公开(公告)号：WO2009026956A1

公开(公告)日：2009-03-05

申请号：PCT/EP2007/058941

申请日：2007-08-28

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil ,  MERZ, Thomas

Inventor： SHAMAYELI, Khalil ,  MERZ, Thomas

IPC: C11D1/825 ,  C11D3/12 ,  C11D3/37

CPC classification number: C11D1/8255 ,  C11D1/72 ,  C11D3/1253 ,  C11D3/3707 ,  C11D3/3765

Abstract: The invention relates to a hydrous, paste-like cleaning or detergent composition comprising an emulsion having an aqueous phase and an oil phase, the composition comprises based on the whole concentrate 1 to 50 wt-% of one or more alka- unity source, 1 to 60 wt-% of a guerbet alcohol ethoxylate of the formula (R 1 - (OC 2 H 4 ) n -OH, wherein Ri is a branched C 9 to C 20 alkyl group and n is from 2 to 10, 1 to 30 wt-% of a linear alkoxylated fatty alcohol of the formula R 2 -(OC 2 H 4 ) X - (OC 3 H 6 ) y -OH, wherein R 2 is a linear C 10 to C 16 group and n is from 3 to 7 and m is from 3 to 7, 0.01 - 10 wt-% of one or more crosslinked or partly crosslinked polyacrylic acid or polymethacrylic acid or mixtures thereof, 1 - 10 wt-% of a thickener system comprising the following components: 1 - 5 wt-% of a polyacrylate, 0 - 5 wt-% of a swellable phyllosilicate, 0 - 2 wt-% of a polyethylene glycol with the provision that the thickener system comprises at least two of these components, and the rest up to 100 wt-% is water.

Abstract translation: 本发明涉及包含具有水相和油相的乳液的含水，糊状清洁或洗涤剂组合物，该组合物包含基于整个浓缩物1至50重量％的一种或多种碱性物质，1 至60重量％的式（R1-（OC2H4）n-OH的格列伯醇乙氧基化物，其中R 1是支链C 9至C 20烷基，n是2至10，1至30重量％的线性 式（R 2）（OC 2 H 4）X - （OC 3 H 6）y -OH的烷氧基化脂肪醇，其中R 2是直链C 10至C 16基团，n为3-7，m为3至7，0.01至10重量％ 的一种或多种交联或部分交联的聚丙烯酸或聚甲基丙烯酸或其混合物，1-10重量％的包含以下组分的增稠剂体系：1-5重量％的聚丙烯酸酯，0-5重量％的 可膨胀的页硅酸盐，0-2重量％的聚乙二醇，条件是增稠剂体系包含这些组分中的至少两种，其余至多100重量％是w 亚特。

公开(公告)号：WO1997011150A1

公开(公告)日：1997-03-27

申请号：PCT/EP1996004024

申请日：1996-09-13

Applicant: HENKEL-ECOLAB GMBH & CO. OHG ,  MERZ, Thomas ,  SHAMAYELI, Khalil ,  AMBERG, Günther ,  WILSBERG, Heinz-Manfred

Inventor： HENKEL-ECOLAB GMBH & CO. OHG

IPC: C11D17/00

CPC classification number: C11D3/3947 ,  C11D1/146 ,  C11D1/22 ,  C11D1/72 ,  C11D1/722 ,  C11D1/8255 ,  C11D1/8305 ,  C11D3/3907 ,  C11D17/003

Abstract: Described is a paste-form washing and cleaning agent including 20 to 58 % by wt. of, in particular non-ionic, surfactants, 2 to 40 % by wt. of builders and 2 to 40 % by wt. of a bleach containing a peroxy oxidizing agent and a bleach activator.

