公开(公告)号：WO2011038081A1

公开(公告)日：2011-03-31

申请号：PCT/US2010/049945

申请日：2010-09-23

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  YACKABONIS, William E.

Inventor： VAN HORN, Brett L. ,  YACKABONIS, William E.

IPC: A61K9/70 ,  C12N11/04

CPC classification number: C08J9/127 ,  C08J2203/02 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/142 ,  C08J2203/146 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2203/184 ,  C08J2300/16 ,  C08J2303/02 ,  C08J2329/04 ,  C08J2367/04

Abstract: The invention provides a blowing agent composition and method of making the same comprising mixing carbon dioxide and a co-blowing agent or a blowing agent selected from the group consisting of hydrofluorocarbons, hydrochlorofluorocarbons, hydrofluoroethers, hydrofluoroolefins, hydrochlorofluoroolefins, hydrobromofluoroolefins, hydrofluoroketones, hydrochloroolefins, fluoroiodocarbons, alkyl esters, water, and mixtures thereof. Also provided is a method of making a low density foam using the blowing agent composition, and a biodegradable or biorenewable foam formed from a foamable biodegradable or biorenewable resin composition and the blowing agent composition.

Abstract translation: 本发明提供了一种发泡剂组合物及其制造方法，包括混合二氧化碳和共发泡剂或选自氢氟烃，氢氯氟烃，氢氟醚，氢氟烯烃，氢氯氟烯烃，氢氟氟烯烃，氢氟烯酮，氢氯代烯烃，氟代烃 ，烷基酯，水及其混合物。 还提供了使用发泡剂组合物制造低密度泡沫的方法，以及由可发泡的可生物降解或生物可再生的树脂组合物和发泡剂组合物形成的可生物降解的或生物可再生的泡沫。

公开(公告)号：WO2009114398A1

公开(公告)日：2009-09-17

申请号：PCT/US2009/036268

申请日：2009-03-06

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  BONNET, Philippe

Inventor： VAN HORN, Brett L. ,  BONNET, Philippe

IPC: C07C19/10

CPC classification number: C09K5/044 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/112 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/32 ,  C09K2205/40 ,  C09K2205/41 ,  C10M171/008 ,  C10M2203/065 ,  C10M2203/1006 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2205/223 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/1033 ,  C10N2040/30 ,  C10N2220/301 ,  C10N2220/302 ,  C10N2220/303 ,  C10N2220/305 ,  C10N2240/30 ,  F25B1/053 ,  F25B1/10 ,  F25B9/006 ,  F25B31/002 ,  F25B2339/047 ,  F25B2400/18

Abstract: This invention relates to the use of chloro-trifluoropropenes as refrigerants in negative-pressure liquid chillers and methods of replacing an existing refrigerant in a chiller with chloro-trifluoropropenes. The chloro-trifluoropropenes, particularly 1-chloro-3,3,3-trifluoropropene, have high efficiency and unexpectedly high capacity in liquid chiller applications and are useful as more environmentally sustainable refrigerants for such applications, including the replacement of R-123 and R-11.

Abstract translation: 本发明涉及氯代 - 三氟丙烯作为制冷剂在负压液体制冷机中的应用以及用氯 - 三氟丙烯代替冷却器中的现有制冷剂的方法。 氯 - 三氟丙烯，特别是1-氯-3,3,3-三氟丙烯，在液体冷却器应用中具有高效率和出人意料的高容量，并且可用作这种应用的更环保的可持续制冷剂，包括更换R-123和R -11。

公开(公告)号：WO2011022260A1

公开(公告)日：2011-02-24

申请号：PCT/US2010/045104

申请日：2010-08-11

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  BONNET, Philippe ,  ABBAS, Laurent

Inventor： VAN HORN, Brett L. ,  BONNET, Philippe ,  ABBAS, Laurent

IPC: C07C19/08 ,  C07C21/18

CPC classification number: C09K5/045 ,  C08J9/144 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C09K3/30 ,  C09K2205/122

Abstract: The present invention relates to azeotrope and azeotrope-like compositions comprised of 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) and 1,1,1,2,3-pentafluoropropane (HFC-245eb), and uses thereof.

Abstract translation: 本发明涉及由1-氯-3,3,3-三氟丙烯（HCFO-1233zd）和1,1,1,2,3-五氟丙烷（HFC-245eb）组成的共沸物和类共沸组合物及其用途 。

公开(公告)号：WO2008121783A1

公开(公告)日：2008-10-09

申请号：PCT/US2008/058600

申请日：2008-03-28

Applicant: ARKEMA INC. ,  CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  VAN HORN, Brett L. ,  COSTA, Joseph S.

