公开(公告)号：WO2007038581A1

公开(公告)日：2007-04-05

申请号：PCT/US2006/037650

申请日：2006-09-27

Applicant: BASF AKTIENGESELLSCHAFT ,  VIRANI, Naheed ,  SEAGRAVES, Thomas ,  MUSSELMAN, Wayne, David ,  CHAN, William, Stewart ,  KNAEBEL, Kent, S. ,  SHIN, Heungsoo

Inventor： VIRANI, Naheed ,  SEAGRAVES, Thomas ,  MUSSELMAN, Wayne, David ,  CHAN, William, Stewart ,  KNAEBEL, Kent, S. ,  SHIN, Heungsoo

IPC: B01D53/04 ,  C01B21/14

CPC classification number: C01B21/1418 ,  B01D53/047 ,  B01D2257/402 ,  Y02C20/10 ,  Y02P20/153

Abstract: Hydroxylamine is formed in a reactor through a partial hydrogenation of nitric oxide gas (NO) with hydrogen gas (H 2 ) in an aqueous medium with nitrogen gas (N 2 ) as an inert gas. The formation of the hydroxylamine forms nitrous oxide gas (N 2 O). The gases and the water vapor are flowed away from the reactor in a vent gas stream enabling recycling of the gases. The N 2 O is removed from the vent gas stream to reduce flammability. Once the N 2 O is removed, the NO, H 2 , and N 2 are recycled and re-used in the reactor to form additional hydroxylamine. The N 2 O removed from the vent gas stream can be commercially sold or economically discarded.

Abstract translation: 羟胺在反应器中通过在氮气（N 2/2）的水性介质中将一氧化氮气体（NO）与氢气（H 2 H 2）部分氢化形成为反应器， 惰性气体。 羟胺的形成形成一氧化二氮气体（N 2 O 2）。 气体和水蒸气以能够再循环气体的排气气流从反应器中流出。 从排出气流中除去N 2 O 2以降低可燃性。 一旦去除了N 2 O 2，则NO，H 2 N 2和N 2 O 2被再循环并重新用于反应器以形成额外的 羟胺。 从排放气流中除去的N 2 O 2可以商业销售或经济地丢弃。

公开(公告)号：WO2007038661B1

公开(公告)日：2007-08-02

申请号：PCT/US2006037797

申请日：2006-09-27

Applicant: BASF AG ,  VIRANI NAHEED ,  SEAGRAVES THOMAS ,  MUSSELMAN WAYNE DAVID ,  CHAN WILLIAM STEWART ,  KNAEBEL KENT S ,  SHIN HEUNGSOO

Inventor： VIRANI NAHEED ,  SEAGRAVES THOMAS ,  MUSSELMAN WAYNE DAVID ,  CHAN WILLIAM STEWART ,  KNAEBEL KENT S ,  SHIN HEUNGSOO

IPC: B01D53/047

CPC classification number: B01D53/047 ,  B01D53/053 ,  B01D53/261 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/80 ,  B01D2259/40001 ,  B01D2259/40052 ,  B01D2259/40081 ,  B01D2259/402 ,  B01D2259/404 ,  Y02C20/10

Abstract: Hydroxylamine is formed in a reactor through a partial hydrogenation of nitric oxide gas (NO) with hydrogen gas (H 2 ) in an aqueous medium with nitrogen gas (N 2 ) as an inert gas. The formation of the hydroxylamine forms nitrous oxide gas (N 2 O). The gases and the water vapor are flowed away from the reactor in a vent gas stream enabling recycling of the gases. The N 2 O is removed from the vent gas stream to reduce flammability. The method of removing N 2 O comprises the steps of (a) flowing the vent gas through a nitrous oxide adsorbent material comprising particles such that the N 2 O is adsorbed onto the particles; (b) forming a buffer zone comprising N 2 adjacent to the nitrous oxide adsorbent material; (c) flowing additional N2O through the nitrous oxide adsorbent material to displace the other gas; and (d) desorbing the N 2 O from the nitrous oxide adsorbent material. Once the N 2 O is removed, the NO, H 2 , and N 2 are recycled and re-used in the reactor to form additional hydroxylamine. The N 2 O removed from the vent gas stream is of high purity and can be commercially sold or economically discarded.

