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公开(公告)号：WO2013165477A1
公开(公告)日：2013-11-07
申请号：PCT/US2013/000121
申请日：2013-04-30
CPC分类号： A01N49/00 , A01N31/06 , A01N35/06 , A01N37/02 , A01N37/18 , A01N37/36 , A01N37/42 , A01N43/08 , A01N43/16 , A01N2300/00 , A01N37/10
摘要： Control or repellency of mosquitoes is accomplished by bringing the insects into contact with at least one of the compounds of the structure (I): Formula (I) wherein R is selected from -OH, =O, -OC(O)R 4 , -OR 6 , -(OR) 2 , wherein each R 6 is independently selected from an alkyl group containing from 1 to 4 carbon atoms and R 4 is a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH 2 , with the proviso that when X is O R can only be =O; each Z is independently selected from (CH) and (CH 2 ); y is a numeral selected from 1 and 2; R 1 is selected from H or a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; R 2 is selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms; R 3 is selected from the group consisting of H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, -(CH 2 ) n OH, -C(O)OR 5 , -CH 2 C(O)OR 7 , -CH 2 C(O)R 8 , -C(O)NR 9 R 10 , -CH 2 C(O)NR 11 R 12 where each of R 5 , R 7 , R 8 , R 9 ,R 10 , R 11 and R 12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms and n is an integer of from 1 to 12; the bond between the 2 and 3 positions in the ring structure may be a single or a double bond; and wherein the compounds of structure (I) contain from 11 to 20 total carbon atoms in the compounds, with the proviso that when R is =0, X is CH 2 , Z is CH 2 , y is 1 R 2 is H, and R 3 is CH 2 C(0)OR 7 then the total number of carbon atoms in the compounds of structure (I) is from 15 to 20 carbon atoms, and when X is O and R is =O the total number of carbon atoms in the compounds of structure (I) is from 11 to 17 carbon atoms. The invention also includes optical isomers, diastereomers and enantiomers of the named structures. Thus, at all stereocenters where stereochemistry is not explicitly defined, all possible epimers are envisioned.
摘要翻译： 通过使昆虫与结构（I）的至少一种化合物接触来实现蚊子的控制或排斥：式（I）其中R选自-OH，= O，-OC（O）R 4， - OR 6， - （OR）2，其中每个R 6独立地选自含有1至4个碳原子的烷基，R 4是具有0至2个双键和1至15个碳原子的支链或直链，饱和或不饱和烃基 碳原子 X是O或CH2，条件是当X是O时，R只能是= O; 每个Z独立地选自（CH）和（CH 2）; y是选自1和2的数字; R 1选自H或具有0至2个双键和1至15个碳原子的支链或直链饱和或不饱和烃基; R2选自H和具有0至3个双键和1至15个碳原子的支链或直链饱和或不饱和烃基; R3选自H和具有0至3个双键和1至15个碳原子的支链或直链饱和或不饱和烃基， - （CH 2）n OH，-C（O）OR 5，-CH 2 C （O）OR 7，-CH 2 C（O）R 8，-C（O）NR 9 R 10，-CH 2 C（O）NR 11 R 12，其中R 5，R 7，R 8，R 9，R 10，R 11和R 12各自独立地选自H和支链或 具有0至3个双键和1至15个碳原子的直链，饱和或不饱和烃基，n为1至12的整数; 环结构中2和3位之间的键可以是单键或双键; 并且其中结构（I）的化合物在化合物中含有11至20个总碳原子，条件是当R为0时，X为CH 2，Z为CH 2，y为1 R 2为H，且R 3为CH 2 C （0）OR7，结构（I）化合物中碳原子总数为15〜20个碳原子，当X为O且R为= O时，结构（I）化合物中的碳原子总数 ）为11至17个碳原子。 本发明还包括命名结构的光学异构体，非对映体和对映异构体。 因此，立体化学没有明确定义的所有立体中心者，都设想到所有可能的差异。
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公开(公告)号：WO2016033069A1
公开(公告)日：2016-03-03
申请号：PCT/US2015/046734
申请日：2015-08-25
IPC分类号： A01M1/10
摘要： Compositions and methods are provided for attracting stink bugs (e.g., Halyomorpha halys). The compositions include at least one pheromone and at least one synergist. The synergist/attractant is preferably at least one of an alkyl or alkenyl ester of (2E,4Z)-decadienoic acid such as ethyl (2E,4Z)-decadienoate; an alkyl or alkenyl ester of (2Z,4E)-decadienoic acid such as ethyl (2Z,4E)- decadienoate; an alkyl or alkenyl ester of (2E,4E)-decadienoic acid such as ethyl (2E,4E)-decadienoate; an alkyl or alkenyl ester of (2E,4E,6Z)-decatrienoic acid such as ethyl (2E,4E, 6Z)-decatrienoate; and any stereoisomers thereof, and any combinations thereof. The pheromone is preferably murgantiol. This disclosure provides traps containing the composition for attracting stink bugs, and methods for attracting, capturing, killing or sterilizing stink bugs using the composition.
