Abstract:
The present invention relates to a cascade refrigeration system which circulates a refrigerant comprising a fluoroolefin therethrough. The cascade refrigeration system includes a low temperature refrigeration loop and a medium temperature refrigeration loop. The fluoroolefin circulates through either loop, or both. In a particular embodiment, the fluoroolefin circulates through the medium temperature loop. In a particular embodiment, where the cascade refrigeration system includes a first and a second cascade heat exchanger, and a secondary heat transfer loop which extends between the first and second cascade heat exchangers, either the first and/or second refrigerant may be, but need not necessarily be, a fluoroolefin.
Abstract:
The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be a terpene, terpenoid or fullerene; or a mixture of a terpene, terpenoid or fullerene with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
Abstract:
The present invention relates to a refrigeration or air-conditioning apparatus which utilizes a vapor compression refrigeration system having a refrigerant circulating therethrough that comprises a compressor powered by an engine exhaust gas driven turbine. A mini centrifugal compressor may advantageously be used with such an apparatus, thus allowing the use of low GWP refrigerants. The present invention further relates to methods for powering a compressor, such as a mini-centrifugal compressor, in a refrigeration or air-conditioning apparatus, and methods for controlling compressor surge, impeller speed and cooling capacity.
Abstract:
Disclosed herein are haloketone refrigerant or heat transfer fluid compositions that are useful in refrigeration or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor systems that employ two-stage compressors or single slab/single pass heat exchangers.
Abstract:
The present invention relates to dispersion compositions comprising synthetic oils or other heat transfer fluids and fine particles. The compositions also comprise at least one dispersant. The dispersion compositions have improved thermal conductivity properties, which may translate to improved energy efficiency performance in a variety of heat transfer applications. Such applications include vapor compression air conditioning and refrigeration systems of all types, secondary heat transfer fluids, and other heating or cooling fluid applications.
Abstract:
Disclosed herein are 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone compositions for use in refrigeration and air conditioning systems, particularly centrifugal compressor systems. Also disclosed are 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone in combination with fluoroethers, which are azeotropic or near azeotropic.
Abstract:
Disclosed herein are haloketone refrigerant or heat transfer fluid compositions that are useful in refrigeration or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor systems that employ two-stage compressors or single slab/single pass heat exchangers.
Abstract:
Disclosed herein is a chiller apparatus containing a composition comprising from about 6 to about 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to about 94 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein are compositions comprising from about 58.0 to about 59.5 weight percent 2,3,3,3-tetrafluoropropene and from about 42.0 to about 40.5 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein are compositions comprising from about 54.0 to about 56.0 weight percent 2,3,3,3-tetrafluoropropene and from about 46.0 to about 44.0 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a composition comprising a refrigerant consisting essentially of from about 58.0 to about 59.5 weight percent 2,3,3,3-tetrafluoropropene and from about 42.0 to about 40.5 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a composition comprising a refrigerant consisting essentially of from about 54.0 to about 56.0 weight percent 2,3,3,3-tetrafluoropropene and from about 46.0 to about 44.0 weight percent 1,1,1,2-tetrafluoroethane. Also disclosed herein is a method for producing cooling in a chiller. The method comprises (a) evaporating a liquid refrigerant comprising from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane in an evaporator having a heat transfer medium passing therethrough thereby producing a vapor refrigerant; and (b) compressing the vapor refrigerant in a compressor, wherein the volumetric cooling capacity of the refrigerant is greater than the individual volumetric cooling capacities of both 2,3,3,3-tetrafluoropropene and 1,1,1,2-tetrafluoroethane alone. Also disclosed herein is a method for replacing a refrigerant in a chiller designed for using HFC-134a or CFC-12 as refrigerant, comprising charging said chiller with a composition comprising a refrigerant consisting essentially of from about 6 to 70 weight percent 2,3,3,3-tetrafluoropropene and from about 30 to 94 weight percent 1,1,1,2-tetrafluoroethane thereby increasing the cooling capacity of the chiller.
Abstract:
The present disclosure relates to compositions comprising at least one fluoroolefin and an effective amount of a stabilizer comprising at least one phosphorus-containing compound selected from the group consisting of thiophosphates, butylated triphenylphosphorothionates, and organophosphates. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.
Abstract:
The present invention relates to compositions comprising at least one fluoroolefin and an effective amount of stabilizer that may be an amine or a mixture of an amine with other stabilizers. The stabilized compositions may be useful in cooling apparatus, such as refrigeration, air-conditioning, chillers, and heat pumps, as well as in applications as foam blowing agents, solvents, aerosol propellants, fire extinguishants, and sterilants.