POLYMERS EXHIBITING NONLINEAR OPTICAL PROPERTIES
    2.
    发明申请
    POLYMERS EXHIBITING NONLINEAR OPTICAL PROPERTIES 审中-公开
    聚合物展示非线性光学性质

    公开(公告)号:WO1994020881A1

    公开(公告)日:1994-09-15

    申请号:PCT/US1994002424

    申请日:1994-03-07

    Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electron donating group substituted to different phenyl rings of the fluorene moiety (I), wherein: A is an electron withdrawing substituent; D is an electron donating substituent; R and R are the same or different and are divalent conjugated organic or inorganic moiety; m, n and p are the same or different at each occurrence and are integers from 1 to 4 wherein the sum of p and n, as well as the sum of p and m, is equal to 4; k and o are the same or different at each occurrence and are integers from 1 to 5 wherein the sum of k and o is equal to 5; i and j are the same or different and are 0 or an integer from 1 to 5; R is the same or different at each occurrence and is any substituent which does not adversely affect the non-linear optical properties of the polymer unduly; x and y are the same or different and are 0 or an integer from 1 to about 10; T and Z chosen to have general structures of polyesters, polycarbonates, polyamides, polyethers, polyurethanes, polyimides, epoxyresins.

    Abstract translation: 本发明涉及具有非线性光学性质的聚合物,该聚合物包括具有至少一个电子接受基团的芴部分和至少一个被芴部分(I)的不同苯环取代的给电子基团,其中:A是吸电子 取代基; D是给电子取代基; R 1和R 2相同或不同,为二价共轭有机或无机部分; m,n和p在每次出现时相同或不同,为1〜4的整数,其中p和n之和以及p和m之和等于4; k和o在每次出现时相同或不同,并且是1至5的整数,其中k和o的和等于5; i和j相同或不同,为0或1至5的整数; R 3在每次出现时相同或不同,是不适当地不利地影响聚合物的非线性光学性质的任何取代基; x和y相同或不同,为0或1〜10的整数; 选择T和Z具有聚酯,聚碳酸酯,聚酰胺,聚醚,聚氨酯,聚酰亚胺,环氧树脂的一般结构。

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