公开(公告)号：WO2016202663A1

公开(公告)日：2016-12-22

申请号：PCT/EP2016/063034

申请日：2016-06-08

Applicant: BASF SE

Inventor： SCHARF, Florian ,  ZHANG, Lian ,  REESINK, Bernard Hendrik ,  VAN ASTEN, David

IPC: F25B21/00

CPC classification number: F25B21/00 ,  F25B2321/002 ,  F25B2321/0021 ,  H01F1/012 ,  Y02B30/66

Abstract: The invention relates to a magnetocaloric lattice element formed by fibres of magnetocaloric material, wherein the fibres are arranged in respective parallel lattice planes, each fibre having a respective mass of magnetocaloric material, the fibres of a given lattice plane do not contact each other but each fibre of a given lattice plane is attached to at least two fibres in a next neighbouring lattice plane, and wherein the magnetocaloric lattice element exhibits exactly one predominant mass-weighted direction of longitudinal fibre extension. When arranged in alignment of its predominant mass-weighted direction of longitudinal fibre extension with an external magnetic field, the magnetocaloric lattice element achieves an advantageous, particularly high magnetization of the magnetocaloric material, and as a consequence improves the performance of the magnetocaloric cooling device.

Abstract translation: 本发明涉及由磁热材料纤维形成的磁热晶格元件，其中纤维布置在相应的平行晶格面中，每个纤维具有相应质量的磁热材料，给定晶格面的纤维不彼此接触，但每个 给定晶格面的光纤在下一个相邻晶格面中连接到至少两根光纤，并且其中磁热晶格元素表现出正好一个主要的质量加权方向的纵向光纤延伸。 当其主要的纵向纤维延伸的质量加权方向与外部磁场对准布置时，磁热晶格元件实现了磁热材料的有利的，特别高的磁化，并且因此提高了磁热冷却装置的性能。

公开(公告)号：WO2015018678A1

公开(公告)日：2015-02-12

申请号：PCT/EP2014/066132

申请日：2014-07-28

Applicant: BASF SE

Inventor： GUILLO, Francois ,  BRUECK, Ekkehard ,  REESINK, Bernard Hendrik

IPC: H01F1/01

CPC classification number: H01F1/015 ,  F25B21/00 ,  F25B2321/002

Abstract: A magnetocaloric material of the general formula (I) (Mn x Fe 1-x ) 2+u P 1–y-z Si y B z wherein 0.55 ≤ x ≤ 0.75, 0.25 ≤ y

Abstract translation: 通式（I）（Mn x Fe 1-x）2 + u P1-y-zSiyBz的磁热材料，其中0.55≤x≤0.75,0.25≤y<0.4,0.05

公开(公告)号：WO2015018610A1

公开(公告)日：2015-02-12

申请号：PCT/EP2014/065107

申请日：2014-07-15

Applicant: BASF SE

Inventor： GUILLO, Francois ,  BRUECK, Ekkehard ,  REESINK, Bernard Hendrik

IPC: H01F1/01

CPC classification number: H01F1/015 ,  F25B21/00 ,  F25B2321/002

Abstract: A magnetocaloric material of the general formula (I) (Mn x Fe 1-x ) 2+u P 1-y-z Si y B z wherein 0.25 ≤ x ≤ 0.55, 0.25 ≤ y ≤ 0.65, 0

Abstract translation: 通式（I）（Mn x Fe 1-x）2 + u P1-y-zSiyBz的磁热材料，其中0.25≤x≤0.55,0.25≤y≤0.65,0≤z≤0.2-0.1≤u≤0.05，y +z≤0.7。

公开(公告)号：WO2014115057A1

公开(公告)日：2014-07-31

申请号：PCT/IB2014/058251

申请日：2014-01-14

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： CARROLL, Colman ,  ROGGE, Olaf ,  REESINK, Bernard Hendrik ,  ROWE, Andrew ,  ARNOLD, Danny ,  TURA, Armando

IPC: H01F1/00 ,  F25B21/00

CPC classification number: F25B21/00 ,  F25B2321/002 ,  H01F1/012 ,  Y02B30/66

Abstract: A magnetocaloric cascade containing at least three different magnetocaloric materials with different Curie temperatures, which are arranged in succession by descending Curie temperature, wherein none of the different magnetocaloric materials with different Curie temperatures has a higher layer performance Lp than the magnetocaloric material with the highest Curie temperature and wherein at least one of the different magnetocaloric materials with different Curie temperatures has as lower layer performance Lp than the magnetocaloric material with the highest Curie temperature wherein Lp of a particular magnetocaloric material being calculated according to formula (I): Lp = m * dT ad,max with dT ad,max : maximum adiabatic temperature change which the particular magnetocaloric material undergoes when it is magnetized from a low magnetic field to high magnetic field during magnetocaloric cycling, m: mass of the particular magnetocaloric material contained in the magnetocaloric cascade.

Abstract translation: 包含具有不同居里温度的至少三种不同磁热材料的磁热级联，其通过降低居里温度而相继排列，其中具有不同居里温度的不同的热电材料不具有比具有最高居里的磁热材料更高的层性能Lp 其中具有不同居里温度的不同磁热材料中的至少一种具有比具有最高居里温度的磁热材料具有较低层性能Lp，其中特定磁热材料的Lp根据式（I）计算：Lp = m * dTad，max，dTad，max：特定磁热材料在磁热循环期间从低磁场磁化到高磁场时经历的最大绝热温度变化，m：包含在磁热级联中的特定磁热材料的质量。