公开(公告)号：WO2005095522A2

公开(公告)日：2005-10-13

申请号：PCT/EP2005/051323

申请日：2005-03-23

Applicant: CIBA SPECIALTY CHEMICALS HOLDING INC. ,  ELIU, Victor Paul ,  SAUDER, Thomas ,  KAUFFMANN, Dominique ,  FRÖHLING, Beate

Inventor： ELIU, Victor Paul ,  SAUDER, Thomas ,  KAUFFMANN, Dominique ,  FRÖHLING, Beate

IPC: C09B44/16

CPC classification number: C09B44/16

Abstract: Disclosed are azo dyes of formula (1) , wherein R 1 is hydrogen; C 1 -C 14 alkyl; hydroxy- C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a) -(CH 2 ) n1 -O-(CH 2 ) n2 -CH 3 ; a radical of formula (1b) C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R3 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 1 0aryl-C 1 -C 6 alkyl; or CO-R 6 ; R 4 is CO-R 6 ; R 5 is C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R 6 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; or C 6 -C 10 aryl; R 7 , R 8 , R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; m is 1; or 2; An - is an anion; If m = 1, R 2 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a); a radical of formula (1b) ; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; If m = 2, R 2 is the direct bond; or C 1 -C 14 alkylene, which is optionally substituted by one or more C 1 -C 4 alkyl, or which is optionally interrupted by C 5 -C 10 arylene, -O- or -NR 9 R 10 -; R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.

Abstract translation: 公开了式（1）的偶氮染料，其中R 1是氢; ç<子> 1 -C <子> 14 烷基; 羟基-C 1 -C 14 - 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a） - （CH 2）n1 -O-（CH 2）n2 -n- CH <子> 3 ; 式（1b）C10芳基的基团; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R3是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; ç<子> 6 -C <子> 1 0aryl-C <子> 1 -C <子> 6 烷基; 或CO-R 6; R 4是CO-R 6; R 5是C 1 -C 14烷基; R 5是C 1 -C 14烷基。 ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R 6是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 或C≡C-C10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m是1; 或2; An ^{- 是一个阴离子; 如果m = 1，则R 2是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a）的基团; 式（1b）的基团; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 如果m = 2，则R 2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基 ，或者任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10取代的亚苯基， > - ; R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; 并且n1，n2，n3和n4彼此独立地为0-5的数。所述化合物可用于染色有机材料，优选人发。}

公开(公告)号：WO2005095522A3

公开(公告)日：2005-11-10

申请号：PCT/EP2005051323

申请日：2005-03-23

Applicant: CIBA SC HOLDING AG ,  ELIU VICTOR PAUL ,  SAUDER THOMAS ,  KAUFFMANN DOMINIQUE ,  FROEHLING BEATE

Inventor： ELIU VICTOR PAUL ,  SAUDER THOMAS ,  KAUFFMANN DOMINIQUE ,  FROEHLING BEATE

IPC: C07C231/02 ,  C07C231/12 ,  C07C245/20 ,  C09B29/36 ,  C09B43/11 ,  C09B43/40 ,  C09B44/00 ,  C09B44/16 ,  A61K7/13

CPC classification number: C09B44/16

Abstract: Disclosed are azo dyes of formula (1) , wherein R1 is hydrogen; C1-C14alkyl; hydroxy- C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a) -(CH2)n1-O-(CH2)n2-CH3; a radical of formula (1b) C10aryl; or C6-C10aryl-C1-C6alkyl; R3 is hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C6alkyl; or CO-R6; R4 is CO-R6; R5 is C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; R6 is hydrogen; C1-C14alkyl; C2-C14alkenyl; or C6-C10aryl; R7, R8, R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; m is 1; or 2; An is an anion; If m = 1, R2 is hydrogen; C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a); a radical of formula (1b) ; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; If m = 2, R2 is the direct bond; or C1-C14alkylene, which is optionally substituted by one or more C1-C4alkyl, or which is optionally interrupted by C5-C10arylene, -O- or -NR9R10-; R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.

Abstract translation: 公开了式（1）的偶氮染料，其中R 1是氢; C1-C 1-4烷基; 羟基-C 1 -C 14烷基; C2-C14alkenyl; （1a） - （CH2）n1-O-（CH2）n2-CH3的基团; 式（1b）的基团C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R3是氢; C1-C 1-4烷基; C2-C14alkenyl; C6-C10芳基; C6-C10芳基，C1-C6烷基; 或CO-R6; R4是CO-R6; R5是C1-C14烷基; C2-C14alkenyl; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; R6是氢; C1-C 1-4烷基; C2-C14alkenyl; 或C 6 -C 10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m为1; 或2; 一种阴离子; 如果m = 1，则R2为氢; C1-C 1-4烷基; C2-C14alkenyl; 式（1a）的基团; 式（1b）的基团; C6-C10芳基; 或C 6 -C 10芳基-C 1 -C 6烷基; 如果m = 2，则R2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基取代，或任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10 - 取代; R9和R10彼此独立地是氢; 或C 1 -C 5烷基; 和n1，n2，n3和n4彼此独立地为0至5的数字。该化合物可用于染色有机材料，优选人发。