Inventor： CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  VAN HORN, Brett L. ,  COSTA, Joseph S.

IPC: C08J9/00 ,  C08J9/14

CPC classification number: C08J9/144 ,  C08J9/127 ,  C08J9/149 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract translation: 公开了一种用于热固性泡沫的发泡剂。 发泡剂主要是氢氯氟烯烃（HCFO）HFCO-1233zd单独或与氢氟烯烃（HFO），氢氟烃（HFC），氢氯氟烯烃（HCFO），烃类的组合的反式异构体。 发泡剂在制造热固性泡沫时作为发泡剂是有效的。

公开(公告)号：WO2009108547A1

公开(公告)日：2009-09-03

申请号：PCT/US2009/034348

申请日：2009-02-18

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  BERTELO, Christopher A. ,  SCHMIDT, Scott C. ,  MACY, Noah E. ,  PAPAKONSTANTOPOULOS, George J.

Inventor： VAN HORN, Brett L. ,  BERTELO, Christopher A. ,  SCHMIDT, Scott C. ,  MACY, Noah E. ,  PAPAKONSTANTOPOULOS, George J.

IPC: C09K5/00

CPC classification number: C09K5/045 ,  C09K2205/12 ,  C09K2205/126 ,  C10M171/008 ,  C10M2203/065 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2203/1045 ,  C10M2203/1065 ,  C10M2205/0285 ,  C10M2205/143 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/084 ,  C10M2209/102 ,  C10M2209/1033 ,  C10M2209/104 ,  C10N2220/021 ,  C10N2220/302 ,  C10N2220/303 ,  C10N2230/70 ,  C10N2240/30

Abstract: The present invention relastes to fluorine free polymeric oil-return agents that increase the miscibility of lubricants such as mineral oils and/or oxygenated lubricants with refrigerants in order to improve oil return and system performance of refrigeration systems. It was discovered that fluorine free block copolymers having a block compatible with the oil phase, and at least one block compatible with the refrigerant phase can effectively compatibilize lubricanting oils with HFC and HFO refrigerants.

Abstract translation: 本发明涉及无氟聚合物回油剂，其增加润滑剂如矿物油和/或含氧润滑剂与制冷剂的混溶性，以改善制冷系统的回油和系统性能。 发现具有与油相相容的嵌段的无氟嵌段共聚物和与制冷剂相相容的至少一个嵌段可以有效地使润滑油与HFC和HFO制冷剂相容。

公开(公告)号：WO2008121779A1

公开(公告)日：2008-10-09

申请号：PCT/US2008/058596

申请日：2008-03-28

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  ELSHEIKH, Maher Y. ,  CHEN, Benjamin B. ,  BONNET, Philippe

Inventor： VAN HORN, Brett L. ,  ELSHEIKH, Maher Y. ,  CHEN, Benjamin B. ,  BONNET, Philippe

IPC: C08J9/00 ,  C08J9/14

CPC classification number: C08J9/146 ,  C08J9/149 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2203/202 ,  C08J2205/05 ,  Y10T428/249953

Abstract: The present invention relates to blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3, 3,3-trifluoropropene (HCFO-1233zd), particularly the trans- isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.

Abstract translation: 本发明涉及包含用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物。 本发明的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），特别是反式异构体2-氯-3,3,3-三氟丙烯（HCFO -1233xf），二氯氟化丙烯及其混合物。 本发明的发泡剂组合物与包括二氧化碳，气氛气体，氢氟烃（HFC），氢氟烯烃（HFO），烷烃，氢氟醚（HFE））及其混合物的助熔剂一起使用。 在本发明中用作起泡剂的优选的HFCs包括但不限于1,1,1,2-四氟乙烷（HFC-134a），1,1-二氟乙烷（HFC-152a），1,1,1-三氟乙烷 三氟乙烷（HFC-143a），五氟乙烷（HFC-125），二氟甲烷（HFC-32）。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。

公开(公告)号：WO2015126662A1

公开(公告)日：2015-08-27

申请号：PCT/US2015/015139

申请日：2015-02-10

Applicant: ARKEMA INC.

Inventor： ELSHEIKH, Maher Y. ,  CHEN, Benjamin Bin ,  VAN HORN, Brett L. ,  ABBAS, Laurent ,  SESHADRI, Sri R.

