公开(公告)号：WO2012089652A1

公开(公告)日：2012-07-05

申请号：PCT/EP2011/073925

申请日：2011-12-23

Applicant: POLIMERI EUROPA S.P.A. ,  PAMPALONI, Guido ,  RENILI, Filippo ,  SOMMAZZI, Anna ,  MARCHETTI, Fabio ,  MASI, Francesco ,  POLESELLO, Mario

Inventor： PAMPALONI, Guido ,  RENILI, Filippo ,  SOMMAZZI, Anna ,  MARCHETTI, Fabio ,  MASI, Francesco ,  POLESELLO, Mario

IPC: C07F7/00

CPC classification number: C07F19/00 ,  B01J31/122 ,  C07F7/006 ,  C08F4/42 ,  C08F10/00 ,  C08F4/659

Abstract: Metal alkyl-arene having general formula (I) or (Ia): M (η 6 -arene) 2 Al q X r R s (I) M (η 6 -arene)Al q X r R s (Ia) wherein: - M represents zirconium (Zr), hafnium (Hf), or mixtures thereof, preferably zirconium; - arene represents a benzene, or a benzene 10 substituted with from 1 to 6 linear or branched C 1 -C 6 alkyl groups, or mixtures thereof; - X represents a halogen atom selected from chlorine, bromine, fluorine, iodine, preferably chlorine; - R represents a linear or branched C 1 -C 15 alkyl group; - q is a number ranging from 2 to 6, preferably 3 for a metal alkyl-arene having general formula (I), 2 for a metal alkyl-arene having general formula (Ia); - r is a number ranging from 1 to 20, preferably 9 for a metal alkyl-arene having general formula (I), 6 for a metal alkyl-arene having general formula (Ia); - s is a number ranging from 1 to 6, preferably 2. Said metal alkyl-arene can be advantageously used for the preparation of solid components of catalysts for the (co)polymerization of α-olefins.

Abstract translation: 具有通式（I）或（Ia）的金属烷基芳烃：M（ε6-芳烃）2AlqXrRs（I）M（ε6-芳烃）AlqXrRs（Ia）其中：-M表示锆（Zr），铪 ）或其混合物，优选锆; 芳烃代表苯或被1至6个直链或支链C 1 -C 6烷基取代的苯10，或其混合物; -X表示选自氯，溴，氟，碘，优选氯的卤素原子; -R表示直链或支链的C 1 -C 15烷基; 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，q是2至6的数，优选3。 对于具有通式（I）的金属烷基芳烃，对于具有通式（Ia）的金属烷基芳烃，r为1至20，优选9。 s为1至6的数，优选为2.所述金属烷基芳烃可有利地用于制备用于α-烯烃的（共）聚合的催化剂的固体组分。

公开(公告)号：WO2002102861A3

公开(公告)日：2002-12-27

申请号：PCT/EP2002/006497

申请日：2002-06-12

Applicant: ENI S.p.A. ,  POLIMERI EUROPA S.p.A. ,  CALDERAZZO, Fausto ,  MASI, Francesco ,  SOMMAZZI, Anna ,  SANTI, Roberto ,  RICCI, Giovanni ,  PAMPALONI, Guido ,  BONSIGNORE, Stefanio ,  VALENTI, Silvia ,  BIANCHINI, Claudio

Inventor： MASI, Francesco ,  SOMMAZZI, Anna ,  SANTI, Roberto ,  RICCI, Giovanni ,  PAMPALONI, Guido ,  BONSIGNORE, Stefanio ,  VALENTI, Silvia ,  BIANCHINI, Claudio

IPC: C08F36/00

Abstract: A process is described for the homo- and co-polymerization of conjugagted dienes characterized in that it is carried out in the presence of a catalytic system comprising a complex having general formula (II): Fe(L)n(X)s wherein n is an integer ranging from 1 to 3; X is independently a group of an anionic nature bound to Fe(II) as an anion in an ionic couple or with a covalent bond of the σ type; "s" expresses the number of x groups sufficient for neutralizing the formal oxidation charge of Fe(II), and is equal to 2 if all the X groups are monovalent; L is a ligand having general formula (I)

公开(公告)号：WO02102861A2

公开(公告)日：2002-12-27

申请号：PCT/EP0206497

申请日：2002-06-12

Applicant: ENI SPA ,  POLIMERI EUROPA SPA ,  MASI FRANCESCO ,  SOMMAZZI ANNA ,  SANTI ROBERTO ,  RICCI GIOVANNI ,  CALDERAZZO FAUSTO ,  PAMPALONI GUIDO ,  BONSIGNORE STEFANIO ,  VALENTI SILVIA ,  BIANCHINI CLAUDIO

Inventor： MASI FRANCESCO ,  SOMMAZZI ANNA ,  SANTI ROBERTO ,  RICCI GIOVANNI ,  PAMPALONI GUIDO ,  BONSIGNORE STEFANIO ,  VALENTI SILVIA ,  BIANCHINI CLAUDIO

