公开(公告)号：WO9859105A3

公开(公告)日：1999-06-10

申请号：PCT/US9812342

申请日：1998-06-12

Applicant: ALLIED SIGNAL INC

Inventor： NALEWAJEK DAVID ,  STACHURA LEONARD M ,  ZYHOWSKI GARY J

IPC: C07F9/09 ,  C07F9/12 ,  C11D1/00 ,  C11D3/24 ,  D06L1/04 ,  C07D213/20 ,  C09K3/18 ,  C11D3/43

CPC classification number: D06L1/04 ,  C07F9/098 ,  C07F9/12 ,  C11D1/006 ,  C11D3/24 ,  C11D3/245 ,  C11D3/43

Abstract: The invention provides a fluorinated surfactant for use with halocarbon and hydrofluoroether solvents. Additionally, the invention provides drying, dry cleaning, and soil repellency compositions containing a halocarbon or hydrofluoroether and a fluorinated surfactant.

Abstract translation: 本发明提供一种与卤代烃和氢氟醚溶剂一起使用的氟化表面活性剂。 此外，本发明提供了含有卤代烃或氢氟醚和氟化表面活性剂的干燥，干洗和防污组合物。

公开(公告)号：WO0043338A3

公开(公告)日：2000-12-14

申请号：PCT/US0001800

申请日：2000-01-24

Applicant: ALLIED SIGNAL INC

Inventor： BRADLEY DAVID E ,  BENSON KEVIN ,  NALEWAJEK DAVID ,  THENAPPAN ALAGAPPAN

IPC: C07C17/20 ,  C07C19/08 ,  C07C17/08 ,  C07C17/158

CPC classification number: C07C17/206 ,  C07C19/08 ,  C07C19/10

Abstract: A process for producing a fluorinated organic compound comprising: (a) reacting an organic starting material with hydrogen fluoride in the presence of a fluorination catalyst and an HFC reaction solvent to produce a product stream containing the fluorinated organic compound wherein the reaction solvent has a boiling point higher than that of the fluorinated organic compound; and (b) recovering the fluorinated organic compound from the product stream.

Abstract translation: 一种氟化有机化合物的制造方法，其特征在于，包括：（a）在氟化催化剂和HFC反应溶剂的存在下，使有机原料与氟化氢反应，制造含有氟化有机化合物的产物流，其中，反应溶剂为沸点 高于氟化有机化合物; 和（b）从产物流中回收氟化有机化合物。

公开(公告)号：WO8910327A3

公开(公告)日：1989-12-14

申请号：PCT/US8901081

申请日：1989-03-16

Applicant: ALLIED SIGNAL INC

Inventor： NALEWAJEK DAVID

IPC: C01B9/02 ,  C01B9/08 ,  C01B31/00 ,  C01B31/30 ,  H01M4/58 ,  H01M4/583

CPC classification number: H01M4/583 ,  C01B32/10 ,  H01M4/5835

Abstract: Direct fluorination of the intermediate (CyFxClz)n (x 0.7, y 1 and z 0.1) in the absence of chlorine produces, either carbon fluoride CFx (x 1) or carbon fluoride chloride (CyFxClz)n (x 0.9, y = 1, z 0.01) in as brief a period as 1 hour.

公开(公告)号：WO8910328A3

公开(公告)日：1989-11-30

申请号：PCT/US8901184

申请日：1989-03-23

Applicant: ALLIED SIGNAL INC

Inventor： NALEWAJEK DAVID

IPC: C01B31/00

CPC classification number: C01B32/22 ,  C01B32/10

Abstract: The preparation of carbon fluoride and carbon fluoride chloride from a graphite intercalate is described. Treatment of group V-A pentahalide intercalates of graphite with fluorine or fluorine/chlorine gas mixtures at a temperature of about 300°C results in the production of highly fluorinated CFx: x 1 or (CyFxClz)n: x 1.0, z 0.1, y = 1. In the process, carbon fluoride or carbon fluoride chloride can be prepared from a highly ordered graphitic carbon at a temperature substantially lower than that of the decomposition temperature of the product, CFx or (CyFxClz)n. In particular, carbon fluoride or carbon fluoride chloride is prepared from a group V-A pentahalogen intercalate and fluorine gas or fluorine/chlorine gas mixtures at temperatures in the order of 250-300°C. The process provides a controlled, reproducible method of preparing a carbon fluoride or carbon fluoride chloride material from a graphite feedstock having fluorine-to-carbon ratios of 1 or greater from the pentahalide compound and fluorine gas or fluorine/chlorine gas mixtures at temperatures substantially removed from the decomposition temperature of the final product, thus eliminating the potential of an explosive reaction or the formation of unstable by-products.