47/04 ,  C10G47/26 ,  C10G67/02 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/4006

Abstract: A process for hydrogenating a Fischer-Tropseh ("FT") wax includes placing hydrogenation catalyst particles within a low-temperature hydrogenation reactor having a mixing sub-system and a vent at the top for excess hydrogen, placing the FT wax at a low temperature up to a predetermined level within the Sow-temperature, hydrogenation reactor, leaving a vapor space above the predetermined level, adding hydrogen under a desired pressure into the low-temperature hydrogenation reactor, mixing the input FT wax, the hydrogen gas and the hydrogenating catalyst particles together to create a mixture using the mixing subsystem and continuing the mixing until the FT wax has hydrogenated, stopping the mixing to allow the hydrogenation catalyst particles to settle, and removing an hydrogenated FT wax with residual hydrogenating catalyst particles from the low-temperature hydrogenation reactor. The hydrogenated FT wax may he filtered and subjected to vacuum distillation. Other embodiments are also disclosed.

Abstract translation: 氢化费 - 托（“FT”）蜡的方法包括将氢化催化剂颗粒置于低温氢化反应器内，所述低温氢化反应器具有混合子系统和位于顶部的用于过量氢的排气口，将FT蜡置于低温 在低温加氢反应器内达到预定水平，留下高于预定水平的蒸气空间，在所需压力下将氢气加入低温氢化反应器中，混合输入的FT蜡，氢气和氢化催化剂 颗粒混合在一起以使用混合子系统产生混合物，并继续混合直至FT蜡已氢化，停止混合以使氢化催化剂颗粒沉降，并且用来自低温氢化的残余氢化催化剂颗粒除去氢化的FT蜡 反应堆。 氢化的FT蜡可以过滤并进行真空蒸馏。 其他实施例也被公开。

公开(公告)号：WO2014144855A3

公开(公告)日：2014-12-24

申请号：PCT/US2014029442

申请日：2014-03-14

Applicant: INGA JUAN R ,  GI GASIFICATION INTERNATIONAL LUXEMBOURG S A

Inventor： INGA JUAN R

IPC: B01J38/50 ,  B01J38/56 ,  C07C27/26 ,  C10G2/00

CPC classification number: B01J38/50 ,  B01J23/74 ,  B01J23/94 ,  B01J38/10 ,  B01J38/12 ,  B01J38/48 ,  B01J38/56 ,  C10G2/332 ,  C10G2/34 ,  C10G2300/70

Abstract: Systems, methods and apparatuses for regenerating a Fischer-Tropsch ("FT") catalyst that is to be regenerated with a first wash fluid comprising at least one hydrocarbon and contacting the washed FT catalyst with a gas comprising hydrogen, method of regenerating a Fischer-Tropsch ("'FT") catalyst that is at least partially spent through having been utilized to produce FT hydrocarbons via FT synthesis in an FT reactor. The method includes the steps of washing the FT catalyst to be regenerated with a first wash fluid. The FT catalyst to be regenerated comprises pores, and at least a fraction of the pores contain a first mixture of hydrocarbons, The first wash fluid comprises at least one hydrocarbon, and the average molecular weight of the at least one hydrocarbon of the first wash fluid is less than the average molecular weight of the hydrocarbons in the first mixture of hydrocarbons.

Abstract translation: 用于再生含有至少一种烃的第一洗涤流体并使经洗涤的FT催化剂与包含氢的气体接触的Fischer-Trop（“FT”）催化剂再生的系统，方法和装置， Tropsch（“'FT”）催化剂，其通过在FT反应器中通过FT合成被用于生产FT烃的至少部分消耗。 该方法包括用第一洗涤流体洗涤待再生的FT催化剂的步骤。 待再生的FT催化剂包含孔，并且孔的至少一部分含有烃的第一混合物。第一洗涤流体包含至少一种烃，并且第一洗涤流体的至少一种烃的平均分子量 小于烃的第一混合物中烃的平均分子量。