公开(公告)号：WO2017218879A1

公开(公告)日：2017-12-21

申请号：PCT/US2017/037853

申请日：2017-06-16

Applicant: BASF CORPORATION

Inventor： MCGUIRE, Robert ,  SMITH, Gary, M. ,  YILMAZ, Bilge ,  SERNEELS, Sven

IPC: C10G11/05 ,  B01J37/00 ,  B01J29/08

Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina- containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 A. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.

Abstract translation: 提供了一种在催化裂化过程中使镍和钒钝化的沸石流体催化裂化催化剂。 沸石流体催化裂化催化剂包括从含偏高岭土的煅烧微球体原位结晶的Y-八面沸石。 沸石流化催化裂化催化剂还包括通过煅烧含有偏高岭土的煅烧微球中包含的可分散结晶勃姆石和高岭土而获得的含氧化铝基质，其中可分散结晶勃姆石的微晶尺寸小于500埃。还提供了 是一种减少污染物焦炭和氢气产量的方法，以及一种催化裂化重质烃原料的方法。