Abstract:
A primary cell having an anode comprising lithium or lithium alloy and a cathode comprising iron disulfide (FeS 2 ) and carbon particles. The electrolyte comprises a lithium salt preferably lithium iodide (LiI) dissolved in an organic solvent mixture. The solvent mixture preferably comprises dioxolane and dimethoxyethane. The electrolyte typically contains between about 100 and 2000 parts by weight water per million parts by weight (ppm) electrolyte therein. The anode may be lithium metal or preferably is a lithium alloy. A cathode slurry is prepared comprising iron disulfide powder, carbon, binder, and a liquid solvent. The mixture is coated onto a conductive substrate and solvent evaporated leaving a dry cathode coating on the substrate. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.
Abstract:
A primary lithium battery can include a current collector that includes aluminum, a cap that includes aluminum, or both. The aluminum battery components can have high mechanical strength and low electrical resistance.
Abstract:
A primary cell having an anode comprising lithium and a cathode comprising iron disulfide (FeS2) and carbon particles. The cell can be in the configuration of a coin cell or the anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added. _ The electrolyte comprises a lithium salt dissolved in a nonaqueous solvent mixture which may include an organic cyclic carbonate such as ethylene carbonate and propylene carbon. The cell after assembly is subjected to a two step preconditioning (prediscahrge) protocol involving at least two distinct discharge steps having at lease one cycle of pulsed current drain in each step and at least one rest period (step rest) between said two steps, wherein said step rest period is carried out for a period of time at above ambient temperature. The preconditioning improves cell performance.
Abstract:
A primary lithium battery can include a current collector that includes aluminum, a cap that includes aluminum, or both. The aluminum battery components can have high mechanical strength and low electrical resistance.
Abstract:
Electrochemical cells are disclosed. In some embodiments, an electrochemical cell includes a cathode having less than about 2,000 ppm of water, an anode, and an electrolyte having a first lithium salt and LiPFF 6 .
Abstract:
An electrochemical secondary cell is disclosed. The cell includes a cathode, an anode, a current collector including aluminum, and an electrolyte containing a perchlorate salt and a second salt. The electrolyte is essentially free of LiPF 6 .
Abstract:
A battery includes an anode including an alkali metal as the active material, a cathode having, for example, iron disulfide as the active material, and an electrolyte including an organic solvent and an aluminum salt selected from the group consisting of aluminum iodide and aluminum tri(sec-butoxide).
Abstract:
A battery includes an anode including an alkali metal as the active material, a cathode having, for example, iron disulfide as the active material, and an electrolyte including an organic solvent and an aluminum salt selected from the group consisting of aluminum iodide and aluminum tri(sec-butoxide).
Abstract:
An alkaline cell (810) having an anode mixture (815) comprising zinc particles, aqueous alkaline electrolyte, and molecular sieve additive. The cathode (812) preferably comprises manganese dioxide. The cell may be cylindrical or any other shape or size. The molecular sieve additive preferably comprises a crystalline aluminosilicate material which is in at least a partially dehydrated state before admixture with the aqueous electrolyte, preferably potassium hydroxide. The aluminosilicate crystalline structure has average pore size between about 3 and 25 Angstrom. The addition of the molecular sieves to the zinc anode improves the cell's discharge capacity and service life. The molecular sieves preferably comprises between about 0.07 and 0.7 percent by weight of the anode mixture.
Abstract:
A primary lithium battery can include a current collector that includes aluminum, a positive lead that includes aluminum, or both. The aluminum battery components can have high mechanical strength and low electrical resistance.