摘要翻译： 提供了组合物和方法来吸引臭虫（例如，Halyomorpha halys）。 组合物包括至少一种信息素和至少一种增效剂。 增效剂/引诱剂优选为（2E，4Z） - 十二碳烯酸的烷基或链烯基酯如（2E，4Z） - 癸二烯酸乙酯中的至少一种; （2Z，4E） - 癸二烯酸的烷基或链烯基酯，例如乙基（2Z，4E） - 癸二烯酸酯; （2E，4E） - 癸二烯酸的烷基或链烯基酯，例如（2E，4E） - 癸二烯酸乙酯; （2E，4E，6Z） - 十几烯酸如（2E，4E，6Z） - 十一碳烯酸乙酯的烷基或链烯基酯; 及其任何立体异构体，及其任何组合。 信息素优选是金刚酚。 本公开提供了包含用于吸引臭臭虫的组合物的陷阱，以及使用该组合物吸引，捕获，杀死或消毒臭臭虫的方法。
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公开(公告)号：WO2016028897A1
公开(公告)日：2016-02-25
申请号：PCT/US2015/045900
申请日：2015-08-19
IPC分类号： C07C255/07 , A61Q13/00 , C11B9/00
CPC分类号： C07C253/30 , C07B2200/09 , C07C255/07 , C11B9/0023
摘要： A perfume composition comprising an effective amount of at least one alkadienenitrile selected from 4,8-undecadienenitrile and isomers thereof, 4,9- dodecadienenitrile and isomers thereof, and 4,10-tridecadienenitrile and isomers thereof. The isomers of 4,8-undecadienenitrile comprise Z,Z-4,8- undecadienenitrile, E,E-4,8-undecadienenitrile, and mixed Z/E isomers of 4,8- undecadienenitrile; the isomers of 4,9-dodecadienenitrile comprise Z,Z-4,9- dodecadienenitrile, E,E-4,9-dodecadienenitrile, and mixed Z/E isomers of 4,9- dodecadienenitrile; and the isomers of 4,10-tridecadienenitrile comprise Z,Z-4,10- tridecadienenitrile, E,E-4,10-tridecadienenitrile, and mixed Z/E isomers of 4,10- tridecadienenitrile. A composition comprising an effective amount of at least one alkadienenitrile selected from 4,8-undecadienenitrile and isomers thereof, 4,9- dodecadienenitrile and isomers thereof, and 4,10-tridecadienenitrile and isomers thereof. Processes for the preparation of the isomeric alkadienenitriles are provided. The isomeric alkadienenitriles have a range of fresh, citric, ozonic and floral notes of exceptional strength.