IPC: C09K5/04 ,  C07C21/04

CPC classification number: C09K5/044 ,  A62D1/0057 ,  C08F2/42 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C08J2325/06 ,  C08J2375/04 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C11D3/0084 ,  C11D7/247 ,  C11D7/261 ,  C11D7/263 ,  C11D7/5018

Abstract: Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.

Abstract translation: 公开了氢氟烯烃和/或氢氯氟烯烃与稳定剂的组合，其中稳定剂使储存，处理和使用期间氢氟烯烃和氢氯氟烯烃的降解最小化，但允许大气降解。 这些组合表现出低或零臭氧消耗潜能和较低的全球变暖潜能，使其成为氯氟烃和氢氟碳化物的替代品。 本发明的组合包括与选自自由基清除剂，酸清除剂，除氧剂，聚合抑制剂及其组合的稳定剂或稳定剂组合的氢氟烯烃和/或氢氯氟烯烃。

公开(公告)号：WO2012158870A1

公开(公告)日：2012-11-22

申请号：PCT/US2012/038264

申请日：2012-05-17

Applicant: ARKEMA INC. ,  KENNOY, Debra H. ,  VAN HORN, Brett L. ,  CHEN, Benjamin Bin ,  BONNET, Philippe

Inventor： KENNOY, Debra H. ,  VAN HORN, Brett L. ,  CHEN, Benjamin Bin ,  BONNET, Philippe

IPC: C07C21/18

CPC classification number: A62D1/0028 ,  C08J9/144 ,  C08J2203/162 ,  C08J2203/202 ,  C09K3/00 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K2205/122 ,  C09K2205/126 ,  C10M171/008 ,  C10N2220/30 ,  C10N2220/301 ,  C10N2230/00 ,  C11D7/30 ,  C11D7/5018 ,  C11D7/5054

Abstract: The present invention relates to non-flammable compositions comprising chlorotrifluoropropene with reduced risk of flammability which are useful as refrigerants, heat transfer fluids, solvents, cleaners, blowing agents, aerosols, extraction fluids, and the like.

Abstract translation: 本发明涉及包含氯三氟丙烯的不可燃组合物，其具有降低的可燃性的风险，其可用作制冷剂，传热流体，溶剂，清洁剂，发泡剂，气溶胶，萃取液等。

公开(公告)号：WO2012006206A3

公开(公告)日：2012-01-12

申请号：PCT/US2011/042520

申请日：2011-06-30

Applicant: ARKEMA INC. ,  BOUSSAND, Beatrice ,  VAN HORN, Brett L.

Inventor： BOUSSAND, Beatrice ,  VAN HORN, Brett L.

IPC: C09K5/02

Abstract: The present invention relates to heat transfer fluid combinations for use in refrigeration, heat transfer, heat pump, and air conditioning applications. More particularly, the present invention relates to heat transfer fluid combinations of 1,3,3,3-tetrafluoropropene and polyol ester (POE) oils which are useful in refrigeration, heat transfer, heat pump, and air conditioning systems.

公开(公告)号：WO2009151669A1

公开(公告)日：2009-12-17

申请号：PCT/US2009/036266

申请日：2009-03-06

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  CROOKER, Richard M.

Inventor： VAN HORN, Brett L. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  CROOKER, Richard M.

IPC: C09K5/00

CPC classification number: C09K5/044 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/112 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/32 ,  C09K2205/40 ,  C09K2205/41 ,  C10M171/008 ,  C10M2203/065 ,  C10M2203/1006 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2205/223 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/1033 ,  C10N2040/30 ,  C10N2220/301 ,  C10N2220/302 ,  C10N2220/303 ,  C10N2220/305 ,  C10N2240/30 ,  F25B1/053 ,  F25B1/10 ,  F25B9/006 ,  F25B31/002 ,  F25B2339/047 ,  F25B2400/18

Abstract: The invention relates to heat transfer agents and heat transfer compositions containing hydrocarbon lubricating oils and halogentaed alkene heat transfer fluid that promote oil flow and provide for improved oil return. The heat transfer compositions are useful in various heat transfer systems such as refrigeration, cooling, air conditioning, chiller operations.

Abstract translation: 本发明涉及含有烃润滑油和卤代烯烃传热流体的传热剂和传热组合物，其促进油流并提供改善的回油。 传热组合物可用于各种传热系统，例如制冷，冷却，空调，冷冻机操作。