公开(公告)号：WO1986004063A1

公开(公告)日：1986-07-17

申请号：PCT/FI1985000102

申请日：1985-12-20

申请人： KSV-CHEMICALS OY ,  VIRTANEN, Jorma ,  KINNUNEN, Paavo ,  KULO, Arvo

发明人： KSV-CHEMICALS OY

IPC分类号： C07F07/08

CPC分类号： C08G77/04 ,  B01J20/286 ,  B01J20/3204 ,  B01J20/3219 ,  B01J20/3257 ,  B01J20/3259 ,  B01J20/3261 ,  B01J20/3263 ,  B01J20/3272 ,  C07F7/122 ,  C07F7/1804 ,  Y10T428/2995 ,  Y10T428/2998 ,  Y10T428/31 ,  Y10T428/315 ,  Y10T428/31612

摘要： New compounds for making a hydrophilic surface lipophilic. The compouns have general formula (I), wherein Z and Z independently is chlorine, fluorine, bromine, alkoxy with not more than 6 carbon atomes, NH, -NH2, -NR2, wherein R' is alkyl with 1 to 3 carbon atoms, -SH, -CN, - N3 or hydrogen, and R is formula (II), wherein each S-substituent which can be the same or different is hydrogen, whereby the phenyl ring may contain at the most four hydrogen substituents, alkyl with 2 to 4 carbon atoms, or methyl or methoxy, in which case there may be at the most three hydrogen substituents in the phenyl ring, cyano, ethoxy, or two adjacent S-substituents form with the phenyl nucleus a naphtalene or anthracene group, or three adjacent S-substituents form together with the phenyl nucleus a pyrene group, and X is the group -(CH2)n , wherein n is 0 to 20, preferably 10 to 16, or the group (III), wherein i is 0 to 10 and k is 1 to 5, whereby, when n is not 0, i.e. X is a spacer group, the S-substituents, especially S3, can also be phenoxy or biphenyl, and R is equal to Z or R , or is lower alkyl, lower alkenyl, phenyl, or phenyl substituted with lower alkyl or lower alkoxy. The novel compounds may be used as such for modifying the hydrophilic surface for a variety of purposes, such as for chromatographic purposes or for use in electronics, or the compound may be polymerized, optionally using as coreactants known silanes, to form polymers especially well suited for chromatographic purposes.

摘要翻译： 用于使亲水表面亲油的新化合物。 化合物具有通式（I），其中Z 1和Z 2独立地是氯，氟，溴，具有不超过6个碳原子的烷氧基，NH，-NH 2，-NR 2，其中R'是烷基与 1至3个碳原子，-SH，-CN，-N 3或氢，R 1是式（II），其中每个可以相同或不同的S取代基是氢，由此苯环可以含有 最多四个氢取代基，具有2至4个碳原子的烷基，或甲基或甲氧基，在这种情况下，在苯环中可以具有最多三个氢取代基，氰基，乙氧基或两个相邻的S-取代基与苯基 核是一个萘或蒽基，或三个相邻的S取代基与苯基一起形成一个芘基，X是基团 - （CH 2）n ，其中n为0至20，优选10至16，或 其中i为0至10且k为1至5，其中当n不为0时，即X为间隔基，S-取代基，特别是S3也可以是苯氧基或 联苯基和R 2等于Z 1或R 1，或者为低级烷基，低级烯基，苯基或被低级烷基或低级烷氧基取代的苯基。 新颖的化合物可以原样用于改变亲水性表面，用于各种目的，例如用于色谱目的或用于电子学中，或者化合物可以聚合，任选地使用已知硅烷的共反应物形成聚合物，特别适合于 用于色谱目的。

公开(公告)号：WO1987000343A1

公开(公告)日：1987-01-15

申请号：PCT/FI1986000067

申请日：1986-06-27

申请人： KSV-CHEMICALS OY ,  KINNUNEN, Paavo ,  VIRTANEN, Jorma

发明人： KSV-CHEMICALS OY

IPC分类号： H01B01/12

CPC分类号： H01L51/0052 ,  H01L51/005 ,  H01L51/0053 ,  H01L51/0054 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/0075 ,  H01L51/0076 ,  H01L51/0077 ,  H01L51/0083

摘要： Film aggregate having electricity conducting characteristics. The film is comprised of a substantially inert support surface carrying one or several monomolecular film layers formed by a surface active material of liquid crystal type having modifiable electrical properties. The film layer is of a sandwich type construction containing at least the folllowing zones: - a spacer-zone (2) containing aliphatic hydrocarbyl groups and which to its electrical characteristics is substantially inert, - a conducting area (3-5) which on the one hand is comprised of a charge-transfer zone (3 or 5) and on the otherhand of a polarizable zone (5 or 3) as well as of a spacer zone (4) between these zones, - a spacer zone (6) which corresponds to the above zone (2), - a hydrophilic zone (7). The invention concerns also new glycerophospholipids and threitolphospholipids to be used in the films, containing in their fatty side chains at least one, but preferably two active groups, i.e. a polarizable group and charge-transfer group. The invention also concerns the fatty acids, alcohols group and amines used for the side chains in the lipids and carrying a polarizable group and a charge-transfer group.

摘要翻译： 具有导电特性的薄膜聚集体。 该薄膜由携带由具有可修改的电性能的液晶型表面活性材料形成的一个或多个单分子膜层的基本惰性的支撑表面组成。 膜层是至少包含以下区域的夹层结构： - 含有脂族烃基并且其电特性基本上是惰性的间隔区（2） - 导电区域（3-5），其在 一方面由电荷转移区域（3或5）组成，另一方面由可极化区域（5或3）以及这些区域之间的间隔区域（4）构成;间隔区域（6） 对应于上述区域（2）， - 亲水区域（7）。 本发明还涉及在膜中使用的新的甘油磷脂和硫代磷脂，其脂肪侧链含有至少一个但优选两个活性基团，即可极化基团和电荷转移基团。 本发明还涉及用于脂质中的侧链的脂肪酸，醇基和胺，并携带可极化基团和电荷转移基团。