摘要翻译： 一种香料组合物，其包含有效量的至少一种选自4,8-十一碳烯腈及其异构体的链烯二腈，4,9-十二碳二烯腈及其异构体，以及4,10-十三碳烯腈及其异构体。 4,8-十一碳烯腈的异构体包括Z，Z-4,8-十一碳烯腈，E，E-4,8-十一碳烯腈和4,8-十一二烯腈的混合Z / E异构体; 4,9-十二碳二烯腈的异构体包含Z，Z-4,9-十二碳烯腈，E，E-4,9-十二碳二烯腈和4,9-十二二烯腈的混合Z / E异构体; 4,10-十三碳烯腈的异构体包括Z，Z-4,10-十三碳烯腈，E，E-4,10-十三碳烯腈和4,10-十三碳烯腈的混合Z / E异构体。 一种组合物，其包含有效量的至少一种选自4,8-十一碳烯腈及其异构体的链烯二腈，4,9-十二二烯腈及其异构体，以及4,10-十三碳烯腈及其异构体。 提供了制备异构烷撑亚胺的方法。 异构链烷二腈具有特别强度的新鲜，柠檬酸，臭氧和花香的范围。
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公开(公告)号：WO2016028892A1
公开(公告)日：2016-02-25
申请号：PCT/US2015/045894
申请日：2015-08-19
IPC分类号： C11D3/50
CPC分类号： C07C47/21 , C11B9/0015
摘要： A perfume composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. The isomers of 4,8-undecadienal comprise Z,Z-4,8-undecadienal, E,E-4,8-undecadienal, and mixed Z/E isomers of 4,8-undecadienal; the isomers of 4,9-dodecadienal comprise Z,Z-4,9-dodecadienal, E,E-4,9-dodecadienal, and mixed Z/E isomers of 4,9- dodecadienal; and the isomers of 4,10-tridecadienal comprise Z,Z-4,10- tridecadienal, E,E-4,10-tridecadienal, and mixed Z/E isomers of 4,10- tridecadienal. A composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. Processes for the preparation of the isomer mixtures of alkadienals are provided. The isomeric alkadienals have a range of fresh, watery, ozone, grapefruit, tangerine, orange peel, aldehydic notes of exceptional strength.
摘要翻译： 一种香料组合物，其包含有效量的至少一种选自4,8-十一碳烯醛及其异构体的链烷二烯，4,9-十二二烯醛及其异构体，以及4,10-十三碳二烯及其异构体。 4,8-十一碳二烯的异构体包括Z，Z-4,8-十一碳二烯醛，E，E-4,8-十一碳二烯醛，以及4,8-十一二烯醛的混合Z / E异构体; 4,9-十二碳二烯醛的异构体包含Z，Z-4,9-十二二烯醛，E，E-4,9-十二二烯醛和4,9-十二二烯醛的混合Z / E异构体; 4,10-十三碳二烯醛的异构体包含Z，Z-4,10-十三碳二烯醛，E，E-4,10-十三碳二烯醛和4,10-十三烷二烯的混合Z / E异构体。 一种组合物，其包含有效量的至少一种选自4,8-十一碳烯醛及其异构体的链烷二烯，4,9-十二二烯醛及其异构体，以及4,10-十三碳二烯及其异构体。 提供了制备烷二醛的异构体混合物的方法。 异构链烷二酮具有一系列新鲜，含水，臭氧，葡萄柚，橘子，橙皮，醛特别强度的醛类。
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5.发明申请SYNERGISTIC FORMULATIONS FOR CONTROL AND REPELLENCY OF BITING ARTHROPODS 审中-公开用于控制和排斥的ARTHROPODS的协调制剂
公开(公告)号：WO2015073671A1
公开(公告)日：2015-05-21
申请号：PCT/US2014/065454
申请日：2014-11-13
CPC分类号： A01N37/18 , A01N31/02 , A01N31/06 , A01N35/02 , A01N37/30 , A01N37/36 , A01N37/40 , A01N37/42 , A01N43/08 , A01N43/16 , A01N49/00 , A01N37/10
摘要： Control or repellency of biting arthropods, particularly biting insects, is accomplished by bringing the biting arthropods into contact with combinations of compounds identical or related to those found on human/animal skin or in plants acting synergistically with one another, or in combination with conventional repellents like DEET®, para-menthane-3,8-diol (PMD), sec -butyl-2-(2-hydroxyethyl) piperidine carboxylate ("Picaridin"), or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds, or any synergistic combination of DEET®, PMD, Picaridin, or other nitrogen containing repellents selected from amines, amides and nitrogen containing heterocyclic compounds.
