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    WASTE WATER TREATMENT WITH A MN ( III ) OR MN ( IV) COMPLEX AS CATALYST
    7.
    发明申请
    WASTE WATER TREATMENT WITH A MN ( III ) OR MN ( IV) COMPLEX AS CATALYST 审中-公开
    具有MN（III）或MN（IV）复合物作为催化剂的废水处理

    公开(公告)号：WO2009115376A1

    公开(公告)日：2009-09-24

    申请号：PCT/EP2009/051616

    申请日：2009-02-12

    Applicant: UNILEVER PLC ,  UNILEVER N.V. ,  HAGE, Ronald ,  KORF, Hilda ,  LIENKE, Joachim ,  PRINS, Ferry ,  SOH, Tristan, Conway

    Inventor： HAGE, Ronald ,  KORF, Hilda ,  LIENKE, Joachim ,  PRINS, Ferry ,  SOH, Tristan, Conway

    IPC: C02F1/72

    CPC classification number: C02F1/722 ,  B01J31/1815 ,  B01J2531/72 ,  C02F1/4678 ,  C02F1/66 ,  C02F1/725 ,  C02F2101/308 ,  C02F2101/345 ,  C02F2103/30 ,  C02F2103/343 ,  C02F2209/02 ,  C02F2209/06 ,  C02F2209/44

    Abstract: A method of treating aqueous industrial waste comprising the following steps : (i) storing the aqueous industrial waste in a holding vessel (ii) adding to the aqueous industrial waste a transition metal catalyst or precursor thereof and hydrogen peroxide to provide a concentration of the transition metal catalyst in a concentration from 0.1 to 100 mM and a concentration of the hydrogen peroxide from 1 to 1500 mM and (iii) releasing the effluent after treatment for further processing or directly into the environment, wherein the tansition metal catalyst is a specific mononuclear or dinuclear complex of a Mn (iii) or Mn (IV) transition metal catalyst, and wherein the pH of the aqueous solution is maintained within the operating window of 2.5 pH units in the pH range 7.5 to 11.5. The preformed catalyst is subjected to an electrochemical reduction step before addition to the waste solution.

    Abstract translation: 一种处理水性工业废物的方法，包括以下步骤：（i）将水性工业废物储存在保持容器中（ii）向工业废水中加入过渡金属催化剂或其前体和过氧化氢以提供过渡浓度 浓度为0.1至100mM的氧化金属催化剂和1至1500mM的过氧化氢浓度，和（iii）将处理后的流出物进一步处理或直接进入环境中，其中所述的改性金属催化剂是特定的单核或 Mn（ⅲ）或Mn（Ⅳ）过渡金属催化剂的双核络合物，并且其中在7.5至11.5的pH范围内，水溶液的pH值保持在2.5 pH单位的操作窗口内。 将预成型催化剂在添加到废溶液中之前经历电化学还原步骤。

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