Abstract translation: 公开的是具有20至58重量％，尤其非离子表面活性剂，2〜40米重量％的助洗剂，并且包含含有过氧氧化剂和漂白活化剂的漂白剂组分的2至40重量％的糊状洗涤剂和清洁剂。

公开(公告)号：WO2008148420A1

公开(公告)日：2008-12-11

申请号：PCT/EP2007/055483

申请日：2007-06-04

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil ,  MERZ, Thomas

Inventor： SHAMAYELI, Khalil ,  MERZ, Thomas

IPC: C11D1/825 ,  C11D3/37

CPC classification number: C11D17/0017 ,  C11D1/72 ,  C11D1/8255 ,  C11D3/3765

Abstract: The invention relates to a liquid detergent concentrate composition comprising an emulsion having an aqueous phase and an oil phase, the composition comprises based on the whole concentrate 1 to 50 wt-% of one or more alkalinity source, 1 to 60 wt-% of a guerbet alcohol ethoxylate of the formula R 1 -(OC 2 H 4 ) n -OH, wherein R 1 is a branched C g to C 20 alkyl group and n is from 2 to 10, 1 to 30 wt-% of a linear alkoxylated fatty alcohol of the formula R 2 -(OC 2 H 4 ) X - (OC 3 H 6 ) y -OH, wherein R 2 is a linear C 10 to C 16 group and x is from 3 to 7 and y is from 3 to 7. 0.01 - 10 wt-% of one or more crosslinked or partly crosslinked polyacrylic acid or polymethacrylic acid or mixtures thereof and the rest up to 100 wt-% is water.

Abstract translation: 本发明涉及一种液体洗涤剂浓缩物组合物，其包含具有水相和油相的乳液，该组合物包含基于整个浓缩物1至50重量％的一种或多种碱度源，1至60重量％的 具有式R1-（OC2H4）n-OH的格伯特醇乙氧基化物，其中R 1是支链C 8至C 20烷基，n是2至10，1至30重量％的式R 2 - （OC2H4）X-（OC3H6）y-OH，其中R2是直链C10至C16基团，x为3-7，y为3-7.0.01-10重量％的一种或多种交联或部分交联 聚丙烯酸或聚甲基丙烯酸或其混合物，其余高达100重量％的是水。

公开(公告)号：WO2007101470A1

公开(公告)日：2007-09-13

申请号：PCT/EP2006/060465

申请日：2006-03-06

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil ,  MERZ, Thomas ,  KNOP, Ralf-Erbo

Inventor： SHAMAYELI, Khalil ,  MERZ, Thomas ,  KNOP, Ralf-Erbo

IPC: C11D3/37 ,  C11D3/02 ,  C11D1/72

CPC classification number: C11D3/044 ,  C11D1/72 ,  C11D3/3765

Abstract: The invention relates to liquid detergent concentrate composition comprising an emulsion having a water phase and an oil phase, the composition comprising 5 - 30 wt-% of one or more alkalinity source 1 - 70 wt-% of a at least one non-ionic surfactant 0.01 - 10 wt-% of one or more crosslinked or partly crosslinked polyacrylic acid or polymethacrylic acid. Furthermore the invention relates to a stable aqueous use solution, comprising a liquid detergent concentrate according to the invention and to a method for washing textiles with the aqueous use solution.

Abstract translation: 本发明涉及包含具有水相和油相的乳液的液体洗涤剂浓缩物组合物，该组合物包含5-30重量％的一种或多种碱度源1-70重量％的至少一种非离子表面活性剂 0.01〜10重量％的一种或多种交联或部分交联的聚丙烯酸或聚甲基丙烯酸。 此外，本发明涉及一种稳定的水性使用溶液，其包含根据本发明的液体洗涤剂浓缩物和用水性使用溶液洗涤纺织品的方法。

公开(公告)号：WO2005118767A1

公开(公告)日：2005-12-15

申请号：PCT/EP2004/050963

申请日：2004-05-28

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil

Inventor： SHAMAYELI, Khalil

IPC: C11D17/00

CPC classification number: C11D3/044 ,  C11D1/722 ,  C11D1/825 ,  C11D3/06 ,  C11D3/08 ,  C11D17/003