摘要翻译： 咬人节肢动物（特别是叮咬昆虫）的控制或排斥是通过使咬咬的节肢动物与在人/动物皮肤或与植物相互作用的植物中相同或相关的化合物的组合接触或与常规驱避剂组合 如DEET，对薄荷烷-3,8-二醇（PMD），仲丁基-2-（2-羟乙基）哌啶羧酸酯（“哌啶”）或其它含氮驱虫剂，其选自胺，酰胺和含氮杂环 化合物，或DEET®，PMD，哌啶或其它含氮驱虫剂的选择胺，酰胺和含氮杂环化合物的任何协同组合。
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公开(公告)号：WO2010062368A1
公开(公告)日：2010-06-03
申请号：PCT/US2009/005926
申请日：2009-11-02
CPC分类号： A01N35/06 , A01N2300/00
摘要： D- and 1-tetrahydrocarvone and d- and 1 dihydrocarvone are effective for the control of termites, fire ants and carpenter ants.
摘要翻译： D-和1-四氢呋喃酮和d-和1二氢卡泊芬对白蚁，蚂蚁和木蚂蚁的控制是有效的。
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公开(公告)号：WO2021071896A1
公开(公告)日：2021-04-15
申请号：PCT/US2020/054508
申请日：2020-10-07
摘要： This disclosure provides a synergistic biting arthropod control or repellent formulation and a method for the control or repellency of biting arthropods comprising bringing the biting arthropods into contact with said formulation, which comprises: (I) at least one compound (a) selected from the group consisting of: (1) alkyl ketones and cyclic ketones, saturated or unsaturated, branched or unbranched, containing from about 6 to about 18 carbon atoms; (2) compounds of a defined structure (A); (3) branched or unbranched, straight chain or cyclic, saturated or unsaturated, carboxylic acids containing from about 3 to about 18 carbon atoms, including isomers thereof; and (4) esters of branched or unbranched, straight chain or cyclic, saturated or unsaturated, carboxylic acids containing from about 3 to about 18 carbon atom, including isomers thereof; and (II) at least one sensate compound.
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公开(公告)号：WO2019055479A1
公开(公告)日：2019-03-21
申请号：PCT/US2018/050608
申请日：2018-09-12
CPC分类号： A01N43/16 , A01N31/06 , A01N31/08 , A01N35/06 , A01N37/18 , A01N37/36 , A01N37/42 , A01N43/08 , A01N49/00 , A01N25/18 , A01N25/34
摘要： Killing one or more biting arthropods selected from the group consisting of mosquitoes, bed bugs and ticks is accomplished by bringing the biting arthropods into contact with a toxic amount of a formulation comprising: (1) one or more compounds of structure (I), wherein the compounds of structure (I) is as defined in the summary.
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公开(公告)号：WO2019055408A1
公开(公告)日：2019-03-21
申请号：PCT/US2018/050453
申请日：2018-09-11
摘要： Killing one or more biting arthropods selected from the group consisting of mosquitoes, bed bugs and ticks is accomplished by bringing the biting arthropods into contact with a toxic amount of a formulation comprising: (1) one or more compounds of structure (I), wherein the compounds of structure is shown in the summary of invention and (2) one or more toxicant compounds selected from the group consisting of pyrethroids, carbamates, and organophosphates. The formulation can be a synergistic formulation.
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公开(公告)号：WO2018140718A1
公开(公告)日：2018-08-02
申请号：PCT/US2018/015439
申请日：2018-01-26
摘要： This disclosure relates to a method for the control or repellency of biting arthropods. The method comprises bringing the biting arthropods into contact with a biting arthropod repellent formulation. The biting arthropod repellent formulation comprises nootkatol separate from, or in combination, or in synergistic combination, with skin or plant derived compounds and compounds structurally similar to them (e.g., ketones, cyclic ketones, esters, gamma or delta lactones, and branched and/or unsaturated carboxylic acids), and/or one or more repellents selected from the group consisting of DEET®, para-menthane-3,8-diol (PMD), Picaridin, ethyl 3-[acetyl(butyl)amino]propanoate (IR3535), and other nitrogen-containing repellents including amines, amides, and nitrogen-containing heterocyclic compounds. This disclosure also relates to a biting arthropod repellent formulation comprising nootkatol separate from, or in combination, or in synergistic combination, with the skin or plant derived compounds and compounds structurally similar to them, and/or the one or more repellents.
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