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    COMPOSITIONS FOR DRIP FUMIGATION
    4.
    发明申请
    COMPOSITIONS FOR DRIP FUMIGATION 审中-公开
    DRIP FUMIGATION组成

    公开(公告)号：WO2011133292A3

    公开(公告)日：2012-03-08

    申请号：PCT/US2011030132

    申请日：2011-03-28

    申请人： HONEYWELL INT INC ,  POSS ANDREW JOSEPH ,  SINGH RAJIV RATNA ,  NALEWAJEK DAVID ,  CANTLON CHERYL

    发明人： POSS ANDREW JOSEPH ,  SINGH RAJIV RATNA ,  NALEWAJEK DAVID ,  CANTLON CHERYL

    IPC分类号： A01N29/02 ,  A01N25/18 ,  A01N25/30 ,  A01N59/00

    CPC分类号： A01N29/00 ,  A01N25/04 ,  A01N2300/00

    摘要： Soil fumigation compositions are provided herein that include methyl iodide, at least one fluorocarbon or hydrofluorocarbon, at least one surfactant, and water. The fumigant can be produced by combining the water and surfactant with an intial mixture that is an azeotropic or azeotrope-like mixture of methyl iodide and at least one fluorocarbon or hydrofluorocarbon. The fumigant compositions can be utilized in drip fumigation processes, and have increased volatility as compared to methyl iodide alone, which can reduce the risk of water contamination when utilizing methyl iodide as a fumigant.

    摘要翻译： 本文提供了包括甲基碘，至少一种碳氟化合物或氢氟烃，至少一种表面活性剂和水的土壤熏蒸组合物。 熏蒸剂可以通过将水和表面活性剂与甲基碘和至少一种碳氟化合物或氢氟烃的共沸或类共沸混合物的初始混合物结合来制备。 熏蒸剂组合物可用于滴水熏蒸方法，并且与单独的甲基碘相比具有增加的挥发性，当使用甲基碘作为熏蒸剂时，可以降低水污染的风险。

    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE
    6.
    发明申请
    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE 审中-公开
    制备十六烷基-2-丁基的方法

    公开(公告)号：WO2011146812A2

    公开(公告)日：2011-11-24

    申请号：PCT/US2011037298

    申请日：2011-05-20

    申请人： HONEYWELL INT INC ,  POSS ANDREW JOSEPH ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA

    发明人： POSS ANDREW JOSEPH ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA

    CPC分类号： C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

    摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX=CXCF3, where X = halogen; and (b) treating CF3CX=CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX=CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX=CHCF3 is greatly reduced or eliminated.

    摘要翻译： 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下用脱卤催化剂处理CF 3 C X = CXCF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = CXCF 3转移到卤素受体化合物。 由于Y不是氢，CF3CX = CHCF3的形成大大降低或消除。

    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE
    7.
    发明申请
    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE 审中-公开
    制备氟化苯乙烯的方法

    公开(公告)号：WO2011146792A2

    公开(公告)日：2011-11-24

    申请号：PCT/US2011/037268

    申请日：2011-05-20

    申请人： HONEYWELL INTERNATIONAL INC. ,  POSS, Andrew Joseph ,  VAN DER PUY, Michael ,  SINGH, Rajiv Ratna ,  NALEWAJEK, David ,  NAIR, Haridasan K.

    发明人： POSS, Andrew Joseph ,  VAN DER PUY, Michael ,  SINGH, Rajiv Ratna ,  NALEWAJEK, David ,  NAIR, Haridasan K.

    CPC分类号： C07C17/23 ,  C07B2200/09 ,  C07C17/10 ,  C07C17/206 ,  C07C17/278 ,  C07C21/18 ,  C07C19/10

    摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).

    摘要翻译： 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。

    COMPOSITIONS FOR DRIP FUMIGATION
    8.
    发明申请
    COMPOSITIONS FOR DRIP FUMIGATION 审中-公开
    DRIP FUMIGATION的组成

    公开(公告)号：WO2011133292A2

    公开(公告)日：2011-10-27

    申请号：PCT/US2011/030132

    申请日：2011-03-28

    申请人： HONEYWELL INTERNATIONAL INC. ,  POSS, Andrew, Joseph ,  SINGH, Rajiv, Ratna ,  NALEWAJEK, David ,  CANTLON, Cheryl

    发明人： POSS, Andrew, Joseph ,  SINGH, Rajiv, Ratna ,  NALEWAJEK, David ,  CANTLON, Cheryl

    IPC分类号： A01N29/02 ,  A01N25/18 ,  A01N59/00 ,  A01N25/30

    CPC分类号： A01N29/00 ,  A01N25/04 ,  A01N2300/00

    摘要： Soil fumigation compositions are provided herein that include methyl iodide, at least one fluorocarbon or hydrofluorocarbon, at least one surfactant, and water. The fumigant can be produced by combining the water and surfactant with an intial mixture that is an azeotropic or azeotrope-like mixture of methyl iodide and at least one fluorocarbon or hydrofluorocarbon. The fumigant compositions can be utilized in drip fumigation processes, and have increased volatility as compared to methyl iodide alone, which can reduce the risk of water contamination when utilizing methyl iodide as a fumigant.

    摘要翻译： 本文提供了包括甲基碘，至少一种碳氟化合物或氢氟烃，至少一种表面活性剂和水的土壤熏蒸组合物。 熏蒸剂可以通过将水和表面活性剂与作为甲基碘和至少一种碳氟化合物或氢氟烃的共沸或类共沸混合物的初始混合物结合来制备。 熏蒸剂组合物可用于滴水熏蒸方法，并且与单独的甲基碘相比具有增加的挥发性，当使用甲基碘作为熏蒸剂时，这可以降低水污染的风险。

    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE
    10.
    发明申请
    PROCESS FOR THE PREPARATION OF FLUORINATED CIS-ALKENE 审中-公开
    制备氟化苯乙烯的方法

    公开(公告)号：WO2011146792A3

    公开(公告)日：2012-04-12

    申请号：PCT/US2011037268

    申请日：2011-05-20

    申请人： HONEYWELL INT INC ,  POSS ANDREW JOSEPH ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K

    发明人： POSS ANDREW JOSEPH ,  VAN DER PUY MICHAEL ,  SINGH RAJIV RATNA ,  NALEWAJEK DAVID ,  NAIR HARIDASAN K

    IPC分类号： C07C17/25 ,  C07C17/23 ,  C07C21/18

    CPC分类号： C07C17/23 ,  C07B2200/09 ,  C07C17/10 ,  C07C17/206 ,  C07C17/278 ,  C07C21/18 ,  C07C19/10

    摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).

    摘要翻译： 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。