Abstract: The present invention refers to a paste-like, thixotropic, alkaline detergent or cleaning concentrate comprising a) at least one first component selected from one or more compounds represented by the general formula (I): R 1 -(OC 2 H 4 ) n -(OC 3 H 6 ) m -OH wherein R 1 represents an unbranched or branched alkyl or alkenyl group having 4 to 8, preferably 5 to 7, carbon atoms, and wherein the sum of the average degree of ethoxylation n and propoxylation m ranges from 1 to 9, preferably from 3 to 7, with one of n and m optionally being 0, and b) at least one second component selected from one or more compounds repre­sented by the general formula (II): R 2 -(OC 2 H 4 ) 0 -(OC 3 H 6 ) p -OH wherein R 2 represents an unbranched or branched alkyl or alkenyl group having 9 to 22, preferably 10 to 16, carbon atoms, and wherein the sum of the average degree of ethoxylation o and propoxylation p is between 1 and 9, preferably between 3 and 7, with one of o or p optionally being 0, the cleaning concentrate exhibiting at 25°C a viscosity of from 80 000 mPas to 250 000 mPas at 5 revolutions per minute and a viscosity of from 20 000 mPas to 80 000 mPas at 50 revolutions per minute, each measured using a Brookfield rotational viscometer (spindle no. 7) under otherwise identical conditions. Moreover, it deals with a stable parent lye containing said concentrate and a method for washing textiles comprising one step in which a parent lye is prepared by diluting said concentrate and in 30 which the waste water accumulated during the whole washing process or parts thereof may be purified using a membrane filtration unit.

Abstract translation: 本发明涉及一种糊状触变性碱性洗涤剂或清洁浓缩物，其包含a）至少一种选自一种或多种由通式（I）表示的化合物的第一组分：R 1 - （OC 2 H 4）n - （OC 3 H 6）m -OH，其中R 1表示具有4至8个，优选5至7个碳原子的无支链或支链烷基或烯基，其中平均乙氧基化度n和丙氧基化m之和m的范围为1 至9，优选3至7，n和m中的任一个任选地为0，以及b）至少一种选自一种或多种由通式（II）表示的化合物的第二组分：R 2 - （OC 2 H 4） 0-（OC 3 H 6）p -OH，其中R 2表示具有9至22个，优选10至16个碳原子的无支链或支链烷基或烯基，其中平均乙氧基化度o和丙氧基化p之和为 在1和9之间，优选3和7之间，其中o或p之一任选地为0，清洁浓缩物表现出 在25℃下，以5转/分钟的粘度为80,000mPas至250,000mPa·s，并且使用Brookfield旋转粘度计（主轴编号）测量的粘度为每分钟50转至20 000mPas至80 000mPas。 7）在其他相同条件下。 此外，它涉及含有所述浓缩物的稳定的母液和洗涤纺织品的方法，其包括一个步骤，其中通过稀释所述浓缩物制备母液碱，以及在整个洗涤过程中积聚的废水或其部分可能为 使用膜过滤单元进行纯化。

公开(公告)号：WO2005118760A1

公开(公告)日：2005-12-15

申请号：PCT/EP2004/050959

申请日：2004-05-28

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil ,  KNOP, Ralf-Erbo

Inventor： SHAMAYELI, Khalil ,  KNOP, Ralf-Erbo

IPC: C11D1/83

CPC classification number: C11D3/2003 ,  C11D1/04 ,  C11D1/72 ,  C11D3/2044 ,  C11D3/2065 ,  C11D3/2068 ,  C11D10/04 ,  C11D10/045 ,  C11D17/003

Abstract: The present invention provides a paste-like cleaning or detergent composition comprising a) a surfactant component comprising a compound of the general formula R 1 -COOM (1), a fatty alcohol alkoxylate and/or an oxo alcohol alkoxylate with an average degree of alkoxylation at least 5; and optionally an anionic surfactant; b) a compound of the general formula R 2 -O-R 3 (II); c) water and/or a compound of the general formula X-CH 2 -(CHY) n -CH 2 -Z (III), provided that at least 2 hydroxyl groups are present; d) an alkalinity source, and e) one or more organic and/or anorganic builders on a non-silicate basis; wherein the composition essentially is free from graying inhibitors on a cellulose basis, silicates and phosphates. Moreover, the present invention relates to a method for washing textiles using said composition, wherein the waste water accumulated during the washing process may be purified by a membrane filtration unit comprising reverse osmosis steps.

