公开(公告)号：WO2015094922A1

公开(公告)日：2015-06-25

申请号：PCT/US2014/069816

申请日：2014-12-11

Applicant: BASF CORPORATION

Inventor： SMITH, Gary, M. ,  MCGUIRE, Robert ,  YILMAZ, Bilge

IPC: B01J29/82 ,  B01J29/89 ,  C10G47/20 ,  C10G49/02

CPC classification number: B01J29/146 ,  B01J21/04 ,  B01J21/16 ,  B01J23/8472 ,  B01J29/088 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/28 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/36 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise catalytic microspheres containing a zeolite, a non-zeolitic component, and a rare earth component. The microspheres are modified with phosphorus. The FCC catalyst composition can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有沸石，非沸石组分和稀土组分的催化微球。 微球用磷改性。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油原料，导致较低的氢气和焦炭产率。

公开(公告)号：WO2015094908A1

公开(公告)日：2015-06-25

申请号：PCT/US2014/069771

申请日：2014-12-11

Applicant: BASF CORPORATION

Inventor： McGUIRE, Robert ,  SMITH, Gary, M. ,  YILMAZ, Bilge

IPC: B01J21/02 ,  B01J29/06 ,  C10G11/05 ,  C10G25/03

CPC classification number: B01J29/088 ,  B01J21/02 ,  B01J21/04 ,  B01J21/16 ,  B01J23/755 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/04 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/26 ,  C10G11/04 ,  C10G11/05 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles containing a non-zeolitic component and one or more boron oxide components. In embodiments, the FCC catalyst composition contains a zeolite component and optionally a rare earth component and a transition alumina. FCC catalytic compositions may comprise a first particle type containing one or more boron oxide components and a first matrix component mixed with a second particle type containing a second matrix component, and a zeolite. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含含有非沸石组分和一种或多种氧化硼组分的颗粒。 在实施方案中，FCC催化剂组合物含有沸石组分和任选的稀土组分和过渡氧化铝。 FCC催化组合物可以包含含有一种或多种氧化硼组分的第一颗粒类型和与含有第二种基质组分的第二种颗粒类型和沸石混合的第一种基质组分。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油进料，导致较低的氢气和焦炭产率。

公开(公告)号：WO2017218879A1

公开(公告)日：2017-12-21

申请号：PCT/US2017/037853

申请日：2017-06-16

Applicant: BASF CORPORATION

Inventor： MCGUIRE, Robert ,  SMITH, Gary, M. ,  YILMAZ, Bilge ,  SERNEELS, Sven

IPC: C10G11/05 ,  B01J37/00 ,  B01J29/08

Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina- containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 A. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.

Abstract translation: 提供了一种在催化裂化过程中使镍和钒钝化的沸石流体催化裂化催化剂。 沸石流体催化裂化催化剂包括从含偏高岭土的煅烧微球体原位结晶的Y-八面沸石。 沸石流化催化裂化催化剂还包括通过煅烧含有偏高岭土的煅烧微球中包含的可分散结晶勃姆石和高岭土而获得的含氧化铝基质，其中可分散结晶勃姆石的微晶尺寸小于500埃。还提供了 是一种减少污染物焦炭和氢气产量的方法，以及一种催化裂化重质烃原料的方法。

公开(公告)号：WO2022040303A1

公开(公告)日：2022-02-24

申请号：PCT/US2021/046489

申请日：2021-08-18

Applicant: BASF CORPORATION

Inventor： DE SILVA, Wathudura, Indika Namal ,  STOCKWELL, David, M. ,  SMITH, Gary, M. ,  KOMVOKIS, Vasileios ,  YILMAZ, Bilge

IPC: B01J21/12 ,  B01J21/16 ,  B01J29/89

Abstract: Disclosed herein is a fluid catalyst cracking (FCC) catalyst composition that includes a first component and a second component. The first component includes zeolite Y and a first matrix that includes a metal passivating constituent. The second component includes beta zeolite and a second matrix. Also disclosed herein are methods of preparing the FCC catalyst composition and method of using the FCC catalyst composition.

公开(公告)号：WO2015094920A1

公开(公告)日：2015-06-25

申请号：PCT/US2014/069805

申请日：2014-12-11

Applicant: BASF CORPORATION

Inventor： SMITH, Gary, M. ,  McGUIRE, Robert ,  YILMAZ, Bllge

IPC: B01J29/06 ,  B01J29/82 ,  B01J21/02 ,  B01J27/16 ,  C10G11/05 ,  C10G25/03

CPC classification number: C10G11/04 ,  B01J21/02 ,  B01J21/16 ,  B01J29/06 ,  B01J29/061 ,  B01J29/088 ,  B01J35/0006 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/64 ,  C10G11/18

Abstract: Described are fluid catalytic cracking (FCC) compositions, methods of manufacture and use. FCC catalyst compositions comprise particles first particle type comprising one or more boron oxide components and a first matrix component and a second particle type having a composition different from the first particle type, the second particle type comprising a second matrix component, a phosphorus component and 20 % to 95 % by weight of a zeolite component. The FCC catalyst compositions can be used to crack hydrocarbon feeds, particularly resid feeds containing high V and Ni, resulting in lower hydrogen and coke yields.

Abstract translation: 描述了流化催化裂化（FCC）组合物，制造和使用方法。 FCC催化剂组合物包含包含一种或多种氧化硼组分的颗粒第一颗粒类型和具有不同于第一颗粒类型的组成的第一基质组分和第二颗粒类型，第二颗粒类型包括第二基质组分，磷组分和20 95％（重量）的沸石组分。 FCC催化剂组合物可用于裂解烃进料，特别是含有高V和Ni的渣油进料，导致较低的氢气和焦炭产率。