IPC: C07F15/02 ,  C08F4/70 ,  C08F36/00

CPC classification number: C08F36/00 ,  C07F15/025 ,  C08F4/80 ,  C08F4/7006

Abstract: A process is described for the homo- and co-polymerization of conjugagted dienes characterized in that it is carried out in the presence of a catalytic system comprising a complex having general formula (II): Fe(L)n(X)s wherein n is an integer ranging from 1 to 3; X is independently a group of an anionic nature bound to Fe(II) as an anion in an ionic couple or with a covalent bond of the sigma type; "s" expresses the number of x groups sufficient for neutralizing the formal oxidation charge of Fe(II), and is equal to 2 if all the X groups are monovalent; L is a ligand having general formula (I)

Abstract translation: 描述了用于共轭二烯的均聚和共聚的方法，其特征在于其在包含通式（II）的络合物的催化体系存在下进行：Fe（L）n（X）s，其中n 是1〜3的整数; X独立地是与离子对或与σ型共价键作为阴离子的Fe（II）结合的阴离子性基团; “s”表示足以中和Fe（II）的形式氧化电荷的x族数，如果所有X基都是一价，则等于2; L是具有通式（I）的配体，

公开(公告)号：WO2003010210A1

公开(公告)日：2003-02-06

申请号：PCT/EP2002/007684

申请日：2002-07-10

Applicant: POLIMERI EUROPA S.P.A. ,  SOMMAZZI, Anna ,  MASI, Francesco ,  BORSOTTI, Giampietro ,  SANTI, Roberto ,  CALDERAZZO, Fausto ,  PAMPALONI, Guido ,  PASSARELLI, Vincenzo

Inventor： SOMMAZZI, Anna ,  MASI, Francesco ,  BORSOTTI, Giampietro ,  SANTI, Roberto ,  CALDERAZZO, Fausto ,  PAMPALONI, Guido ,  PASSARELLI, Vincenzo

IPC: C08F10/00

CPC classification number: C08F10/00 ,  C08F4/65927 ,  Y10S526/943 ,  C08F4/65912

Abstract: An organometallic composition which can be used as activating component in a metallocene catalyst for the (co)polymerization of α-olefins, comprises: (A) a fluorinated di-unsaturated cyclic compound, having a relatively acid hydrogen atom, (B) an organometallic compound sufficiently basic to react with the acid hydrogen of the above compound (A), and (C) a polar aprotic organic compound, not containing metallic atoms, having a dielectric constant, in the pure state, equal to or greater than 2, and a weak coordinating capacity. Said composition allows a metallocene catalytic system of the ionic type to be obtained, with a high activity in the (co)polymerization of olefins and a reduced content of metallic residue in the polymeric product thus obtained.

Abstract translation: 可用作α-烯烃（共）聚合的茂金属催化剂中的活化组分的有机金属组合物包括：（A）具有相对酸性氢原子的氟化二不饱和环状化合物，（B）有机金属 具有足够碱性的化合物与上述化合物（A）的酸性氢反应，和（C）在纯状态下不具有介电常数的金属原子的极性非质子有机化合物等于或大于2，以及 协调能力弱。 所述组合物允许获得离子型茂金属催化体系，在烯烃的（共）聚合中具有高活性，并且由此获得的聚合物中的金属残余物含量降低。

公开(公告)号：WO2012089562A1

公开(公告)日：2012-07-05

申请号：PCT/EP2011/073429

申请日：2011-12-20

Applicant: POLIMERI EUROPA S.P.A. ,  SOMMAZZI, Anna ,  MASI, Francesco ,  PAMPALONI, Guido ,  RENILI, Filippo ,  MARCHETTI, Fabio ,  RASPOLLI GALLETTI, Anna Maria

Inventor： SOMMAZZI, Anna ,  MASI, Francesco ,  PAMPALONI, Guido ,  RENILI, Filippo ,  MARCHETTI, Fabio ,  RASPOLLI GALLETTI, Anna Maria

IPC: C08F10/02 ,  C08F4/655 ,  C08F4/659 ,  C07F7/00

CPC classification number: C08F10/02 ,  C07F17/00 ,  C08F4/52 ,  C08F4/65912 ,  C08F4/76 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6557 ,  C08F4/65904 ,  C08F4/6552 ,  C08F2500/12 ,  C08F210/14

Abstract: A solid catalyst component for the (co) polymerization of α-olefins having general formula (I): Zr n MA1 x C1Mg p (I) wherein : M represents titanium (Ti), vanadium (V), or mixtures thereof; n is a number ranging from 0.01 to 2; x is a number ranging from 0.1 to 4; y is a number ranging from 5 to 53; p is a number ranging from 0 to 15; obtained by means of a process comprising putting at least one zirconium arene in contact with at least one metal compound and, optionally, with at least one com¬ pound of magnesium. Said solid catalyst component can be advantageously used as a solid component in a catalyst for the (co) polymerization of α-olefins. Said catalyst can be advantageously used in a process for the (co) polymerization of α-olefins.

Abstract translation: 具有通式（I）的α-烯烃（共）聚合的固体催化剂组分：ZrnMA1xC1Mgp（I）其中：M表示钛（Ti），钒（V）或其混合物; n为0.01〜2的数; x是从0.1到4的数字; y是从5到53的数字; p是从0到15的数字; 通过包括将至少一种锆芳烃与至少一种金属化合物和任选地与至少一种镁混合的方法获得。 所述固体催化剂组分可有利地用作α-烯烃（共）聚合的催化剂中的固体组分。 所述催化剂可有利地用于α-烯烃的（共）聚合方法中。