Abstract translation: 本发明提供了一种糊状清洁或洗涤剂组合物，其包含a）包含通式R 1 -COOM（1）的化合物，脂肪醇烷氧基化物和/或羰基醇烷氧基化物的表面活性剂组分，其平均度 的烷氧基化至少5; 和任选的阴离子表面活性剂 b）通式为R 2 -O-R 3（II）的化合物; c）水和/或通式X-CH 2 - （CHY）n -CH 2 -Z（III）的化合物，条件是存在至少2个羟基; d）碱性源，和e）非硅酸盐基上的一种或多种有机和/或无机助洗剂; 其中所述组合物基本上不含有基于纤维素的灰化抑制剂，硅酸盐和磷酸盐。 此外，本发明涉及使用所述组合物洗涤纺织品的方法，其中在洗涤过程中积聚的废水可以通过包括反渗透步骤的膜过滤单元来纯化。

公开(公告)号：WO1995009229A1

公开(公告)日：1995-04-06

申请号：PCT/EP1994003122

申请日：1994-09-19

Applicant: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN ,  BEAUJEAN, Hans-Josef ,  MERZ, Thomas ,  HOLZ, Erich ,  HOLDERBAUM, Thomas ,  AMBERG, Günther ,  SHAMAYELI, Khalil ,  MARSCHNER, Michael ,  HARTH, Hubert

Inventor： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN

IPC: C11D10/04

CPC classification number: C11D10/045 ,  C11D1/14 ,  C11D1/22 ,  C11D1/72 ,  C11D1/722 ,  C11D10/04 ,  C11D17/0004

Abstract: In order to prevent the ingredients of pasty washing or cleaning agents from dissociating, both during their production and when they are removed from transport or storage containers, and in order to further increase the storage stability of the paste, washing or cleaning pastes with a viscous structure are produced by using a mixture of storage stable, substantially water-free, free-flowing surface-active agents. This mixture contains 40 % to 70 % by weight of a non-ionic surface-active agent that remains fluid at room temperature and has the general formula R -(OC2H4)n-OH, in which R stands for an alkyl or alkenyl residue with 20 to 20 C atoms and mean ethoxylation values n from 1 to 8, 20 % to 50 % by weight of a non-ionic surface-active agent that remains fluid at room temperature and has the general formula R -(OC2H4)r-(OC3H6)p)-OH, in which R stands for an alkyl or alkenyl residue with 10 to 20 C atoms, mean ethoxylation values r from 2 to 8 and mean propoxylation values p from 1 to 6, and 1 % to 10 % by weight of a C10-C22-carboxylic acid and/or its alkali salt. These agents have such a high viscosity when they are not-subjected to shearing forces that they do not flow freely under gravity at room temperature, but when they are subjected to shearing forces they show a clearly reduced viscosity, become free-flowing and may be pumped under gravity.

Abstract translation: 另外，在浆料的成分的糊状洗涤剂或清洁剂分层都应该在制造过程中以及从运输或供给容器和浆料的贮存稳定性的去除的条件下进一步增加被避免。 这基本上是由生产假塑性洗涤剂或清洗剂糊剂的使用含有.- 40重量％的储存稳定的基本上不含水的，可流动的表面活性剂混合物在通式R <的室温下为液态的非离子表面活性剂1来实现，特别是70重量％ > - （OC 2 H 4）N-OH，其中R <1>是具有10至20个碳原子，并且平均乙氧基化度的n可以假设为1〜8重量％至20重量第50值的烷基或烯基 - ％的通式为R的室温下为液态的非离子表面活性剂<2> - （OC 2 H 4）R（OC3H6）p-OH，<2>是烷基或链烯基团，具有在R，平均乙氧基化度为10〜20个碳原子 ř从C10的2至8和丙氧基化p的平均度可以假设值1至6，和1重量％到10重量％的值至C 22羧酸和/或碱金属盐。 这样的装置包括但剪切力这样的高粘度使得它们在室温下不是可流动重力的作用下，具有在剪切但低得多的粘度，并且可以重力可流动和可泵送的作用下是接着的动作。

