公开(公告)号：WO1995010581A1

公开(公告)日：1995-04-20

申请号：PCT/EP1994003259

申请日：1994-09-30

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： BASF AKTIENGESELLSCHAFT ,  DYLLICK-BRENZINGER, Rainer ,  RAULFS, Friedrich-Wilhelm ,  SCHLÖSSER, Ulrike ,  BECK, Karin, Heidrun ,  SCHOLZ, Gerhard

IPC: C10L01/00

CPC classification number: C09B29/12 ,  C09B29/26 ,  C09B31/062 ,  C10L1/003 ,  C10L1/226 ,  C10M171/007 ,  G01N33/2882

Abstract: A process for detecting marked mineral oils by treating the marked mineral oil with an extracting agent containing water, a solvent and a base, in which use is made as the marking agent of an azo dye of formula (I), in which ring A may be benzo-anellated and l is 1 or 2, m is 1 to 4, X is hydrogen, C1-C4-alkyl, cyano, nitro or possibly substituted phenylazo; X is hydrogen, C1-C4-alkyl, cyano, nitro, C1-C4-alkoxy or C1-C16-alkoxy carbonyl; X is hydrogen, C1-C4-alkyl, cyano or C1-C16-alkoxy carbonyl and X is hydrogen, hydroxy, possibly substituted C1-C8-alkyl, C1-C4-alkoxy, amino, C1-C4-dialkyl amino or possibly substituted C1-C16-monoalkylamino. A partially or completely water-miscible organic solvent is used as the solvent and the base is an alkaline or alkaline earth hydroxide, an alkali carbonate or a quaternary ammonium hydroxide. The invention also relates to the use of azo dyes as marking agents for mineral oils and novel azo dyes.

Abstract translation: 通过用萃取剂包括水，溶剂和碱处理所标记的矿物油，使用作为标记的式（I）的偶氮染料，其中环A可以被苯并稠合和升1或2所述的检测标记的矿物油的方法， m为1〜4，X <1>为氢，C1-C4烷基，氰基，硝基或任选取代的苯偶氮基，X <2>为氢，C1-C4烷基，氰基，硝基，C1-C4烷氧基或C1-C16 烷氧基羰基，X <3>为氢，C1-C4烷基，氰基，或C1-C16烷氧羰基，且X <4>是氢，羟基，任选取代的C1-C8烷基，C1-C4烷氧基，氨基，C1-C4 意味着二烷基氨基，或任选取代的C1-C16-单烷基氨基，作为溶剂中的部分或完全与水混溶的有机溶剂和作为碱的碱金属或碱土金属氢氧化物，碱金属碳酸盐或氢氧化季铵，使用偶氮染料作为Markierungsmit的 电话为矿物油和新颖偶氮染料。