公开(公告)号：WO1988001535A1

公开(公告)日：1988-03-10

申请号：PCT/US1987002160

申请日：1987-08-27

Applicant: BATTELLE MEMORIAL INSTITUTE

Inventor： BATTELLE MEMORIAL INSTITUTE ,  JAMES, Brian, R. ,  LI-LEE, Chung ,  LILGA, Michael, A. ,  NELSON, David, A.

IPC: B01D53/14

CPC classification number: B01J31/4038 ,  B01J31/226 ,  B01J31/2404 ,  B01J2231/70 ,  B01J2531/0216 ,  B01J2531/0219 ,  B01J2531/824 ,  C01B3/04 ,  C01B17/05 ,  C07F15/0066 ,  Y02E60/364 ,  Y02P20/584

Abstract: A process of abstracting sulfur from H2S and generating hydrogen comprising dissolving Pd2X2(mu-dppm)2 in a solvent and then introducing H2S. The palladium complex abstracts sulfur, forming hydrogen and a (mu-S) complex. The (mu-S) complex is readily oxidizable to a (mu-SO2) adduct which spontaneously loses SO2 and regenerates the palladium complex.