公开(公告)号：WO1992005235A1

公开(公告)日：1992-04-02

申请号：PCT/EP1991001722

申请日：1991-09-10

Applicant: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN ,  MERZ, Thomas ,  SHAMAYELI, Khalil ,  KUHLMANN, Werner

Inventor： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN

IPC: C11D01/722

CPC classification number: C11D1/8255 ,  C11D1/72 ,  C11D1/722

Abstract: Disclosed is a non-ionic liquid surfactant combination which, in spite of the fact that it does not contain added solvent, shows no tendency to separate over a wide temperature range from -10 to +40 °C and can be measured out easily, without any significant change in viscosity at various temperatures. The surfactant combination contains 20-50 % by wt. of an ethoxylated primary C12-C15 fatty alcohol with an average of 2-7 ethylene glycol ether groups, 20-50 % by wt. of an alkoxylated primary C12-C15 fatty acid with an average of 3-7 ethylene glycol ether groups and 2-8 propylene glycol ether groups, 5-50 % by wt. of a mixture of primary linear C12-C15 fatty alcohols and branched-chain C12-C15 fatty alcohols, with a methyl group in the 2-position, with an average of 2-8 ethylene glycol groups and, optionally, up to 20 % by wt. of water.

公开(公告)号：WO2008110205A1

公开(公告)日：2008-09-18

申请号：PCT/EP2007/052313

申请日：2007-03-12

Applicant: ECOLAB INC. ,  SHAMAYELI, Khalil ,  MERZ, Thomas ,  KNOP, Ralf-Erbo ,  BEISEMANN, Peter

Inventor： SHAMAYELI, Khalil ,  MERZ, Thomas ,  KNOP, Ralf-Erbo ,  BEISEMANN, Peter

IPC: C11D1/83 ,  C11D10/04 ,  C11D3/20 ,  C11D11/00 ,  C11D17/00 ,  C11D3/37 ,  C11D3/00 ,  C11D1/04 ,  C11D1/72 ,  C11D1/722

CPC classification number: C11D1/83 ,  C11D1/04 ,  C11D1/72 ,  C11D1/722 ,  C11D1/8305 ,  C11D3/0026 ,  C11D3/2013 ,  C11D3/202 ,  C11D3/2031 ,  C11D3/2041 ,  C11D3/2044 ,  C11D3/2048 ,  C11D3/2068 ,  C11D3/373 ,  C11D3/3738 ,  C11D10/04 ,  C11D10/045 ,  C11D11/0076 ,  C11D17/003

Abstract: The invention relates to a paste-like cleaning or detergent composition comprising a) a surfactant component comprising a compound of the general formula R 1 -COOM (I), wherein R 1 represents a linear or branched alkyl- or alkenyl residue with 8 to 22 carbon atoms and M represents an alkali metal ion; a fatty alcohol alkoxylate and/or an oxo alcohol alkoxylate with 8 to 22 carbon atoms and an average degree of alkoxylation of at least 5; and optionally an anionic surfactant; b) a compound of the general formula R2-O-R3 (II), wherein R2 represents a linear or branched alkyl or alkenyl residue with 8 to 22 carbon atoms and R3 represents hydrogen or a linear or branched alkyl residue with 1 to 8 carbon atoms; c) water and/or a compound of the general formula X-CH2-(CHY)n-CH2-Z (Hi), d) wherein n is an integer of from 0 to 2 and X, Y and Z independently symbolize hydrogen or a hydroxyl group provided that at least 2 hydroxyl groups are present; e) one or more alkalinity sources f) one or more organic and/or anorganic builders on a non-silicate basis; g) a defoamer comprising crosslinked or partly crosslinked polysiloxane having a three dimensional structure.