Abstract translation: 羟胺在反应器中通过在氮气（N 2/2）的水性介质中将一氧化氮气体（NO）与氢气（H 2 H 2）部分氢化形成为反应器， 惰性气体。 羟胺的形成形成一氧化二氮气体（N 2 O 2）。 气体和水蒸气以能够再循环气体的排气气流从反应器中流出。 从排出气流中除去N 2 O 2以降低可燃性。 除去N 2 O O的方法包括以下步骤：（a）使排出气体流过包含颗粒的一氧化二氮吸附剂材料，使得N 2 O 2吸附在 粒子; （b）形成与一氧化二氮吸附剂材料相邻的包含N 2 N的缓冲区; （c）通过一氧化二氮吸附材料流动额外的N2O以置换其他气体; 和（d）从一氧化二氮吸附剂材料中解吸N 2 O 3。 一旦去除了N 2 O 2，则NO，H 2 N 2和N 2 O 2被再循环并重新用于反应器以形成额外的 羟胺。 从排出气流中除去的N 2 O 2是高纯度的，可以商业销售或经济地丢弃。

公开(公告)号：WO2007038661A1

公开(公告)日：2007-04-05

申请号：PCT/US2006/037797

申请日：2006-09-27

Applicant: BASF AKTIENGESELLSCHAFT ,  VIRANI, Naheed ,  SEAGRAVES, Thomas ,  MUSSELMAN, Wayne, David ,  CHAN, William, Stewart ,  KNAEBEL, Kent, S. ,  SHIN, Heungsoo

Inventor： VIRANI, Naheed ,  SEAGRAVES, Thomas ,  MUSSELMAN, Wayne, David ,  CHAN, William, Stewart ,  KNAEBEL, Kent, S. ,  SHIN, Heungsoo

IPC: B01D53/047

CPC classification number: B01D53/047 ,  B01D53/053 ,  B01D53/261 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/80 ,  B01D2259/40001 ,  B01D2259/40052 ,  B01D2259/40081 ,  B01D2259/402 ,  B01D2259/404 ,  Y02C20/10

Abstract: Hydroxylamine is formed in a reactor through a partial hydrogenation of nitric oxide gas (NO) with hydrogen gas (H 2 ) in an aqueous medium with nitrogen gas (N 2 ) as an inert gas. The formation of the hydroxylamine forms nitrous oxide gas (N 2 O). The gases and the water vapor are flowed away from the reactor in a vent gas stream enabling recycling of the gases. The N 2 O is removed from the vent gas stream to reduce flammability. The method of removing N 2 O comprises the steps of (a) flowing the vent gas through a nitrous oxide adsorbent material comprising particles such that the N 2 O is adsorbed onto the particles; (b) forming a buffer zone comprising N 2 adjacent to the nitrous oxide adsorbent material; (c) flowing additional N2O through the nitrous oxide adsorbent material to displace the other gas; and (d) desorbing the N 2 O from the nitrous oxide adsorbent material. Once the N 2 O is removed, the NO, H 2 , and N 2 are recycled and re-used in the reactor to form additional hydroxylamine. The N 2 O removed from the vent gas stream is of high purity and can be commercially sold or economically discarded.

Abstract translation: 羟胺在反应器中通过用氮气（N 2）作为惰性气体。 羟胺的形成形成一氧化二氮气体（N 2 O）。 气体和水蒸气在排气流中从反应器流出，使气体能够再循环。 将N 2 O从排出气流中除去以降低可燃性。 除去N 2 O的方法包括以下步骤：（a）使排出气体流过包含颗粒的一氧化二氮吸附材料，使得N 2 O被吸附到 粒子; （b）在该氧化亚氮吸附材料附近形成包含N 2的缓冲区; （c）使另外的N 2 O流过一氧化二氮吸附剂材料以置换另一种气体; 和（d）从一氧化二氮吸附剂材料解吸N 2 O. 一旦除去N 2 O，就将NO，H 2和N 2 2再循环并在反应器中重新使用以形成另外的 羟胺。 从排出气流中去除的N 2 O具有高纯度并且可以商业销售或经济地丢弃。