Abstract translation: 本发明涉及一种糊状清洁或洗涤剂组合物，其包含a）包含通式为R 1 -COOM（I）的化合物的表面活性剂组分，其中R 1， 表示具有8至22个碳原子的直链或支链烷基或烯基残基，M表示碱金属离子; 具有8至22个碳原子的平均烷氧基化度至少为5的脂肪醇烷氧基化物和/或羰基合成醇烷氧基化物; 和任选的阴离子表面活性剂; b）通式为R 2 -O-R 3（II）的化合物，其中R 2表示具有8至22个碳原子的直链或支链烷基或链烯基，R 3表示氢或具有1至8个碳的直链或支链烷基 原子; c）水和/或通式X-CH 2 - （CHY）n -CH 2 -Z（Hi）的化合物，d）其中n是0-2的整数，X，Y和Z独立地表示氢或 提供存在至少2个羟基的羟基; e）一种或多种碱度源f）非硅酸盐基上的一种或多种有机和/或无机助洗剂; g）包含具有三维结构的交联或部分交联的聚硅氧烷的消泡剂。

公开(公告)号：WO2005001011A1

公开(公告)日：2005-01-06

申请号：PCT/EP2004/051177

申请日：2004-06-21

Applicant: ECOLAB INC. ,  GRAUS, Stephanie ,  HEIN, Andrea ,  MERZ, Thomas ,  SCHEGETZ, Renate ,  SHAMAYELI, Khalil

Inventor： GRAUS, Stephanie ,  HEIN, Andrea ,  MERZ, Thomas ,  SCHEGETZ, Renate ,  SHAMAYELI, Khalil

IPC: C11D1/83

CPC classification number: C11D3/48 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  C11D1/8255 ,  C11D1/83 ,  C11D1/94

Abstract: The present invention refers to a concentrate for use as disinfectant and/or detergent comprising: a) 5 to 90 percent by weight of at least one nonionic surfactant selected from the group consisting of compounds represented by the aa) general formula (1) R 1 -(OC 2 H 4 )n-(OC 3 H 6 ) m -OH (1) whereby R 1 is an unbranched or branched alkyl or alkenyl residue having 5 to 17 carbon atoms, and the sum of the median degree of ethoxylation n and the median degree of propoxylation m is of from 0,3 to 10, ab) general formula (2) R 2- (OC 2 H 4 ) o -OH (2) whereby R 2 is an unbranched or branched alkyl or alkenyl residue having 5 to 17 carbon atoms, and o is of from 0 to 10, ac) general formula (3) R 3 -(OC 3 H 6 ) p -OH (3) whereby R 3 is an unbranched or branched alkyl or alkenyl residue having 5 to 17 carbon atoms, and p is of from 0 to 10, and mixtures thereof, and b) 5 to 90 percent by weight of at least one amphoteric and/or anionic surfactant, whereby optionally the balance is water, the sum of all compounds present in the concentrate is 100 percent by weight, and the concentrate has a viscosity of from 100 to 20.000 mPa s (23 0 C, Brookfield viscosity, spindle 2) at 20 revolutions per minute of the spindle and to a composition comprising the concentrate and a suitable diluent.

Abstract translation: 本发明涉及用作消毒剂和/或洗涤剂的浓缩物，其包含：a）5-90重量％的至少一种非离子表面活性剂，其选自由aa）通式（1）表示的化合物， （OC 2 H 4）n - （OC 3 H 6）m -OH（1），其中R 1是具有5至17个碳原子的无支链或支链烷基或烯基残基，并且中间乙氧基化度n和 丙氧基化的中位数m为0.3〜10，ab）通式（2）R 2 - （OC 2 H 4）o -OH（2），其中R 2为无支链或支链的烷基或烯基残基， 5〜17个碳原子，o为0〜10，ac）通式（3）R 3 - （OC 3 H 6）p -OH（3）其中R 3为无支链或支链烷基或链烯基 具有5至17个碳原子，p为0至10，以及它们的混合物，以及b）5至90重量％的至少一种两性和/或阴离子表面活性剂，其中任选的余量为水，总和 所有的compou 浓缩物中存在的nds为100重量％，并且浓缩物在纺锤每分钟20转时具有100至20.000mPa·s（23℃，Brookfield粘度，纺锤体2）的粘度，并且包含 浓缩物和合适的稀释剂。